Critical Review on the Toxicity of Some Widely Used Engineered Nanoparticles

With tremendous increase in development of nanotechnology, there is a developing enthusiasm toward the application of nanoparticles in diverse areas. Carbon nanotubes, fullerenes, quantum dots, dendrimers, iron oxide, silica, and gold and silver nanoparticles are frequently used in different applications such as drug delivery, ceramic materials, semiconductors, electronics, medicine, cosmetics, etc. Some of these nanoparticles have shown major toxic effects on fauna, flora, and human beings, such as inflammation, cytotoxicity, tissue ulceration, and reduction of cell viability. Single-walled carbon nanotubes (SWCNTs) and multiwalled carbon nanotubes (MWCNTs) can induce oxidative stress and fibrosis in the lungs of rat and mice. SWCNTs can also induce oxidative stress to the nervous system in human beings. Inflammatory injury and respiratory distress can be observed due to TiO2 nanoparticles with small diameter. Nanoparticles can also pose detrimental effects on plants, such as decreased growth rate, genom...

[1]  Woong Kim,et al.  The effect of multi-walled carbon nanotubes on soil microbial activity. , 2011, Ecotoxicology and environmental safety.

[2]  Te-Hao Chen,et al.  Zinc oxide nanoparticles alter hatching and larval locomotor activity in zebrafish (Danio rerio). , 2014, Journal of hazardous materials.

[3]  Ritesh K Shukla,et al.  ROS-mediated genotoxicity induced by titanium dioxide nanoparticles in human epidermal cells. , 2011, Toxicology in vitro : an international journal published in association with BIBRA.

[4]  Gian Carlo Delgado,et al.  Economics and governance of nanomaterials: potential and risks , 2010 .

[5]  N. Hullavarad,et al.  Synthesis and characterization of monodispersed CdS nanoparticles in SiO2 fibers by sol–gel method , 2007 .

[6]  S. S. Kim,et al.  Synthesis of ceria nanoparticles by flame electrospray pyrolysis , 2007 .

[7]  Milton Sommerfeld,et al.  Toxicity assessment of manufactured nanomaterials using the unicellular green alga Chlamydomonas reinhardtii. , 2008, Chemosphere.

[8]  Young Hee Lee,et al.  Crystalline Ropes of Metallic Carbon Nanotubes , 1996, Science.

[9]  Sirajuddin,et al.  Phosphomolybdate-doped-poly(3,4-ethylenedioxythiophene) coated gold nanoparticles: synthesis, characterization and electrocatalytic reduction of bromate. , 2013, Analytica chimica acta.

[10]  D. Girard,et al.  Zinc oxide nanoparticles delay human neutrophil apoptosis by a de novo protein synthesis-dependent and reactive oxygen species-independent mechanism. , 2014, Toxicology in vitro : an international journal published in association with BIBRA.

[11]  Shuming Nie,et al.  Quantum dot-encoded mesoporous beads with high brightness and uniformity: rapid readout using flow cytometry. , 2004, Analytical chemistry.

[12]  M. Starowicz,et al.  Electrochemical Synthesis of ZnO Nanoparticles , 2008 .

[13]  Alexandra Kroll,et al.  Testing Metal‐Oxide Nanomaterials for Human Safety , 2010, Advanced materials.

[14]  Á. González-Fernández,et al.  Potential impact of metal oxide nanoparticles on the immune system: The role of integrins, L-selectin and the chemokine receptor CXCR4. , 2014, Nanomedicine : nanotechnology, biology, and medicine.

[15]  B. Meenan,et al.  Comparative in vitro cytotoxicity study of carbon nanotubes and titania nanostructures on human lung epithelial cells. , 2011, Journal of hazardous materials.

[16]  Sung Ju Cho,et al.  Quantum dot-induced cell death involves Fas upregulation and lipid peroxidation in human neuroblastoma cells , 2007, Journal of nanobiotechnology.

[17]  Joel N Meyer,et al.  Comparative toxicity of silver nanoparticles on oxidative stress and DNA damage in the nematode, Caenorhabditis elegans. , 2014, Chemosphere.

[18]  S. Oldenburg,et al.  Evaluation of Silver Nanoparticle Toxicity in Skin in Vivo and Keratinocytes in Vitro , 2009, Environmental health perspectives.

[19]  A. Rinzler,et al.  Carbon nanotube actuators , 1999, Science.

[20]  H. Jang Experimental study of synthesis of silica nanoparticles by a bench-scale diffusion flame reactor , 2001 .

[21]  M. Cai,et al.  Preparation and characterization of ceria nanoparticles using crystalline hydrate cerium propionate as precursor , 2007 .

[22]  Anne Kahru,et al.  Toxicity of nanosized and bulk ZnO, CuO and TiO2 to bacteria Vibrio fischeri and crustaceans Daphnia magna and Thamnocephalus platyurus. , 2008, Chemosphere.

[23]  Ya‐Ping Sun,et al.  Advances in Bioapplications of Carbon Nanotubes , 2009 .

[24]  A Paul Alivisatos,et al.  Cellular effect of high doses of silica-coated quantum dot profiled with high throughput gene expression analysis and high content cellomics measurements. , 2006, Nano letters.

[25]  T. Xia,et al.  Toxic Potential of Materials at the Nanolevel , 2006, Science.

[26]  Chao Liu,et al.  Synthesis of bilayer oleic acid-coated Fe3O4 nanoparticles and their application in pH-responsive Pickering emulsions. , 2007, Journal of colloid and interface science.

[27]  S. Cho,et al.  Preparation of α-alumina nanoparticles via vapor-phase hydrolysis of AlCl3 , 2009 .

[28]  Horst-Günter Rubahn,et al.  Exposure to silver nanoparticles induces size- and dose-dependent oxidative stress and cytotoxicity in human colon carcinoma cells. , 2014, Toxicology in vitro : an international journal published in association with BIBRA.

[29]  S. Bandyopadhyay,et al.  Exposure of cerium oxide nanoparticles to kidney bean shows disturbance in the plant defense mechanisms. , 2014, Journal of hazardous materials.

[30]  Amit Kumar,et al.  Understanding the toxicity of aggregated zero valent copper nanoparticles against Escherichia coli. , 2010, Journal of hazardous materials.

[31]  Young Hee Lee,et al.  Synthesis of aligned carbon nanotubes using thermal chemical vapor deposition , 1999 .

[32]  G. Pojana,et al.  In vitro effects of suspensions of selected nanoparticles (C60 fullerene, TiO2, SiO2) on Mytilus hemocytes. , 2010, Aquatic toxicology.

[33]  B. Badie,et al.  Internalization of MWCNTs by microglia: Possible application in immunotherapy of brain tumors , 2007, NeuroImage.

[34]  C. Branford-White,et al.  Removal of Cu2+ from aqueous solution by chitosan-coated magnetic nanoparticles modified with alpha-ketoglutaric acid. , 2009, Journal of colloid and interface science.

[35]  P. Holden,et al.  Zinc oxide nanoparticles delay soybean development: a standard soil microcosm study. , 2014, Ecotoxicology and environmental safety.

[36]  Yulong Ding,et al.  Investigation into the antibacterial behaviour of suspensions of ZnO nanoparticles (ZnO nanofluids) , 2007 .

[37]  Xiaoyan Zou,et al.  Amino acid-dependent transformations of citrate-coated silver nanoparticles: impact on morphology, stability and toxicity. , 2014, Toxicology letters.

[38]  M. Bogo,et al.  Toxicological effects induced by the nanomaterials fullerene and nanosilver in the polychaeta Laeonereis acuta (Nereididae) and in the bacteria communities living at their surface. , 2013, Marine environmental research.

[39]  Feng Zhao,et al.  Acute toxicological effects of copper nanoparticles in vivo. , 2006, Toxicology letters.

[40]  Y. Maeda,et al.  Sonochemical synthesis of gold nanoparticles on chitosan , 2007 .

[41]  G. Oberdörster,et al.  Pulmonary retention of ultrafine and fine particles in rats. , 1992, American journal of respiratory cell and molecular biology.

[42]  Peng Liu,et al.  Toxicity evaluation of CdTe quantum dots with different size on Escherichia coli. , 2012, Toxicology in vitro : an international journal published in association with BIBRA.

[43]  M. Yudasaka,et al.  Optimum hole-opening condition for Cisplatin incorporation in single-wall carbon nanohorns and its release. , 2006, The journal of physical chemistry. B.

[44]  Jing-Fung Lin,et al.  Linear birefringence and dichroism in citric acid coated Fe3O4 magnetic nanoparticles , 2014 .

[45]  J. Smolík,et al.  Vapor Phase Synthesis of Zirconia Fine Particles from Zirconium Tetra-Tert-Butoxide , 2007 .

[46]  Jinfu Wang,et al.  Silica white obtained from rice husk in a fluidized bed , 2001 .

[47]  M. Castro,et al.  Synthesis of SnO2 nanoparticles through the controlled precipitation route , 2007 .

