The impact of the circulation system on the concentration level of micropollutants in the swimming pool water treatment system

Each pool installation should ensure proper and constant circulation of water in a closed circuit system. However, the operation of such a system can potentially cause the accumulation of small -molecule micropollutants in the pool water treatment system. The aim of this work is to confirm or reject this argument. As part of preliminary tests, the content of organic and inorganic substances in swimming pool water was analyzed based on general indicators such as TOC, UV254 absorbance and conductivity. In the main stage of the research, pool water samples collected from four different points of the swimming pool installation were subjected to chromatographic analysis to determine the small-molecule micropollutants. The tap water used to fill the basin and regular replenishment of volume losses was also tested. This study was intended to exclude the tap water as a potential source of contamination in the pool water. Preliminary studies have shown almost a two-fold increase in the total organic carbon content and absorbance UV254 at the turn of six months, which undoubtedly indicates the accumulation of organic pollutants in pool water circulation systems. It was not observed in the case of inorganic compounds. As a result of the chromatographic analyzes of the pool water, the content of pharmaceuticals and personal care product was determined. It was found that the compensation tank is the place of the highest accumulation of the tested pharmaceuticals in the pool water treatment system , while the cosmetics component accumulated in the pool basin to the greatest degree. It was affected by the duration of the filter cycle.

[1]  F. Ventura,et al.  Behavior of pharmaceuticals and drugs of abuse in a drinking water treatment plant (DWTP) using combined conventional and ultrafiltration and reverse osmosis (UF/RO) treatments. , 2011, Environmental pollution.

[2]  M. Glade,et al.  Caffeine-Not just a stimulant. , 2010, Nutrition.

[3]  Martin Wagner,et al.  Endocrine modulation and toxic effects of two commonly used UV screens on the aquatic invertebrates Potamopyrgus antipodarum and Lumbriculus variegatus. , 2008, Environmental pollution.

[4]  Christian Zwiener,et al.  Drowning in disinfection byproducts? Assessing swimming pool water. , 2007, Environmental science & technology.

[5]  Stuart J. Khan,et al.  Occurrence and daily variability of pharmaceuticals and personal care products in swimming pools , 2016, Environmental Science and Pollution Research.

[6]  L. Vidal,et al.  Ionic liquid-based single-drop microextraction followed by liquid chromatography-ultraviolet spectrophotometry detection to determine typical UV filters in surface water samples. , 2010, Talanta.

[7]  K. Fent,et al.  Global gene expression profile induced by the UV-filter 2-ethyl-hexyl-4-trimethoxycinnamate (EHMC) in zebrafish (Danio rerio). , 2011, Environmental pollution.

[8]  D. Barceló,et al.  Occurrence of pharmaceuticals and UV filters in swimming pools and spas , 2016, Environmental Science and Pollution Research.

[9]  Hélène Budzinski,et al.  Multi-residue analysis of pharmaceutical compounds in aqueous samples. , 2008, Journal of chromatography. A.

[10]  T. Albanis,et al.  Determination of residues of UV filters in natural waters by solid-phase extraction coupled to liquid chromatography-photodiode array detection and gas chromatography-mass spectrometry. , 2004, Journal of chromatography. A.

[11]  M. Dudziak,et al.  Determination of Micropollutants in Water Samples from Swimming Pool Systems , 2017, Water.

[12]  Peizhe Sun,et al.  The Presence of Pharmaceuticals and Personal Care Products in Swimming Pools , 2014 .

[13]  S. Bhattacharya,et al.  Anxiogenic action of caffeine: an experimental study in rats , 1997, Journal of psychopharmacology.

[14]  Emmanuelle Vulliet,et al.  Occurrence of pharmaceuticals and hormones in drinking water treated from surface waters , 2011 .

[15]  T. Albanis,et al.  Gas chromatographic determination of 2-hydroxy-4-methoxybenzophenone and octyldimethyl-p-aminobenzoic acid sunscreen agents in swimming pool and bathing waters by solid-phase microextraction. , 2002, Journal of chromatography. A.

[16]  M. Próba Wybrane antropogeniczne czynniki zanieczyszczenia wód powierzchniowych. Analiza zjawiska , 2013 .

[17]  E. Heath,et al.  Determination of UV filters and antimicrobial agents in environmental water samples , 2007, Analytical and bioanalytical chemistry.

[18]  Y. Valcárcel,et al.  Analysis of the presence of cardiovascular and analgesic/anti-inflammatory/antipyretic pharmaceuticals in river- and drinking-water of the Madrid Region in Spain. , 2011, Chemosphere.

[19]  Ching-Hua Huang,et al.  Sources of pharmaceuticals and personal care products in swimming pools. , 2017, Journal of water and health.