Development of UV/VIS spectrometric methodology for corrosion inhibitor residuals monitoring in oilfield brine

This work focuses on the development of UV/VIS spectrometric methodology for corrosion inhibitor residuals monitoring in oilfield brine. There is no standard method for the determination of corrosion inhibitor concentration in oilfield brine. Developed methodology can be described as a rugged and simple alternative to the sophisticate separation techniques and can be easily applied in the field. The applicability of the method is demonstrated by the analyses of three commercial products. The extensive performance characteristics test, in combination with study and quantification of measurement uncertainty, shows that developed method meets all required criteria and can be directly applied for routine monitoring purposes within quality management system conditions. Therefore, this new method was accredited by the respectable accreditation agency. Valid and reliable determination of corrosion inhibitor residuals in oilfield brine is important in order to ensure effective corrosion protection of metal construction.

[1]  L. Monser,et al.  Liquid chromatographic determination of methylamines. Determination of trimethylamine in fish samples using a porous graphitic carbon stationary phase , 1996 .

[2]  S. Rowland,et al.  Liquid chromatography/electrospray ionisation mass spectrometric investigations of imidazoline corrosion inhibitors in crude oils. , 2002, Rapid communications in mass spectrometry : RCM.

[3]  V. S. Gaind,et al.  Quantification of Solid Sorbent-Sampled Airborne Aliphatic Polyamines on HPLC using a Common Calibration Standard -Application of the Concept of Isolation of a Selected n-System of a Derivative for Specific Detection , 1992 .

[4]  J. Riviello,et al.  Capillary electrophoresis of inorganic cations and low-molecular-mass amines using a copper-based electrolyte with indirect UV detection , 1993 .

[5]  T. Tsuda,et al.  Polyamine determination in clinical laboratories by high-performance liquid chromatography , 1990 .

[6]  G. Arliguie,et al.  Detection or quantitative analysis of a corrosion inhibitor, the sodium monofluorophosphate, in concrete , 2005 .

[7]  John R. Stillian,et al.  Ion Chromatography of Monovalent and Divalent Cations , 1989 .

[8]  P. Jandera,et al.  Comparison of Various Sorbents for the Enrichment of Samples of Aliphatic Amines Using Solid-Phase Extraction Prior to the Determination by HPLC with Fluorimetric Detection , 1994 .

[9]  O. Busto,et al.  Improvement of a solid-phase extraction method for determining biogenic amines in wines , 1995 .

[10]  T. Teerlink,et al.  Determination of dimethylamine in biological samples by high-performance liquid chromatography. , 1997, Journal of chromatography. B, Biomedical sciences and applications.

[11]  R. Kadnar,et al.  Determination of inorganic corrosion inhibitors in heat transfer systems by ion chromatography. , 2003, Journal of chromatography. A.

[12]  H. Schulz,et al.  Determination of polyamines in biological materials by HPLC with 9-fluorenylmethyl chloroformate precolumn derivatization , 1995 .

[13]  F. Sacher,et al.  Analysis of primary and secondary aliphatic amines in waste water and surface water by gas chromatography-mass spectrometry after derivatization with 2,4-dinitrofluorobenzene or benzenesulfonyl chloride , 1997 .

[14]  P. Blanco,et al.  Determination of dimethylamine in groundwater by liquid chromatography and precolumn derivatization with 9-fluorenylmethylchloroformate , 1996 .

[15]  R. Lindahl,et al.  Determination of volatile amines in air by diffusive sampling, thiourea formation and high-performance liquid chromatography , 1993 .

[16]  J. Pawliszyn,et al.  Determination of amines in air and water using derivatization combined with solid-phase microextraction , 1997 .

[17]  J. R. Larson,et al.  Determination of alkyl quaternary ammonium compounds by liquid chromatography with indirect photometric detection , 1983 .

[18]  I. Pucić,et al.  PIXE Spectroscopy for Determination of Volatile Corrosion Inhibitor Concentration in Anticorrosion Polymer Films , 2006 .

[19]  S. Abidi Speciation of aryloxyethoxyethyl benzyl dimethyl ammonium salts by glass capillary gas chromatography and high-performance liquid chromatography , 1981 .

[20]  Y. Mori,et al.  Enantiomeric separations of primary amino compounds by nonaqueous capillary zone electrophoresis with a chiral crown ether , 1997 .

[21]  Maria Rosa Miracle,et al.  Determination of biogenic amines in wines by high-performance liquid chromatography with on-column fluorescence derivatization , 1997 .

[22]  B. Kersten Ion chromatography of polyhydroxy aliphatic amines of pharmaceutical interest , 1992 .

[23]  K. Altria,et al.  Separation of a range of cations by nonaqueous capillary electrophoresis using indirect and direct detection. , 1998, Journal of chromatography. B, Biomedical sciences and applications.

[24]  C. Fu,et al.  High-performance liquid chromatography with post-column chemiluminescence detection for simultaneous determination of trace N-nitrosamines and corresponding secondary amines in groundwater , 1995 .

[25]  H. Engelhardt,et al.  Capillary electrophoresis of organic and inorganic cations with indirect UV detection , 1992 .

[26]  W. H. Matchett,et al.  Preconcentration of Aliphatic Amines from Water Determined by Capillary Electrophoresis with Indirect UV Detection , 1997 .