论文信息 - Oxazolidines versus schiff bases

Oxazolidines versus schiff bases

The formation of oxazolidines from propionaldehyde and aliphatic β-aminoalcohols is complicated by the appearance of appreciable amounts of unsaturated Schiff bases. The simple Schiff base, often the dominant species when aromatic aldehydes react with amines, could not be detected in the present aliphatic systems. We conclude that in aliphatic systems the order of stability is and . The gem-dimethyl group α to nitrogen stablizes the heterocyclic ring remarkably.

R. M. Srivastava | L. B. Clapp | Katherine Weissman

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