Aeolian Dust Preserved in the Guliya Ice Cap (Northwestern Tibet): A Promising Paleo-Environmental Messenger

Asian aeolian dust is a primary factor in Northern Hemisphere atmospheric dynamics. Predicting past and future changes in atmospheric circulation patterns relies in part on sound knowledge of Central Asian dust properties and the dust cycle. Unfortunately for that region, data are too sparse to constrain the variation in dust composition over time. Here, we evaluate the potential of a Tibetan ice core to provide a comprehensive paleo-atmospheric dust record and thereby reduce uncertainties regarding mineral aerosols’ feedback on the climate system. We present the first datasets of the mineralogical, geochemical, and Sr-Nd isotope composition of aeolian dust preserved in pre-Holocene layers of two ice cores from the Guliya ice cap (Kunlun Mountains). The composition of samples from the Summit (GS; 6710 m a.s.l.) and Plateau (GP; 6200 m a.s.l.) cores reveals that the characteristics of the dust in the cores’ deepest ice layers are significantly different. The deepest GS layers reveal isotopic values that correspond to aeolian particles from the Taklimakan desert, contain a mix of fine and coarse grains, and include weathering-sensitive material suggestive of a dry climate at the source. The deep GP layers primarily consist of unusual nodules of well size-sorted grey clay enriched in weathering-resistant minerals and elements typically found in geothermal waters, suggesting that the dust preserved in the oldest GP layers originates from a wet and possibly anoxic source. The variability of the dust composition highlighted here attests to its relevance as a paleo-environmental messenger and warrants further exploration of the particularly heterogenous Guliya glacial dust archive.

[1]  P. Formenti,et al.  Greenland Ice Core Record of Last Glacial Dust Sources and Atmospheric Circulation , 2022, Journal of geophysical research. Atmospheres : JGR.

[2]  C. Yi,et al.  Extensive glaciations between MIS 8 and MIS 5 on the eastern side of the Guliya ice cap, West Kunlun Mountains , 2021, Quaternary International.

[3]  E. Mosley‐Thompson,et al.  Glacier ice archives nearly 15,000-year-old microbes and phages , 2021, Microbiome.

[4]  Shi-chang Kang,et al.  Hf-Nd-Sr Isotopic Composition of the Tibetan Plateau Dust as a Fingerprint for Regional to Hemispherical Transport. , 2021, Environmental science & technology.

[5]  Ashwini Kumar,et al.  Geochemical characterization of modern aeolian dust over the Northeastern Arabian Sea: Implication for dust transport in the Arabian Sea. , 2020, The Science of the total environment.

[6]  Shi-chang Kang,et al.  Hf-Nd-Sr isotopic fingerprinting for aeolian dust deposited on glaciers in the northeastern Tibetan Plateau region , 2019, Global and Planetary Change.

[7]  C. Barbante Variations of trace elements and rare earth elements (REEs) treated by two different methods for snow-pit samples on the Qinghai-Tibetan Plateau and their implications , 2018 .

[8]  G. McTainsh,et al.  Palaeo-dust records: A window to understanding past environments , 2018, Global and Planetary Change.

[9]  E. Mosley‐Thompson,et al.  Ice core records of climate variability on the Third Pole with emphasis on the Guliya ice cap, western Kunlun Mountains , 2018 .

[10]  L. Thompson,et al.  Atmospheric depositions of natural and anthropogenic trace elements on the Guliya ice cap (northwestern Tibetan Plateau) during the last 340 years , 2018 .

[11]  Paolo Gabrielli,et al.  Central Tibetan Plateau atmospheric trace metals contamination: A 500-year record from the Puruogangri ice core. , 2017, The Science of the total environment.

[12]  J. Kovács,et al.  Coupled European and Greenland last glacial dust activity driven by North Atlantic climate , 2017, Proceedings of the National Academy of Sciences.

[13]  G. Baccolo,et al.  Causes of dust size variability in central East Antarctica (Dome B):Atmospheric transport from expanded South American sources during Marine Isotope Stage 2 , 2017 .

[14]  G. Baccolo,et al.  Dust composition changes from Taylor Glacier (East Antarctica) during the last glacial-interglacial transition: A multi-proxy approach , 2017 .

[15]  Zhi Guo,et al.  Geochemical evidence for sources of surface dust deposited on the Laohugou glacier, Qilian Mountains , 2017 .

[16]  P. Gabrielli,et al.  The impact of glacier retreat from the Ross Sea on local climate: Characterization of mineral dust in the Taylor Dome ice core, East Antarctica , 2016 .

[17]  J. Kovács,et al.  Two possible source regions for central Greenland last glacial dust , 2015 .

[18]  S. Behera,et al.  Clay and clay minerals for fluoride removal from water: A state-of-the-art review , 2015 .

[19]  J. Tison,et al.  Retrieving the paleoclimatic signal from the deeper part of the EPICA Dome C ice core , 2015 .

[20]  L. Borgnino,et al.  CHAPTER 1:Fluoride in the Context of the Environment , 2015 .

[21]  C. Xiao,et al.  Geochemical characteristics of insoluble dust as a tracer in an ice core from Miaoergou Glacier, east Tien Shan , 2015 .

[22]  L. Thompson,et al.  Large variability of trace element mass fractions determined by ICP-SFMS in ice core samples from worldwide high altitude glaciers , 2014 .

[23]  A. Carroll,et al.  Controls on Sr isotopic evolution in lacustrine systems: Eocene green river formation, Wyoming , 2014 .