[48]  Kurt Straif,et al.  Carcinogenicity of carbon black, titanium dioxide, and talc. , 2006, The Lancet Oncology.

[49]  C. Vannini,et al.  Phytotoxic and genotoxic effects of silver nanoparticles exposure on germinating wheat seedlings. , 2014, Journal of plant physiology.

[50]  Wei Yang,et al.  Inhaled nanoparticles--a current review. , 2008, International journal of pharmaceutics.

[51]  A. Massarsky,et al.  Silver nanoparticles inhibit the gill Na⁺/K⁺-ATPase and erythrocyte AChE activities and induce the stress response in adult zebrafish (Danio rerio). , 2014, Ecotoxicology and environmental safety.

[52]  Seishiro Hirano,et al.  Uptake and cytotoxic effects of multi-walled carbon nanotubes in human bronchial epithelial cells. , 2010, Toxicology and applied pharmacology.

[53]  Albert Duschl,et al.  SWCNT suppress inflammatory mediator responses in human lung epithelium in vitro. , 2009, Toxicology and applied pharmacology.

[54]  V. C. Moore,et al.  Band Gap Fluorescence from Individual Single-Walled Carbon Nanotubes , 2002, Science.

[55]  F. Perreault,et al.  Different toxicity mechanisms between bare and polymer-coated copper oxide nanoparticles in Lemna gibba. , 2014, Environmental pollution.

[56]  Q. Pankhurst,et al.  Progress in applications of magnetic nanoparticles in biomedicine , 2009 .

[57]  Feng Xu,et al.  Cytotoxicity of titanium dioxide nanoparticles differs in four liver cells from human and rat , 2011 .

[58]  Vicki Stone,et al.  Review of fullerene toxicity and exposure--appraisal of a human health risk assessment, based on open literature. , 2010, Regulatory toxicology and pharmacology : RTP.

[59]  Robert L. Tanguay,et al.  In vivo evaluation of carbon fullerene toxicity using embryonic zebrafish. , 2007, Carbon.

[60]  Wei-xian Zhang,et al.  Nanoscale Iron Particles for Environmental Remediation: An Overview , 2003 .

[61]  E. Oberdörster Manufactured Nanomaterials (Fullerenes, C60) Induce Oxidative Stress in the Brain of Juvenile Largemouth Bass , 2004, Environmental health perspectives.

[62]  G. E. Gadd,et al.  Comparative toxicity of nanoparticulate ZnO, bulk ZnO, and ZnCl2 to a freshwater microalga (Pseudokirchneriella subcapitata): the importance of particle solubility. , 2007, Environmental science & technology.

[63]  C. Gagnon,et al.  Ecotoxicity of CdTe quantum dots to freshwater mussels: impacts on immune system, oxidative stress and genotoxicity. , 2008, Aquatic toxicology.

[64]  C. Shang,et al.  Adsorption of acid dyes from aqueous solutions by the ethylenediamine-modified magnetic chitosan nanoparticles. , 2011, Journal of hazardous materials.

[65]  M. Haase,et al.  WET-CHEMICAL SYNTHESIS OF DOPED COLLOIDAL NANOPARTICLES : YVO4:LN (LN = EU, SM, DY) , 1998 .

[66]  W. K. Maser,et al.  Large-scale production of single-walled carbon nanotubes by the electric-arc technique , 1997, Nature.

[67]  J. Hahn,et al.  Cytotoxicity of, and innate immune response to, size-controlled polypyrrole nanoparticles in mammalian cells. , 2011, Biomaterials.

[68]  Narinder Singh,et al.  Imidazole and imine coated ZnO nanoparticles for nanomolar detection of Al(III) and Zn(II) in semi-aqueous media , 2014 .

[69]  T. Zaki,et al.  Preparation of high pure α-Al2O3 nanoparticles at low temperatures using Pechini method , 2012 .

[70]  Y. Haik,et al.  Removal and recovery of acridine orange from solutions by use of magnetic nanoparticles. , 2009, Journal of hazardous materials.

[71]  P. Bernier,et al.  Effects of fullerenes and single-wall carbon nanotubes on murine and human macrophages , 2006 .

[72]  Rajan Jose,et al.  Magnetic Iron Oxide Nanoparticles: Chemical Synthesis and Applications Review , 2013 .

[73]  R. Tannenbaum,et al.  Size-controlled synthesis of alumina nanoparticles from aluminum alkoxides , 2005 .

[74]  Y. Kim,et al.  Role of systemic T-cells and histopathological aspects after subcutaneous implantation of various carbon nanotubes in mice , 2006 .

[75]  M. Barnett,et al.  Immobilization of mercury in sediment using stabilized iron sulfide nanoparticles. , 2009, Water research.

[76]  Eiichi Nakamura,et al.  In Vivo Magnetic Resonance Imaging of Single‐Walled Carbon Nanohorns by Labeling with Magnetite Nanoparticles , 2006 .

[77]  José María Monserrat,et al.  Effects of carbon nanomaterials fullerene C₆₀ and fullerol C₆₀(OH)₁₈₋₂₂ on gills of fish Cyprinus carpio (Cyprinidae) exposed to ultraviolet radiation. , 2012, Aquatic toxicology.

[78]  L C Chen,et al.  Metal fume fever: characterization of clinical and plasma IL-6 responses in controlled human exposures to zinc oxide fume at and below the threshold limit value. , 1997, Journal of occupational and environmental medicine.

[79]  Kirk J. Ziegler,et al.  Synthesis of organic monolayer-stabilized copper nanocrystals in supercritical water. , 2001, Journal of the American Chemical Society.

[80]  J. James,et al.  Pulmonary toxicity of single-wall carbon nanotubes in mice 7 and 90 days after intratracheal instillation. , 2003, Toxicological sciences : an official journal of the Society of Toxicology.

[81]  A. Salinaro,et al.  Chemical oxidation and DNA damage catalysed by inorganic sunscreen ingredients , 1997, FEBS letters.

[82]  M. Marszałł,et al.  Synthesis of new chitosan coated magnetic nanoparticles with surface modified with long-distanced amino groups as a support for bioligands binding , 2014 .

[83]  V. Gopinath,et al.  Synthesis and characterization of polyethylene glycol (PEG) coated Fe3O4 nanoparticles by chemical co-precipitation method for biomedical applications. , 2015, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[84]  L. Forró,et al.  Cellular toxicity of carbon-based nanomaterials. , 2006, Nano letters.

[85]  Bo Chen,et al.  In vitro evaluation of cytotoxicity and oxidative stress induced by multiwalled carbon nanotubes in murine RAW 264.7 macrophages and human A549 lung cells. , 2011, Biomedical and environmental sciences : BES.

[86]  Xingguo Chen,et al.  Preparation and characterization of hexadecyl functionalized magnetic silica nanoparticles and its application in Rhodamine 6G removal , 2011 .

[87]  Robert L Tanguay,et al.  Fullerene C60 exposure elicits an oxidative stress response in embryonic zebrafish. , 2008, Toxicology and applied pharmacology.

[88]  P. Prasad,et al.  Zinc Oxide Nanocrystals for Non-resonant Nonlinear Optical Microscopy in Biology and Medicine. , 2008, The journal of physical chemistry. C, Nanomaterials and interfaces.

[89]  Federica Valentini,et al.  Effects of single-wall carbon nanotubes in human cells of the oral cavity: geno-cytotoxic risk. , 2011, Toxicology in vitro : an international journal published in association with BIBRA.

[90]  M. Mahmoud,et al.  Photocatalytic degradation of methyl red dye by silica nanoparticles. , 2008, Journal of hazardous materials.

[91]  C. Murphy,et al.  Seedless, Surfactantless Wet Chemical Synthesis of Silver Nanowires , 2003 .

[92]  Nobuhisa Iwata,et al.  Effects of C60, a Fullerene, on the Activities of Glutathione S-Transferase and Glutathione-Related Enzymes in Rodent and Human Livers , 1998 .

[93]  M. Rao,et al.  Structure, microstructure and physical properties of ZnO based materials in various forms: bulk, thin film and nano , 2007 .

[94]  Wei Liu,et al.  Protein Binding by Functionalized Multiwalled Carbon Nanotubes Is Governed by the Surface Chemistry of Both Parties and the Nanotube Diameter , 2008 .

[95]  Kaja Kasemets,et al.  Toxicity of nanoparticles of ZnO, CuO and TiO2 to yeast Saccharomyces cerevisiae. , 2009, Toxicology in vitro : an international journal published in association with BIBRA.

[96]  V. Gubskaya,et al.  Study of Mutagenic Activity of Fullerene and Some of Its Derivatives Using His+ Reversions of Salmonella typhimurium as an Example , 2002, Russian Journal of Genetics.

[97]  R. Banerjee,et al.  Effect of the size-induced structural transformation on the band gap in CdS nanoparticles , 2000 .

