Using pollution roses to assess sulfur dioxide impacts in a township downwind of a petrochemical complex

This study used pollution roses to assess sulfur dioxide (SO2) pollution in a township downwind of a large petrochemical complex based on data collected from a single air quality monitoring station. The pollution roses summarized hourly SO2 concentrations at the Taishi air quality monitoring station, located approximately 7.8–13.0 km south of the No. 6 Naphtha Cracking Complex in Taiwan, according to 36 sectors of wind direction during the preoperational period (1995–1999) and two postoperational periods (2000–2004 and 2005–2009). The 99th percentile of hourly SO2 concentrations 350˚ downwind from the complex increased from 28.9 ppb in the preoperational period to 86.2–324.2 ppb in the two postoperational periods. Downwind SO2 concentrations were particularly high during 2005–2009 at wind speeds of 6–8 m/sec. Hourly SO2 levels exceeded the U.S. Environmental Protection Agency (EPA) health-based standard of 75 ppb only in the postoperational periods, with 65 exceedances from 0–10˚ and 330–350˚ downwind directions during 2001–2009. This study concluded that pollution roses based on a single monitoring station can be used to investigate source contributions to air pollution surrounding industrial complexes, and that it is useful to combine such directional methods with analyses of how pollution varies between different wind speeds, times of day, and periods of industrial development. Implications: The pollution roses summarize SO2 concentrations by wind direction and to investigate source contribution to air quality. Percentile statistics can catch pollution episodes occurring in a very short time at specific wind directions and speeds. The downwind areas have already exceeded regulated 1-hr SO2 standard since the operation of the complex.

[1]  Gang Zeng,et al.  Divergent growth trajectories in China’s chemical industry: the case of the newly developed industrial parks in Shanghai, Nanjing and Ningbo , 2011 .

[2]  Ruei-Hao Shie,et al.  Urinary levels of 1-hydroxypyrene in children residing near a coal-fired power plant. , 2011, Environmental research.

[3]  J. Ondov,et al.  Application of EPA unmix and nonparametric wind regression on high time resolution trace elements and speciated mercury in Tampa, Florida aerosol. , 2011, Environmental science & technology.

[4]  Alan M. Jones,et al.  Temporal trends in sulphate concentrations at European sites and relationships to sulphur dioxide , 2011 .

[5]  P. Baltrėnas,et al.  Atmospheric BTEX concentrations in the vicinity of the crude oil refinery of the Baltic region , 2011, Environmental monitoring and assessment.

[6]  Kitikorn Charmondusit,et al.  Eco-efficiency evaluation of the petroleum and petrochemical group in the map Ta Phut Industrial Estate, Thailand , 2011 .

[7]  Z. Yumurtacı,et al.  Emissions estimation for lignite-fired power plants in Turkey , 2010 .

[8]  N. Castell,et al.  Photochemical model evaluation of the surface ozone impact of a power plant in a heavily industrialized area of southwestern Spain. , 2010, Journal of environmental management.

[9]  B. Wiens,et al.  Ambient air total gaseous mercury concentrations in the vicinity of coal-fired power plants in Alberta, Canada. , 2009, The Science of the total environment.

[10]  U. Akhtar,et al.  Identification of potential regional sources of atmospheric total gaseous mercury in Windsor, Ontario, Canada using hybrid receptor modeling , 2009 .

[11]  B. Armstrong,et al.  Risk of Asthmatic Episodes in Children Exposed to Sulfur Dioxide Stack Emissions from a Refinery Point Source in Montreal, Canada , 2008, Environmental health perspectives.

[12]  X. Querol,et al.  Identification of FCC refinery atmospheric pollution events using lanthanoid- and vanadium-bearing aerosols , 2008 .

[13]  C. Mensink,et al.  Pollutant roses for daily averaged ambient air pollutant concentrations , 2008 .

[14]  Kang-Tsung Chang,et al.  A comparative case study of cultivated land changes in Fujian and Taiwan , 2007 .

[15]  R. Maronna,et al.  Study of Meteorological Aspects and Urban Concentration of SO2 in Atmospheric Environment of La Plata, Argentina , 2006, Environmental monitoring and assessment.

[16]  X. Querol,et al.  Controlling influences on daily fluctuations of inhalable particles and gas concentrations: Local versus regional and exotic atmospheric pollutants at Puertollano, Spain , 2006 .

[17]  Ruei-Hao Shie,et al.  Workers’ exposures and potential health risks to air toxics in a petrochemical complex assessed by improved methodology , 2006, International archives of occupational and environmental health.

[18]  Eylem Çetin,et al.  Ambient volatile organic compound (VOC) concentrations around a petrochemical complex and a petroleum refinery. , 2003, The Science of the total environment.

[19]  Tae-gu Kim,et al.  Current risk management status of the Korean petrochemical industry , 2002 .

[20]  W. Parkhurst,et al.  Rates of Conversion of Sulfur Dioxide to Sulfate in a Scrubbed Power Plant Plume , 2001, Journal of the Air & Waste Management Association.

[21]  J. Hwang,et al.  Adverse effect of air pollution on respiratory health of primary school children in Taiwan. , 1998, Environmental health perspectives.

[22]  Jing-Shiang Hwang,et al.  Respiratory symptoms of primary school children living in a petrochemical polluted area in Taiwan , 1998, Pediatric pulmonology.

[23]  C. -. Yang,et al.  Respiratory and irritant health effects of a population living in a petrochemical-polluted area in Taiwan. , 1998, Environmental research.

[24]  Jing-Shiang Hwang,et al.  Receptor modeling of VOCs, CO, NOx, and THC in Taipei , 1996 .