Optical Oxygen Sensing Based on the Luminescence Quenching of Europium(III) Complex Immobilized in Fluoropolymer Film

New optical oxygen sensors based on the luminescence intensities of four different europium(III) complexes, ((1,10-phenanthroline)tris(thenoyltrifluoroacetonato)europium(III) complex ([Eu(tta)3phen]), tris(thenoyltrifluoroacetonato)europium(III) dihydrate ([Eu(tta)3]·2H2O), tris(1,1,1-trifluoro-5,5-dimethyl-2,4-hexanedionato)europium(III) complex ([Eu(pta)3]·2H2O) and tris(1,1,1,2,2,3,3-heptafluoro-7,7-dimethyl-4,6-octanedionato)europium(III) complex ([Eu(fod)3]·2H2O)) immobilized in poly(styrene-co-2,2,2-trifluoroethyl methacrylate) (poly-(styrene-co-TFEM)) films were developed. The luminescence intensity of the europium(III) complex films decreased with increasing the oxygen concentration. Stern-Volmer plots of the europium(III) complex films exhibited considerable linearity. The KSV values of [Eu(tta)3phen], [Eu(tta)3]·2H2O, [Eu(pta)3]·2H2O and [Eu(fod)3]·2H2O in films were estimated to be 0.015, 0.005, 0.002 and 0.003 %-1, respectively. The large KSV value of the [Eu(tta)3phen] film was obtained compa...

[1]  W. A. Zisman,et al.  Relation of the Equilibrium Contact Angle to Liquid and Solid Constitution , 1964 .

[2]  Maurice W. Windsor,et al.  Luminescence and Energy Transfer in Solutions of Rare‐Earth Complexes. I. Enhancement of Fluorescence by Deuterium Substitution , 1965 .

[3]  John Olmsted,et al.  Oxygen quenching of fluorescence of organic dye molecules , 1974 .

[4]  R. Felder,et al.  Selective permeation of hydrocarbon gases in poly(tetrafluoroethylene) and poly(fluoroethylene–propylene) copolymer , 1980 .

[5]  W. Rudolf Seitz,et al.  AN OXYGEN PROBE BASED ON TETRAKIS ALKYL AMINOETHYLENE CHEMILUMINESCENCE1 , 1981 .

[6]  H. Marsoner,et al.  A fluorescence-based sterilizable oxygen probe for use in bioreactors☆ , 1983 .

[7]  R. J. Hurtubise,et al.  A study of the interactions of benzo[f]quinoline, quinoline and phenanthrene by infrared and reflectance spectroscopy and the relationship to room-temperature phosphorescence , 1983 .

[8]  E. Bechara,et al.  Ruthenium(II) tris(bipyridyl) ion as a luminescent probe for oxygen uptake. , 1986, Analytical biochemistry.

[9]  W. Seitz,et al.  Luminescence ratio indicators for oxygen , 1987 .

[10]  J. Vanderkooi,et al.  An optical method for measurement of dioxygen concentration based upon quenching of phosphorescence. , 1987, The Journal of biological chemistry.

[11]  James N. Demas,et al.  Determination of oxygen concentrations by luminescence quenching of a polymer-immobilized transition-metal complex , 1987 .

[12]  Otto S. Wolfbeis,et al.  Fiberoptic Oxygen Sensor Based on Fluorescence Quenching and Energy Transfer , 1988 .

[13]  Benjamin A. DeGraff,et al.  Luminescence quenching mechanism for microheterogeneous systems , 1991 .

[14]  Kowk-Yin Wong,et al.  Luminescent platinum complex in solid films for optical sensing of oxygen , 1992 .

[15]  J. Demas,et al.  Design of oxygen sensors based on quenching of luminescent metal complexes : effect of ligand size on heterogeneity , 1993 .

[16]  Daniel J. Bartnik,et al.  Performance and use of paracorporeal fiber optic blood gas sensors , 1994, Photonics West - Lasers and Applications in Science and Engineering.

[17]  Ingo Klimant,et al.  Optical Fiber Sensor for Biological Oxygen Demand , 1994 .

[18]  H. M. Widmer,et al.  Fiber optic sensor for oxygen determination in liquids , 1994 .

[19]  Toru Ishiji,et al.  Photoluminescence of pyrenebutyric acid incorporated into silicone film as a technique in luminescent oxygen sensing , 1995 .

[20]  E. Terrill,et al.  A micro-hole potentiostatic oxygen sensor for oceanic CTDs , 1995 .

[21]  Gelii V. Ponomarev,et al.  Phosphorescent Complexes of Porphyrin Ketones: Optical Properties and Application to Oxygen Sensing , 1995 .

[22]  Max E. Lippitsch,et al.  Luminescence Quenching Behavior of an Oxygen Sensor Based on a Ru(II) Complex Dissolved in Polystyrene , 1995 .

[23]  J. Demas,et al.  Oxygen sensors based on luminescence quenching: interactions of pyrene with the polymer supports. , 1995, Analytical chemistry.

[24]  J. Demas,et al.  Oxygen sensors based on luminescence quenching of metal complexes:  osmium complexes suitable for laser diode excitation. , 1996, Analytical chemistry.

[25]  A. Lepre,et al.  Controlling the Response Characteristics of Luminescent Porphyrin Plastic Film Sensors for Oxygen , 1997 .

[26]  S. Tsutsumi,et al.  Luminescence properties of lanthanide complexes incorporated into sol-gel derived inorganic-organic composite materials , 1998 .

[27]  G. Adachi,et al.  Preparation and Luminescence Properties of Organically Modified Silicate Composite Phosphors Doped with an Europium(III) β-Diketonate Complex , 1999 .

[28]  L. B. Zinner,et al.  Luminescence and structure of europium compounds , 2010 .

[29]  R. Longo,et al.  Spectroscopic properties and design of highly luminescent lanthanide coordination complexes , 2000 .