[98]  M. Foldvari,et al.  Carbon nanotubes as functional excipients for nanomedicines: II. Drug delivery and biocompatibility issues. , 2008, Nanomedicine : nanotechnology, biology, and medicine.

[99]  H. Karlsson,et al.  Size-dependent toxicity of metal oxide particles--a comparison between nano- and micrometer size. , 2009, Toxicology letters.

[100]  E. Bekyarova,et al.  Large-scale fabrication of aligned single-walled carbon nanotube array and hierarchical single-walled carbon nanotube assembly. , 2004, Journal of the American Chemical Society.

[101]  Daniel W. Elliott,et al.  Perchlorate Reduction by Nanoscale Iron Particles , 2005 .

[102]  M. Prato,et al.  Biomedical applications of functionalised carbon nanotubes. , 2005, Chemical communications.

[103]  Weizhen Zeng,et al.  A new sol-gel route using inorganic salt for synthesizing Al2O3 nanopowders , 1998 .

[104]  N. Musee,et al.  The effects of engineered nanoparticles on survival, reproduction, and behaviour of freshwater snail, Physa acuta (Draparnaud, 1805). , 2010, Chemosphere.

[105]  Andrzej Huczko,et al.  Preliminary results on the pathogenic effects of intratracheal exposure to one-dimensional nanocarbons , 2006 .

[106]  L. Reijnders Hazard Reduction in Nanotechnology , 2008 .

[107]  J. Monserrat,et al.  Co-exposure of the organic nanomaterial fullerene C₆₀ with benzo[a]pyrene in Danio rerio (zebrafish) hepatocytes: evidence of toxicological interactions. , 2014, Aquatic toxicology.

[108]  Baoshan Xing,et al.  Root uptake and phytotoxicity of ZnO nanoparticles. , 2008, Environmental science & technology.

[109]  Yang-Chuang Chang,et al.  Magnetic chitosan nanoparticles: Studies on chitosan binding and adsorption of Co(II) ions , 2006 .

[110]  C. Feldmann Polyol‐Mediated Synthesis of Nanoscale Functional Materials , 2003 .

[111]  Udo Weimar,et al.  Morphological analysis of nanocrystalline SnO2 for gas sensor applications , 1996 .

[112]  Zhanhong Sun,et al.  Synthesis of nanocrystalline MgAl2O4 spinel powders by a novel chemical method , 2007 .

[113]  P. Baron,et al.  Unusual inflammatory and fibrogenic pulmonary responses to single-walled carbon nanotubes in mice. , 2005, American journal of physiology. Lung cellular and molecular physiology.

[114]  Amane Shiohara,et al.  On the Cyto‐Toxicity Caused by Quantum Dots , 2004, Microbiology and immunology.

[115]  N. Monteiro-Riviere,et al.  In vitro toxicity assessment of three hydroxylated fullerenes in human skin cells. , 2011, Toxicology in vitro : an international journal published in association with BIBRA.

[116]  Su He Wang,et al.  Polyethyleneimine-Mediated Functionalization of Multiwalled Carbon Nanotubes: Synthesis, Characterization, and In Vitro Toxicity Assay , 2009 .

[117]  E. Figgemeier,et al.  Titanium dioxide nanoparticles prepared by laser pyrolysis : synthesis and photocatalytic properties , 2007 .

[118]  Diane Schwegler-Berry,et al.  Potential in vitro effects of carbon nanotubes on human aortic endothelial cells. , 2009, Toxicology and applied pharmacology.

[119]  Seockheon Lee,et al.  Evaluation of citrate-coated magnetic nanoparticles as draw solute for forward osmosis , 2014 .

[120]  Paul B Tchounwou,et al.  A study of the mechanism of in vitro cytotoxicity of metal oxide nanoparticles using catfish primary hepatocytes and human HepG2 cells. , 2011, The Science of the total environment.

[121]  J. P. Zhang,et al.  Controlled production of aligned-nanotube bundles , 1997, Nature.

[122]  Fei Wu,et al.  The splenic toxicity of water soluble multi-walled carbon nanotubes in mice , 2009 .

[123]  François Huaux,et al.  Respiratory toxicity of carbon nanotubes: How worried should we be? , 2006 .

[124]  Víctor Puntes,et al.  Evaluation of the ecotoxicity of model nanoparticles. , 2009, Chemosphere.

[125]  Mark R. Wiesner,et al.  Effects of fullerene nanoparticles on Escherichia coli K12 respiratory activity in aqueous suspension and potential use for membrane biofouling control , 2009 .

[126]  George M. Whitesides,et al.  Wet chemical approaches to the characterization of organic surfaces: self-assembled monolayers, wetting, and the physical-organic chemistry of the solid-liquid interface , 1990 .

[127]  Ki-tae Kim,et al.  Effect of preparation methods on toxicity of fullerene water suspensions to Japanese medaka embryos. , 2010, The Science of the total environment.

[128]  M. Gallarate,et al.  Photocatalytic Activity of Inorganic Sunscreens , 2001 .

[129]  M. Rezaei,et al.  Synthesis of mesoporous nanocrystalline MgAl2O4 spinel via surfactant assisted precipitation route , 2010 .

[130]  Richard L. Johnson,et al.  Nanotechnologies for environmental cleanup , 2006 .

[131]  S. Hannongbua,et al.  Effect of silver nanoparticles on rice (Oryza sativa L. cv. KDML 105) seed germination and seedling growth. , 2014, Ecotoxicology and environmental safety.

[132]  A. Nayak,et al.  Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles , 2012 .

[133]  Yong Yuan,et al.  High-capacity carbon-coated titanium dioxide core–shell nanoparticles modified three dimensional anodes for improved energy output in microbial fuel cells , 2015 .

[134]  N. Srinivasan,et al.  The effect of various capping agents on the surface modifications of sol–gel synthesised ZnO nanoparticles , 2012 .

[135]  Miqin Zhang,et al.  Folic acid-PEG conjugated superparamagnetic nanoparticles for targeted cellular uptake and detection by MRI. , 2006, Journal of biomedical materials research. Part A.

[136]  Charles M. Lieber,et al.  Carbon nanotube-based nonvolatile random access memory for molecular computing , 2000, Science.

[137]  V. Colvin The potential environmental impact of engineered nanomaterials , 2003, Nature Biotechnology.

[138]  Estibalitz Ochoteco,et al.  Gold coated ferric oxide nanoparticles based disposable magnetic genosensors for the detection of DNA hybridization processes. , 2011, Biosensors & bioelectronics.

[139]  Bong Hyun Chung,et al.  Acute toxicity and pharmacokinetics of 13 nm-sized PEG-coated gold nanoparticles. , 2009, Toxicology and applied pharmacology.

[140]  Tolga Çavaş,et al.  Effects of fullerenol nanoparticles on acetamiprid induced cytoxicity and genotoxicity in cultured human lung fibroblasts. , 2014, Pesticide biochemistry and physiology.

[141]  C. Fajardo,et al.  Impact of Ag and Al₂O₃ nanoparticles on soil organisms: in vitro and soil experiments. , 2014, The Science of the total environment.

[142]  Florence Mouchet,et al.  Toxicity of CeO2 nanoparticles at different trophic levels--effects on diatoms, chironomids and amphibians. , 2015, Chemosphere.

[143]  B. Kim,et al.  Biological synthesis of gold nanoparticles using Magnolia kobus and Diopyros kaki leaf extracts , 2009 .

[144]  A. Afkhami,et al.  Adsorptive removal of Congo red, a carcinogenic textile dye, from aqueous solutions by maghemite nanoparticles. , 2010, Journal of hazardous materials.

[145]  J. Kwon,et al.  Lack of genotoxic potential of ZnO nanoparticles in in vitro and in vivo tests. , 2014, Mutation research. Genetic toxicology and environmental mutagenesis.

[146]  D. Dionysiou,et al.  Trichloroethene hydrodechlorination in water by highly disordered monometallic nanoiron , 2005 .

[147]  Yixue Chen,et al.  Adsorption of copper(II) on multiwalled carbon nanotubes in the absence and presence of humic or fulvic acids. , 2010, Journal of hazardous materials.

[148]  J. Hughes,et al.  Designing Pd-on-Au bimetallic nanoparticle catalysts for trichloroethene hydrodechlorination. , 2005, Environmental science & technology.

[149]  A. Yu,et al.  Design and construction of polymerized-glucose coated Fe3O4 magnetic nanoparticles for delivery of aspirin , 2013 .

[150]  Antonio Marcomini,et al.  Genotoxicity, cytotoxicity, and reactive oxygen species induced by single‐walled carbon nanotubes and C60 fullerenes in the FE1‐Muta™Mouse lung epithelial cells , 2008, Environmental and molecular mutagenesis.

[151]  Xiangke Wang,et al.  Removal of chromium from aqueous solution by using oxidized multiwalled carbon nanotubes. , 2009, Journal of Hazardous Materials.

[152]  W. D. de Heer,et al.  A Carbon Nanotube Field-Emission Electron Source , 1995, Science.

[153]  W. Kreyling,et al.  Translocation of Inhaled Ultrafine Particles to the Brain , 2004, Inhalation toxicology.

[154]  S. Chaudhuri,et al.  Synthesis and optical characterization of sol–gel derived zinc sulphide nanoparticles confined in amorphous silica thin films , 2003 .

[155]  William R. Heineman,et al.  Nanotube electrodes and biosensors , 2007 .

[156]  Wei Bai,et al.  Effects of rare earth oxide nanoparticles on root elongation of plants. , 2010, Chemosphere.

[157]  Y. Yoon,et al.  Hydrothermal synthesis of PtRu nanoparticles supported on graphene sheets for methanol oxidation in direct methanol fuel cell , 2011 .

[158]  Xiao-Dong Zhou,et al.  In vitro toxicity of silica nanoparticles in human lung cancer cells. , 2006, Toxicology and applied pharmacology.

[159]  H. Ratte Bioaccumulation and toxicity of silver compounds: A review , 1999 .

[160]  Peng Wang,et al.  In vitro evaluation of cytotoxicity of engineered metal oxide nanoparticles. , 2009, The Science of the total environment.

[161]  J. Nagy,et al.  Respiratory toxicity of multi-wall carbon nanotubes. , 2005, Toxicology and applied pharmacology.

[162]  Richard D Handy,et al.  Toxicity of titanium dioxide nanoparticles to rainbow trout (Oncorhynchus mykiss): gill injury, oxidative stress, and other physiological effects. , 2007, Aquatic toxicology.

[163]  Yoon,et al.  Crossed nanotube junctions , 2000, Science.

[164]  Rui Qiao,et al.  In vivo biomodification of lipid-coated carbon nanotubes by Daphnia magna. , 2007, Environmental science & technology.

[165]  Y. Yamini,et al.  Extraction of three nitrophenols using polypyrrole-coated magnetic nanoparticles based on anion exchange process. , 2013, Journal of chromatography. A.

[166]  Shin Sik Choi,et al.  Apoptosis-mediated in vivo toxicity of hydroxylated fullerene nanoparticles in soil nematode Caenorhabditis elegans. , 2012, Chemosphere.

[167]  Feng Zhao,et al.  Ultrahigh reactivity provokes nanotoxicity: explanation of oral toxicity of nano-copper particles. , 2007, Toxicology letters.

[168]  M. Saunders,et al.  Uptake and cytotoxicity of chitosan nanoparticles in human liver cells. , 2010, Toxicology and applied pharmacology.

[169]  R. Aitken,et al.  Manufacture and use of nanomaterials: current status in the UK and global trends. , 2006, Occupational medicine.

[170]  S. Fukushima,et al.  Pulmonary toxicity of intratracheally instilled multiwall carbon nanotubes in male Fischer 344 rats. , 2010, Industrial health.

[171]  Jingyun Wang,et al.  Cytotoxicity of single-walled carbon nanotubes on PC12 cells. , 2011, Toxicology in vitro : an international journal published in association with BIBRA.

[172]  V. Trudeau,et al.  Silver nanoparticles stimulate glycogenolysis in rainbow trout (Oncorhynchus mykiss) hepatocytes. , 2014, Aquatic toxicology.

[173]  Nick Serpone,et al.  In vitro photochemical damage to DNA, RNA and their bases by an inorganic sunscreen agent on exposure to UVA and UVB radiation , 1997 .

[174]  T. Scott,et al.  Application of zero-valent iron nanoparticles for the removal of aqueous Co2+ ions under various experimental conditions , 2008 .

[175]  D. Elliott,et al.  Field assessment of nanoscale bimetallic particles for groundwater treatment. , 2001, Environmental science & technology.

[176]  N. Chandra,et al.  Photo degradation of synthetic dyes using cadmium sulfide nanoparticles synthesized in the presence of different capping agents. , 2012 .

[177]  Xingguo Chen,et al.  A simplified method for synthesis of Fe3O4@PAA nanoparticles and its application for the removal of basic dyes , 2012 .

[178]  Ju Yeon Choi,et al.  Hyaluronic acid-coated solid lipid nanoparticles for targeted delivery of vorinostat to CD44 overexpressing cancer cells. , 2014, Carbohydrate polymers.

[179]  J. Gostner,et al.  TiO2 nanoparticles and bulk material stimulate human peripheral blood mononuclear cells , 2014, Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association.

[180]  Y. Hiraku,et al.  Nitrative DNA damage induced by multi-walled carbon nanotube via endocytosis in human lung epithelial cells. , 2012, Toxicology and applied pharmacology.

[181]  B. Fugetsu,et al.  Studies on toxicity of multi-walled carbon nanotubes on suspension rice cells , 2009 .

[182]  N. Renuka,et al.  Mesoporous γ-alumina nanoparticles: Synthesis, characterization and dye removal efficiency , 2012 .

[183]  G. Hota,et al.  Synthesis of ultra-fine α-Al2O3 fibers via electrospinning method , 2011 .

[184]  Thomas B Scott,et al.  The application of zero-valent iron nanoparticles for the remediation of a uranium-contaminated waste effluent. , 2010, Journal of hazardous materials.

[185]  B. K. Mishra,et al.  Mg-doped nano ferrihydrite—A new adsorbent for fluoride removal from aqueous solutions , 2012 .

[186]  J. Teixeira,et al.  Effects of titanium dioxide nanoparticles in human gastric epithelial cells in vitro. , 2014, Biomedicine & pharmacotherapy = Biomedecine & pharmacotherapie.

[187]  Eugenia Valsami-Jones,et al.  Toxicity and accumulation of silver nanoparticles during development of the marine polychaete Platynereis dumerilii. , 2014, The Science of the total environment.

[188]  Y. Kim,et al.  In vivo immunological toxicity in mice of carbon nanotubes with impurities , 2009 .

[189]  B. Xing,et al.  Effect of sub-acute exposure to TiO2 nanoparticles on oxidative stress and histopathological changes in Juvenile Carp (Cyprinus carpio). , 2009, Journal of environmental sciences.

[190]  M. L. Curri,et al.  Photocatalytic degradation of methyl-red by immobilised nanoparticles of TiO2 and ZnO. , 2004, Water science and technology : a journal of the International Association on Water Pollution Research.

[191]  A. Gupta,et al.  Kinetics of adsorptive removal of DEClP and GB on impregnated Al2O3 nanoparticles. , 2010, Journal of hazardous materials.

[192]  P. Oleszczuk,et al.  The effect of inorganic nanoparticles (ZnO, Cr2O3, CuO and Ni) and their bulk counterparts on enzyme activities in different soils , 2014 .

[193]  B. K. Dutta,et al.  Zinc oxide nano-particles--sonochemical synthesis, characterization and application for photo-remediation of heavy metal. , 2012, Ultrasonics sonochemistry.

[194]  Jamie R Lead,et al.  Manufactured nanoparticles: an overview of their chemistry, interactions and potential environmental implications. , 2008, The Science of the total environment.

[195]  Kyunghee Choi,et al.  Pro-inflammatory and potential allergic responses resulting from B cell activation in mice treated with multi-walled carbon nanotubes by intratracheal instillation. , 2009, Toxicology.

[196]  S. Hosseini,et al.  Synthesis and characterization of sulfonated-mercaptopropanoic acid coated Fe3O4 nanoparticles as a novel acid magnetic catalyst for Biginelli reaction , 2013 .

[197]  R. Klaper,et al.  Functionalization impacts the effects of carbon nanotubes on the immune system of rainbow trout, Oncorhynchus mykiss. , 2010, Aquatic toxicology.

[198]  G. Oberdörster,et al.  Nanotoxicology: An Emerging Discipline Evolving from Studies of Ultrafine Particles , 2005, Environmental health perspectives.

[199]  A. Azam Microwave assisted synthesis and characterization of Co doped Cu ferrite nanoparticles , 2012 .

[200]  M. Prato,et al.  Targeted delivery of amphotericin B to cells by using functionalized carbon nanotubes. , 2005, Angewandte Chemie.

[201]  Sheng Chu,et al.  Electrically pumped ultraviolet ZnO diode lasers on Si , 2008 .

[202]  V. Grassian,et al.  Titanium Dioxide Nanoparticles: Grassian et al. Respond , 2008, Environmental Health Perspectives.

[203]  S. Belkin,et al.  CdSe quantum dots induce superoxide stress in engineered biosensor bacteria , 2009 .

[204]  Colin R. Janssen,et al.  Aggregation and ecotoxicity of CeO₂ nanoparticles in synthetic and natural waters with variable pH, organic matter concentration and ionic strength. , 2011, Environmental pollution.

[205]  S. Yasuda,et al.  Room-temperature synthesis of single-wall carbon nanotubes by an electrochemical process , 2012 .

[206]  Eva Oberdörster,et al.  Ecotoxicology of carbon-based engineered nanoparticles: Effects of fullerene (C60) on aquatic organisms , 2006 .

[207]  J. James,et al.  A Review of Carbon Nanotube Toxicity and Assessment of Potential Occupational and Environmental Health Risks , 2006, Critical reviews in toxicology.

[208]  Nick Serpone,et al.  Inorganic and organic UV filters: Their role and efficacy in sunscreens and suncare products , 2007 .

[209]  M. Muhammed,et al.  Arsenate removal with 3-mercaptopropanoic acid-coated superparamagnetic iron oxide nanoparticles. , 2015, Journal of colloid and interface science.

[210]  François Huaux,et al.  Clastogenic and aneugenic effects of multi-wall carbon nanotubes in epithelial cells. , 2008, Carcinogenesis.

[211]  Sara Mahshid,et al.  Synthesis of TiO2 nanoparticles by hydrolysis and peptization of titanium isopropoxide solution , 2006 .

[212]  N. Felorzabihi,et al.  Water-Soluble CdSe Quantum Dots Passivated by a Multidentate Diblock Copolymer , 2007 .

[213]  Huajian Gao,et al.  Effect of single wall carbon nanotubes on human HEK293 cells. , 2005, Toxicology letters.

[214]  F. Ghaffarifar,et al.  Efficacy of biogenic selenium nanoparticles against Leishmania major: in vitro and in vivo studies. , 2013, Journal of trace elements in medicine and biology : organ of the Society for Minerals and Trace Elements.

[215]  J. Dai,et al.  Multi-walled carbon nanotubes decrease lactate dehydrogenase activity in enzymatic reaction. , 2011, Bioelectrochemistry.

[216]  R. Khalifehzadeh,et al.  Sonochemical preparation of TiO2 nanoparticles , 2007 .

[217]  D. Oughton,et al.  Ecotoxicological effects of an aged TiO2 nanocomposite measured as apoptosis in the anecic earthworm Lumbricus terrestris after exposure through water, food and soil. , 2011, Environment international.

[218]  M. Ema,et al.  Evaluation of genotoxicity of multi-walled carbon nanotubes in a battery of in vitro and in vivo assays. , 2012, Regulatory toxicology and pharmacology : RTP.

[219]  M. Pumera,et al.  Electrochemical genosensors for biomedical applications based on gold nanoparticles. , 2007, Biosensors & bioelectronics.

[220]  M. Ozawa Thermal stabilization of catalytic compositions for automobile exhaust treatment through rare earth modification of alumina nanoparticle support , 2006 .

[221]  T. Scott,et al.  Synthesis and characterization of kaolinite-supported zero-valent iron nanoparticles and their application for the removal of aqueous Cu2+ and Co2+ ions , 2009 .

[222]  Lihua Zhu,et al.  Efficient removal of organic pollutants with magnetic Nanoscaled BiFeO(3) as a reusable heterogeneous fenton-like catalyst. , 2010, Environmental science & technology.

[223]  P. Baron,et al.  Exposure to Carbon Nanotube Material: Assessment of Nanotube Cytotoxicity using Human Keratinocyte Cells , 2003, Journal of toxicology and environmental health. Part A.

[224]  Chihpin Huang,et al.  Enhance the photocatalytic activity for the degradation of organic contaminants in water by incorporating TiO2 with zero-valent iron. , 2010, The Science of the total environment.

[225]  Maumita Bandyopadhyay,et al.  In vitro and in vivo genotoxicity of silver nanoparticles. , 2012, Mutation research.

[226]  J. Crittenden,et al.  Arsenate removal by nanostructured ZrO2 spheres. , 2008, Environmental science & technology.

[227]  J. Irudayaraj,et al.  One-stop genomic DNA extraction by salicylic acid-coated magnetic nanoparticles. , 2013, Analytical biochemistry.

[228]  M. Bebianno,et al.  Immunocytotoxicity, cytogenotoxicity and genotoxicity of cadmium-based quantum dots in the marine mussel Mytilus galloprovincialis. , 2014, Marine environmental research.

[229]  Seishiro Hirano,et al.  Multi-walled carbon nanotubes injure the plasma membrane of macrophages. , 2008, Toxicology and applied pharmacology.

[230]  Michael Riediker,et al.  Use of nanoparticles in Swiss Industry: a targeted survey. , 2008, Environmental science & technology.

[231]  J. Filser,et al.  The coating makes the difference: acute effects of iron oxide nanoparticles on Daphnia magna. , 2014, The Science of the total environment.

[232]  N. Chandrasekaran,et al.  Ecotoxicity study of titania (TiO₂) NPs on two microalgae species: Scenedesmus sp. and Chlorella sp. , 2011, Ecotoxicology and environmental safety.

[233]  M. Tsai Powder synthesis of nano grade cerium oxide via homogenous precipitation and its polishing performance , 2004 .

[234]  K. Mizuno,et al.  Pulmonary and systemic responses of highly pure and well-dispersed single-wall carbon nanotubes after intratracheal instillation in rats , 2011, Inhalation toxicology.

[235]  S. Chaudhuri,et al.  Synthesis and optical properties of nanometer to micrometer wide hexagonal cones and columns of ZnO , 2006 .

[236]  M. Hayashi,et al.  Genotoxicity evaluation of fullerene C60 nanoparticles in a comet assay using lung cells of intratracheally instilled rats. , 2012, Regulatory toxicology and pharmacology : RTP.

[237]  Bethany Halford,et al.  INSIGHTS: FULLERENE FOR THE FACECosmetics containing C nanoparticles are entering the market, even if their safety is unclear , 2006 .

[238]  N. Dadgostar Investigations on Colloidal Synthesis of Copper Nanoparticles in a Two-phase Liquid-liquid System , 2008 .

[239]  Hamed Daemi,et al.  Fast removal of malachite green dye using novel superparamagnetic sodium alginate-coated Fe3O4 nanoparticles. , 2014, International journal of biological macromolecules.

[240]  K. Cantrell,et al.  Zero-valent iron for the in situ remediation of selected metals in groundwater , 1995 .

[241]  Kristy Moniz,et al.  Monitoring the developmental impact of copper and silver nanoparticle exposure in Drosophila and their microbiomes. , 2014, The Science of the total environment.

[242]  Haifang Wang,et al.  Long-term accumulation and low toxicity of single-walled carbon nanotubes in intravenously exposed mice. , 2008, Toxicology letters.

[243]  Jun Yang,et al.  Cytotoxic and genotoxic effects of multi-wall carbon nanotubes on human umbilical vein endothelial cells in vitro. , 2011, Mutation research.

[244]  D. Vione,et al.  Behavior of Some Rheological Modifiers Used in Cosmetics Under Photocatalytic Conditions , 2003 .

[245]  D. Maysinger,et al.  Nanoparticles can induce changes in the intracellular metabolism of lipids without compromising cellular viability , 2009, The FEBS journal.

[246]  H. Schwarz,et al.  Cytotoxicity of single-wall carbon nanotubes on human fibroblasts. , 2006, Toxicology in vitro : an international journal published in association with BIBRA.

[247]  S. Bhatia,et al.  Probing the Cytotoxicity Of Semiconductor Quantum Dots. , 2004, Nano letters.

[248]  L. Qi,et al.  Wet Chemical Approaches to Patterned Arrays of Well-Aligned ZnO Nanopillars Assisted by Monolayer Colloidal Crystals , 2009 .

[249]  A. Afkhami,et al.  Removal, preconcentration and determination of Mo(VI) from water and wastewater samples using maghemite nanoparticles , 2009 .

[250]  Craig A. Poland,et al.  Carbon nanotubes introduced into the abdominal cavity of mice show asbestos-like pathogenicity in a pilot study. , 2008, Nature nanotechnology.

[251]  T. Ichihashi,et al.  Preferential Deposition of Pt Nanoparticles Inside Single‐Walled Carbon Nanohorns , 2004 .

[252]  Z. Chai,et al.  Acute toxicity and biodistribution of different sized titanium dioxide particles in mice after oral administration. , 2007, Toxicology letters.

[253]  S. Bachilo,et al.  Near-infrared fluorescence microscopy of single-walled carbon nanotubes in phagocytic cells. , 2004, Journal of the American Chemical Society.

[254]  J. Kanno,et al.  Induction of mesothelioma in p53+/- mouse by intraperitoneal application of multi-wall carbon nanotube. , 2008, The Journal of toxicological sciences.

[255]  Qing Huang,et al.  The acute pulmonary toxicity in mice induced by multiwall carbon nanotubes, benzene, and their combination , 2009, Environmental toxicology.

[256]  Xinhua Xu,et al.  Reduction of hexavalent chromium by carboxymethyl cellulose-stabilized zero-valent iron nanoparticles. , 2010, Journal of contaminant hydrology.

[257]  Haijiao Zhang,et al.  Nanosized zinc oxide particles induce neural stem cell apoptosis , 2009, Nanotechnology.

[258]  Baoshan Xing,et al.  Toxicity of nanoparticulate and bulk ZnO, Al2O3 and TiO2 to the nematode Caenorhabditis elegans. , 2009, Environmental pollution.

[259]  N. Miyata,et al.  Mutagenicity of the fullerene C60-generated singlet oxygen dependent formation of lipid peroxides. , 1996, Carcinogenesis.

[260]  H. Byrne,et al.  In vitro toxicity evaluation of single walled carbon nanotubes on human A549 lung cells. , 2007, Toxicology in vitro : an international journal published in association with BIBRA.

[261]  P. Grange,et al.  Influence of the Preparation Method On the V2o5/tio2/sio2 Catalysts in Selective Catalytic Reduction of Nitric-oxide With Ammonia , 1991 .

[262]  G. S. Shekhawat,et al.  Toxicity of ZnO engineered nanoparticles and evaluation of their effect on growth, metabolism and tissue specific accumulation in Brassica juncea , 2014 .

[263]  L. Fraceto,et al.  Toxicity assessment of TiO₂ nanoparticles in zebrafish embryos under different exposure conditions. , 2014, Aquatic toxicology.

[264]  Chao Liu,et al.  Comparative study of cytotoxicity, oxidative stress and genotoxicity induced by four typical nanomaterials: the role of particle size, shape and composition , 2009, Journal of applied toxicology : JAT.

[265]  M. Honma,et al.  In vitro clastogenicity and phototoxicity of fullerene (C(60)) nanomaterials in mammalian cells. , 2012, Mutation research.

[266]  Abdallah S. Daar,et al.  State of Academic Knowledge on Toxicity and Biological Fate of Quantum Dots , 2009, Toxicological sciences : an official journal of the Society of Toxicology.

[267]  Shigehisa Endoh,et al.  In vitro and in vivo genotoxicity tests on fullerene C60 nanoparticles. , 2009, Toxicology letters.

[268]  Jerzy Leszczynski,et al.  Advancing risk assessment of engineered nanomaterials: application of computational approaches. , 2012, Advanced drug delivery reviews.

[269]  Mirco Bundschuh,et al.  Size-, surface- and crystalline structure composition-related effects of titanium dioxide nanoparticles during their aquatic life cycle. , 2014, The Science of the total environment.

[270]  Pratim Biswas,et al.  Assessing the risks of manufactured nanomaterials. , 2006, Environmental science & technology.

[271]  Sophie Lanone,et al.  Biomedical applications and potential health risks of nanomaterials: molecular mechanisms. , 2006, Current molecular medicine.

[272]  K. J. Reddy,et al.  Adsorption of arsenic(III) and arsenic(V) by cupric oxide nanoparticles. , 2009, Journal of colloid and interface science.

[273]  S. Fukushima,et al.  Genotoxicity and Cytotoxicity of Multi‐wall Carbon Nanotubes in Cultured Chinese Hamster Lung Cells in Comparison with Chrysotile A Fibers , 2010, Journal of occupational health.

[274]  J. West,et al.  The Differential Cytotoxicity of Water-Soluble Fullerenes , 2004 .

[275]  M. Roberts,et al.  Grey Goo on the Skin? Nanotechnology, Cosmetic and Sunscreen Safety , 2007, Critical reviews in toxicology.

[276]  M. Moore,et al.  Do nanoparticles present ecotoxicological risks for the health of the aquatic environment? , 2006, Environment international.

[277]  W. Jin,et al.  Chemical vapor synthesis and characterization of chromium doped zinc oxide nanoparticles , 2007 .

[278]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[279]  G. Bae,et al.  Size response of an SMPS–APS system to commercial multi-walled carbon nanotubes , 2010 .

[280]  Keerti Jain,et al.  Alginate coated chitosan core shell nanoparticles for oral delivery of enoxaparin: in vitro and in vivo assessment. , 2013, International journal of pharmaceutics.

[281]  A. Roberts,et al.  Effects of suspended multi-walled carbon nanotubes on daphnid growth and reproduction. , 2011, Ecotoxicology and environmental safety.

[282]  Sandro Santucci,et al.  Effects of single and multi walled carbon nanotubes on macrophages: cyto and genotoxicity and electron microscopy. , 2011, Mutation research.

[283]  Jing Xu,et al.  In vitro toxicity of multi-walled carbon nanotubes in C6 rat glioma cells. , 2012, Neurotoxicology.

[284]  Tao Zhang,et al.  Comparison of cytotoxic and inflammatory responses of pristine and functionalized multi-walled carbon nanotubes in RAW 264.7 mouse macrophages. , 2012, Journal of hazardous materials.

[285]  V. Himabindu,et al.  Multi wall carbon nanotubes induce oxidative stress and cytotoxicity in human embryonic kidney (HEK293) cells. , 2010, Toxicology.

[286]  Uwe Pieles,et al.  Assessment of uptake and toxicity of fluorescent silica nanoparticles in zebrafish (Danio rerio) early life stages. , 2010, Aquatic toxicology.

[287]  Navid B. Saleh,et al.  Titanium dioxide (P25) produces reactive oxygen species in immortalized brain microglia (BV2): implications for nanoparticle neurotoxicity. , 2006, Environmental science & technology.

[288]  Xiaoshan Zhu,et al.  Acute toxicities of six manufactured nanomaterial suspensions to Daphnia magna , 2009 .

[289]  Katsuhiko Hirano,et al.  Effect of sonication on the photo-catalytic mineralization of some chlorinated organic compounds. , 2005, Ultrasonics sonochemistry.

[290]  X. L. Yang,et al.  Photo-induced cytotoxicity of malonic acid [C(60)]fullerene derivatives and its mechanism. , 2002, Toxicology in vitro : an international journal published in association with BIBRA.

[291]  Tim Liedl,et al.  Cytotoxicity of colloidal CdSe and CdSe/ZnS nanoparticles. , 2005, Nano letters.

[292]  S. Manna,et al.  Single-Walled Carbon Nanotube Induces Oxidative Stress and Activates Nuclear Transcription Factor-κB in Human Keratinocytes , 2005 .

[293]  Yan Li,et al.  Comparative toxicity of several metal oxide nanoparticle aqueous suspensions to Zebrafish (Danio rerio) early developmental stage , 2008, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[294]  Ivan P. Parkin,et al.  Self-cleaning coatings , 2005 .

[295]  D. Mcclements,et al.  Alterations in nanoparticle protein corona by biological surfactants: impact of bile salts on β-lactoglobulin-coated gold nanoparticles. , 2014, Journal of colloid and interface science.

[296]  Seong-Geun Oh,et al.  Preparation and antibacterial effects of Ag-SiO2 thin films by sol-gel method. , 2003, Biomaterials.

[297]  Maumita Bandyopadhyay,et al.  Multi-walled carbon nanotubes (MWCNT): induction of DNA damage in plant and mammalian cells. , 2011, Journal of hazardous materials.

[298]  J. Kumar,et al.  Sol–gel synthesis and anomalous magnetic behaviour of NiO nanoparticles , 2007 .

[299]  Mark Green,et al.  Semiconductor quantum dots and free radical induced DNA nicking. , 2005, Chemical communications.

[300]  R. Naidu,et al.  Removal of methyl orange from aqueous solution using bentonite-supported nanoscale zero-valent iron. , 2011, Journal of colloid and interface science.

[301]  Zhigang Hu,et al.  The sorption of acid dye onto chitosan nanoparticles , 2006 .

[302]  A. S. Luyt,et al.  Effect of maleic anhydride grafting and the presence of oxidized wax on the thermal and mechanical behaviour of LDPE/silica nanocomposites , 2010 .

[303]  M. Morandi,et al.  Nanoparticle‐induced platelet aggregation and vascular thrombosis , 2005, British journal of pharmacology.

[304]  Zhaopu Liu,et al.  The potential toxicity of copper nanoparticles and copper sulphate on juvenile Epinephelus coioides. , 2014, Aquatic toxicology.

[305]  I. Chung,et al.  Physiological and molecular level effects of silver nanoparticles exposure in rice (Oryza sativa L.) seedlings. , 2014, Chemosphere.

[306]  A. Khataee,et al.  Comparative photocatalytic degradation of two dyes on immobilized TiO2 nanoparticles: Effect of dye molecular structure and response surface approach , 2010 .

[307]  Hongjie Dai,et al.  Patterned growth of single-walled carbon nanotubes on full 4-inch wafers , 2001 .

[308]  Huaizhou Zhao,et al.  Size tailoring of ZnS nanoparticles synthesized in reverse micelles and recovered by compressed CO2 , 2004 .

[309]  T. Sheela,et al.  Kinetics and thermodynamics of cadmium and lead ions adsorption on NiO nanoparticles , 2012 .

[310]  G. Dotto,et al.  Biosorption of food dyes onto Spirulina platensis nanoparticles: equilibrium isotherm and thermodynamic analysis. , 2012, Bioresource technology.

[311]  E. Tombácz,et al.  Preparation and characterization of chondroitin-sulfate-A coated magnetite nanoparticles for biomedical applications , 2015 .

[312]  Jianmin Wang,et al.  Synergistic toxic effect of nano-TiO and As(V) on Ceriodaphnia dubia. , 2011, The Science of the total environment.

[313]  S. Kashiwada,et al.  Distribution of Nanoparticles in the See-through Medaka (Oryzias latipes) , 2006, Environmental health perspectives.

[314]  M. Scherer,et al.  Kinetics of nitrate, nitrite, and Cr(VI) reduction by iron metal. , 2002, Environmental science & technology.

[315]  George P Cobb,et al.  Effects of ZnO nanomaterials on Xenopus laevis growth and development. , 2011, Ecotoxicology and environmental safety.

[316]  X. Wen,et al.  Preparation of monodisperse magnetite nanoparticles under mild conditions , 2008 .

[317]  K. Schirmer,et al.  Evaluating the cytotoxicity of palladium/magnetite nano-catalysts intended for wastewater treatment. , 2010, Environmental pollution.

[318]  S. C. O'brien,et al.  C60: Buckminsterfullerene , 1985, Nature.

[319]  M. Umetsu,et al.  Hydrothermal synthesis of surface-modified iron oxide nanoparticles , 2007 .

[320]  Enrique Navarro,et al.  Toxicity of silver nanoparticles to Chlamydomonas reinhardtii. , 2008, Environmental science & technology.

[321]  Yang-Chuang Chang,et al.  Recovery of gold(III) ions by a chitosancoated magnetic nano-adsorbent , 2006 .

[322]  Á. Jos,et al.  Cytotoxicity of carboxylic acid functionalized single wall carbon nanotubes on the human intestinal cell line Caco-2. , 2009, Toxicology in vitro : an international journal published in association with BIBRA.

[323]  S. Doak,et al.  NanoGenotoxicology: the DNA damaging potential of engineered nanomaterials. , 2009, Biomaterials.

[324]  Nancy A Monteiro-Riviere,et al.  Endocytic mechanisms and toxicity of a functionalized fullerene in human cells. , 2009, Toxicology letters.

[325]  T. Webb,et al.  Comparative pulmonary toxicity assessment of single-wall carbon nanotubes in rats. , 2003, Toxicological sciences : an official journal of the Society of Toxicology.

[326]  Ruiqiang Liu,et al.  In situ immobilization of Cu(II) in soils using a new class of iron phosphate nanoparticles. , 2007, Chemosphere.

[327]  Isao Ikemoto,et al.  NMR characterization of isomers of C78, C82 and C84 fullerenes , 1992, Nature.

[328]  M. Drofenik,et al.  The synthesis of iron–nickel alloy nanoparticles using a reverse micelle technique , 2006 .

[329]  Yuliang Zhao,et al.  Cytotoxicity of carbon nanomaterials: single-wall nanotube, multi-wall nanotube, and fullerene. , 2005, Environmental science & technology.

[330]  Yu-Li Chen,et al.  A nearly pure monoclinic nanocrystalline zirconia , 2005 .

[331]  K. A. Matis,et al.  Removal of zinc ion from water by sorption onto iron-based nanoadsorbent. , 2007, Journal of hazardous materials.

[332]  S. Kaul,et al.  Nano‐adsorbents for the removal of metallic pollutants from water and wastewater , 2009, Environmental technology.

[333]  P. Lam,et al.  In vitro cytotoxicity testing of a nanocrystalline silver dressing (Acticoat) on cultured keratinocytes , 2004, British journal of biomedical science.

[334]  Yongxing Hu,et al.  Hierarchical magnetite/silica nanoassemblies as magnetically recoverable catalyst-supports. , 2008, Nano letters.

[335]  Richard D Handy,et al.  Toxicity of single walled carbon nanotubes to rainbow trout, (Oncorhynchus mykiss): respiratory toxicity, organ pathologies, and other physiological effects. , 2007, Aquatic toxicology.

[336]  A. Jebali,et al.  Triglyceride-coated nanoparticles: skin toxicity and effect of UV/IR irradiation on them. , 2013, Toxicology in vitro : an international journal published in association with BIBRA.

[337]  R. Rodríguez,et al.  Adsorption of lead ions in aqueous solution using silica-alumina nanoparticles , 2010 .

[338]  G. Meng,et al.  On the Growth of CdS Nanowires by the Evaporation of CdS Nanopowders , 2002 .

[339]  T. Saleh,et al.  Preparation and characterization of SnO2 nanoparticles using high power pulsed laser , 2010 .

[340]  Nickel oxide coated carbon nanoparticles as temperature sensing materials , 2014 .

[341]  R. Axelbaum,et al.  Gas-phase synthesis of single-walled carbon nanotubes on catalysts producing high yield , 2010 .

[342]  T. Gardner,et al.  Evaluation of Zinc Oxide Sorbents in a Pilot-Scale Transport Reactor: Sulfidation Kinetics and Reactor Modeling , 2004 .

[343]  Fu-hui Wang,et al.  Controlled synthesis of CuO nanoparticles using TritonX-100-based water-in-oil reverse micelles , 2008 .

[344]  H. Jeng,et al.  Toxicity of Metal Oxide Nanoparticles in Mammalian Cells , 2006, Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering.

[345]  Pilar Martín,et al.  Bioanalytical strategies for in-vitro and in-vivo evaluation of the toxicity induced by metallic nanoparticles , 2013 .

[346]  F. Zhang,et al.  Visible thermal emission from sub-band-gap laser excited cerium dioxide particles , 2002 .

[347]  Peter Wick,et al.  Effects of carbon nanotubes on primary neurons and glial cells. , 2009, Neurotoxicology.

[348]  Junko Nakanishi,et al.  Evaluation of dermal and eye irritation and skin sensitization due to carbon nanotubes. , 2011, Regulatory toxicology and pharmacology : RTP.

[349]  David W. Blowes,et al.  Reactive transport modeling of an in situ reactive barrier for the treatment of hexavalent chromium and trichloroethylene in groundwater , 2001 .

[350]  N. Verma,et al.  Photoluminescent properties of ZnS:Mn nanoparticles with in-built surfactant , 2008 .

[351]  Y. An,et al.  Effect of silver nanoparticles in crop plants Phaseolus radiatus and Sorghum bicolor: media effect on phytotoxicity. , 2012, Chemosphere.

[352]  Xiaoke Hu,et al.  ZnO nanoparticles induced cytotoxicity on human pulmonary adenocarcinoma cell line LTEP-a-2 , 2015 .

[353]  Robert N Grass,et al.  Oxide nanoparticle uptake in human lung fibroblasts: effects of particle size, agglomeration, and diffusion at low concentrations. , 2005, Environmental science & technology.

[354]  A. Massè,et al.  Silver coated materials for external fixation devices: in vitro biocompatibility and genotoxicity. , 2002, Biomaterials.

[355]  Sukran Seker,et al.  In vitro cytotoxicity of hydrothermally synthesized ZnO nanoparticles on human periodontal ligament fibroblast and mouse dermal fibroblast cells. , 2014, Toxicology in vitro : an international journal published in association with BIBRA.

[356]  T. Akiyama,et al.  Combustion synthesis of TiO2 nanoparticles as photocatalyst , 2007 .

[357]  J. Gearhart,et al.  In vitro toxicity of nanoparticles in BRL 3A rat liver cells. , 2005, Toxicology in vitro : an international journal published in association with BIBRA.

[358]  Nicole Grobert,et al.  Carbon nanotubes – becoming clean , 2007 .

[359]  M. Salavati‐Niasari,et al.  Synthesis and characterization of metallic copper nanoparticles via thermal decomposition , 2008 .

[360]  Wei-xian Zhang,et al.  Synthesizing Nanoscale Iron Particles for Rapid and Complete Dechlorination of TCE and PCBs , 1997 .

[361]  T. Tsuchiya,et al.  Novel harmful effects of [60]fullerene on mouse embryos in vitro and in vivo , 1996, FEBS letters.

[362]  Amar K Mohanty,et al.  Single-walled carbon nanotubes dispersed in aqueous media via non-covalent functionalization: effect of dispersant on the stability, cytotoxicity, and epigenetic toxicity of nanotube suspensions. , 2010, Water research.

[363]  J. West,et al.  Correlating nanoscale titania structure with toxicity: a cytotoxicity and inflammatory response study with human dermal fibroblasts and human lung epithelial cells. , 2006, Toxicological sciences : an official journal of the Society of Toxicology.

[364]  Haijuan Yan,et al.  In vitro cytotoxicity of monodispersed hematite nanoparticles on Hek 293 cells , 2011 .

[365]  M. Zawrah,et al.  Synthesis andcharacterisation of nanocrystalline MgAl2O4 ceramic powders by use of molten salts , 2002 .

[366]  S. Seena,et al.  Copper oxide nanoparticles can induce toxicity to the freshwater shredder Allogamus ligonifer. , 2012, Chemosphere.

[367]  Rebecca Klaper,et al.  Daphnia magna mortality when exposed to titanium dioxide and fullerene (C60) nanoparticles , 2006, Environmental toxicology and chemistry.

[368]  G Chambers,et al.  Single walled carbon nanotubes induce indirect cytotoxicity by medium depletion in A549 lung cells. , 2008, Toxicology letters.

[369]  P. Krogh,et al.  The toxicity testing of double-walled nanotubes-contaminated food to Eisenia veneta earthworms. , 2008, Ecotoxicology and environmental safety.

[370]  K. A. Matis,et al.  Sorption of Cd ions onto akaganéite-type nanocrystals , 2005 .

[371]  S. Pawar,et al.  Water dispersible oleic acid-coated Fe3O4 nanoparticles for biomedical applications , 2015 .

[372]  Baoshan Xing,et al.  Phytotoxicity of nanoparticles: inhibition of seed germination and root growth. , 2007, Environmental pollution.

[373]  Gerhard Kasper,et al.  In-vitro cell exposure studies for the assessment of nanoparticle toxicity in the lung - A dialog between aerosol science and biology , 2011 .

[374]  Jinxue Guo,et al.  Dependence of the cytotoxicity of multi-walled carbon nanotubes on the culture medium , 2006, Nanotechnology.

[375]  M. Gremião,et al.  Preparation and characterization of PEG-coated silica nanoparticles for oral insulin delivery. , 2014, International journal of pharmaceutics.

[376]  Rebecca Klaper,et al.  Behavioral and physiological changes in Daphnia magna when exposed to nanoparticle suspensions (titanium dioxide, nano-C60, and C60HxC70Hx). , 2007, Environmental science & technology.

[377]  M. Camatini,et al.  Nickel oxide nanoparticles induce inflammation and genotoxic effect in lung epithelial cells. , 2014, Toxicology letters.

[378]  W. N. Chen,et al.  Cytotoxicity of single-walled carbon nanotubes on human hepatoma HepG2 cells: an iTRAQ-coupled 2D LC-MS/MS proteome analysis. , 2011, Toxicology in vitro : an international journal published in association with BIBRA.

[379]  H. Ohkita,et al.  Organic–inorganic hybrid solar cells based on conducting polymer and SnO2 nanoparticles chemically modified with a fullerene derivative , 2007 .

[380]  G. Jiang,et al.  Removal of fluoride from aqueous media by Fe3O4@Al(OH)3 magnetic nanoparticles. , 2010, Journal of hazardous materials.

[381]  Xiaoyan Zou,et al.  Endothelial cell injury and dysfunction induced by silver nanoparticles through oxidative stress via IKK/NF-κB pathways. , 2014, Biomaterials.

[382]  S. Luo,et al.  Fabrication of CdSe Nanoparticles Sensitized Long TiO2 Nanotube Arrays for Photocatalytic Degradation of Anthracene-9-carbonxylic Acid under Green Monochromatic Light , 2010 .

[383]  Biao Yan,et al.  Preparation and magnetic properties of magnetite nanoparticles by sol-gel method , 2010, 2010 3rd International Nanoelectronics Conference (INEC).

[384]  Feng Zhao,et al.  Bio-distribution and metabolic paths of silica coated CdSeS quantum dots. , 2008, Toxicology and applied pharmacology.

[385]  R Tardif,et al.  Effects of inhaled nano-TiO2 aerosols showing two distinct agglomeration states on rat lungs. , 2012, Toxicology letters.

[386]  Pengfei Wu,et al.  Photonic Crystals Based on Periodic Arrays of Aligned Carbon Nanotubes , 2003 .

[387]  Minnamari Vippola,et al.  Genotoxicity of nanomaterials: DNA damage and micronuclei induced by carbon nanotubes and graphite nanofibres in human bronchial epithelial cells in vitro. , 2009, Toxicology letters.

[388]  X. Xia,et al.  Carbon-coated SnSb nanoparticles dispersed in reticular structured nanofibers for lithium-ion battery anodes , 2015 .

[389]  M. Johnson,et al.  Fullerenes C60 and C70 in flames , 1991, Nature.

[390]  Shuk Han Cheng,et al.  Acute and long-term effects after single loading of functionalized multi-walled carbon nanotubes into zebrafish (Danio rerio). , 2009, Toxicology and applied pharmacology.

[391]  Yongsheng Chen,et al.  Pyrolytic carbon-coated Si nanoparticles on elastic graphene framework as anode materials for high-performance lithium-ion batteries , 2015 .

[392]  G. Rivas,et al.  Carbon nanotubes for electrochemical biosensing. , 2007, Talanta.

[393]  Qilin Yu,et al.  A novel toxicity mechanism of CdSe nanoparticles to Saccharomyces cerevisiae: enhancement of vacuolar membrane permeabilization (VMP). , 2014, Chemico-biological interactions.

[394]  Xiaoqing Cai,et al.  The interaction and toxicity of multi-walled carbon nanotubes with Stylonychia mytilus. , 2006, Journal of nanoscience and nanotechnology.

[395]  P. Wust,et al.  Magnetic fluid hyperthermia (MFH): Cancer treatment with AC magnetic field induced excitation of biocompatible superparamagnetic nanoparticles , 1999 .

[396]  J. Kiwi,et al.  Synthesis, activity and characterization of textiles showing self-cleaning activity under daylight irradiation , 2007 .

[397]  A. Ceylan,et al.  Synthesis and magnetic properties of cobalt ferrite (CoFe2O4) nanoparticles prepared by wet chemical route , 2006, cond-mat/0606631.

[398]  J. Kong,et al.  Novel magnetic Fe3O4@C nanoparticles as adsorbents for removal of organic dyes from aqueous solution. , 2011, Journal of hazardous materials.

[399]  H. Iwahashi,et al.  Gene expression profiles in rat lung after inhalation exposure to C60 fullerene particles. , 2009, Toxicology.

[400]  Jose R Peralta-Videa,et al.  Nanomaterials and the environment: a review for the biennium 2008-2010. , 2011, Journal of hazardous materials.

[401]  A. G. Mamalis Recent advances in nanotechnology , 2007 .

[402]  Zhen Yao,et al.  Carbon nanotube intramolecular junctions , 1999, Nature.

[403]  Robert N Grass,et al.  In vitro cytotoxicity of oxide nanoparticles: comparison to asbestos, silica, and the effect of particle solubility. , 2006, Environmental science & technology.

[404]  David B Warheit,et al.  Assessing toxicity of fine and nanoparticles: comparing in vitro measurements to in vivo pulmonary toxicity profiles. , 2007, Toxicological sciences : an official journal of the Society of Toxicology.

[405]  B. Lehnert,et al.  Correlation between particle size, in vivo particle persistence, and lung injury. , 1994, Environmental health perspectives.

[406]  Patrizia Santi,et al.  Toxicity of antimony trioxide nanoparticles on human hematopoietic progenitor cells and comparison to cell lines. , 2009, Toxicology.

[407]  R. Nemanich,et al.  Multi-walled carbon nanotube interactions with human epidermal keratinocytes. , 2005, Toxicology letters.

[408]  Yunqing Kang,et al.  Toxicological effect of ZnO nanoparticles based on bacteria. , 2008, Langmuir : the ACS journal of surfaces and colloids.

[409]  Benjamin G Keselowsky,et al.  Contributions of surface topography and cytotoxicity to the macrophage response to zinc oxide nanorods. , 2010, Biomaterials.

[410]  Wojciech Zareba,et al.  Comparing Inhaled Ultrafine vs. Fine Zinc Oxide Particles in Healthy Adults: a Human Inhalation Study , 2022 .

[411]  J. Mittal,et al.  Oxidative damage induced by the fullerene C60 on photosensitization in rat liver microsomes. , 1998, Chemico-biological interactions.

[412]  Pedro J J Alvarez,et al.  Comparative eco-toxicity of nanoscale TiO2, SiO2, and ZnO water suspensions. , 2006, Water research.

[413]  Kerstin Hund-Rinke,et al.  Ecotoxic Effect of Photocatalytic Active Nanoparticles (TiO2) on Algae and Daphnids (8 pp) , 2006, Environmental science and pollution research international.

[414]  Liping Wei,et al.  Cytotoxicity effects of water dispersible oxidized multiwalled carbon nanotubes on marine alga, Dunaliella tertiolecta. , 2010, Aquatic toxicology.

[415]  A. Das,et al.  Free-flowing, transparent γ-alumina nanoparticles synthesized by a supersonic thermal plasma expansion process , 2012 .

[416]  Robert A Hoke,et al.  Development of a base set of toxicity tests using ultrafine TiO2 particles as a component of nanoparticle risk management. , 2007, Toxicology letters.

[417]  Frank A Witzmann,et al.  Multi-walled carbon nanotube exposure alters protein expression in human keratinocytes. , 2006, Nanomedicine : nanotechnology, biology, and medicine.