[24]  Yun Li,et al.  Distribution and composition of loess sediments in the Ili Basin, Central Asia , 2014 .

[25]  Andrew Sturman,et al.  The global distribution of mineral dust and its impacts on the climate system: A review , 2014 .

[26]  A. Huang,et al.  The impact of the winter North Atlantic Oscillation on the frequency of spring dust storms over Tarim Basin in northwest China in the past half-century , 2013 .

[27]  J. K. Tripathi,et al.  Nd and Sr isotope characteristics of Quaternary Indo-Gangetic plain sediments: Source distinctiveness in different geographic regions and its geological significance , 2013 .

[28]  Jun Chen,et al.  Geothermal constraints on enrichment of boron and lithium in salt lakes: An example from a river-salt lake system on the northern slope of the eastern Kunlun Mountains, China , 2012 .

[29]  Bernd Kahn,et al.  Long-term selective retention of natural Cs and Rb by highly weathered coastal plain soils. , 2012, Environmental science & technology.

[30]  H. Saini,et al.  Depositional history and palaeoclimatic variations at the northeastern fringe of Thar Desert, Haryana plains, India , 2012 .

[31]  M. Ferrat,et al.  Improved provenance tracing of Asian dust sources using rare earth elements and selected trace elements for palaeomonsoon studies on the eastern Tibetan Plateau , 2011 .

[32]  L. Gu,et al.  A topaz- and amazonite-bearing leucogranite pluton in eastern Xinjiang, NW China and its zoning , 2011 .

[33]  Gaojun Li,et al.  Geochemical studies on the source region of Asian dust , 2011 .

[34]  T. Yao,et al.  Sr and Nd isotopic composition of dust in Dunde ice core, Northern China: Implications for source tracing and use as an analogue of long-range transported Asian dust , 2010 .

[35]  X. Fang,et al.  A rock magnetic study of loess from the West Kunlun Mountains , 2010 .

[36]  Vicki H. Grassian,et al.  Interactions between Mineral Dust, Climate, and Ocean Ecosystems , 2010 .

[37]  T. Stocker,et al.  Isotopic tracing (Sr, Nd, U and Hf) of continental and marine aerosols in an 18th century section of the Dye-3 ice core (Greenland) , 2010 .

[38]  C. Laveuf,et al.  A review on the potentiality of Rare Earth Elements to trace pedogenetic processes , 2009 .

[39]  Qianggong Zhang,et al.  Rare earth elements in the surface sediments of the Yarlung Tsangbo (Upper Brahmaputra River) sediments, southern Tibetan Plateau , 2009 .

[40]  J. Ji,et al.  Isotopic evidences for provenance of East Asian Dust , 2009 .

[41]  C. You,et al.  Constraints on water chemistry by chemical weathering in the Lake Qinghai catchment, northeastern Tibetan Plateau (China): clues from Sr and its isotopic geochemistry , 2009 .

[42]  R. Romer,et al.  Size-dependent geochemical signatures of Holocene loess deposits from the Hexi Corridor (China) , 2009 .

[43]  D. Qin,et al.  Tracing the sources of particles in the East Rongbuk ice core from Mt. Qomolangma , 2009 .

[44]  T. Yao,et al.  Geochemistry of dust aerosol over the Eastern Pamirs , 2009 .

[45]  Mianping Zheng,et al.  Hydrochemistry of Salt Lakes of the Qinghai-Tibet Plateau, China , 2009 .

[46]  B. Delmonte,et al.  Aeolian dust in East Antarctica (EPICA‐Dome C and Vostok): Provenance during glacial ages over the last 800 kyr , 2008 .

[47]  Shi-chang Kang,et al.  Shifts of dust source regions over central Asia and the Tibetan Plateau: Connections with the Arctic oscillation and the westerly jet , 2008 .

[48]  D. Muhs,et al.  Loess sedimentation in Tibet: provenance, processes, and link with Quaternary glaciations , 2007 .

[49]  W. Balsam,et al.  Nd and Sr isotopic characteristics of Chinese deserts: Implications for the provenances of Asian dust , 2007 .

[50]  D. A. Edwards,et al.  Metal Oxides , 2020, Metals.

[51]  W. Smykatz-kloss,et al.  REE geochemistry of the recent playa sediments from the Thar Desert, India: An implication to playa sediment provenance , 2007 .

[52]  G. Kamenov,et al.  A simple method for rapid, high-precision isotope measurements of small samples with MC-ICP-MS , 2006 .

[53]  G. Hall,et al.  Asian dustfall in the St. Elias Mountains, Yukon, Canada , 2006 .

[54]  C. Barbante,et al.  Southern Ocean sea-ice extent, productivity and iron flux over the past eight glacial cycles , 2006, Nature.

[55]  F. Grousset,et al.  Tracing dust sources and transport patterns using Sr, Nd and Pb isotopes , 2005 .

[56]  Axel Lauer,et al.  © Author(s) 2006. This work is licensed under a Creative Commons License. Atmospheric Chemistry and Physics Analysis and quantification of the diversities of aerosol life cycles , 2022 .

[57]  K. Moorthy,et al.  Radiative effects of natural aerosols: A review , 2005 .

[58]  V. Lipenkov,et al.  Dust size evidence for opposite regional atmospheric circulation changes over east Antarctica during the last climatic transition , 2004 .

[59]  F. Grousset,et al.  Comparing the Epica and Vostok dust records during the last 220,000 years: stratigraphical correlation and provenance in glacial periods , 2004 .

[60]  H. Shimizu,et al.  Geochemical and isotopic studies of aeolian sediments in China , 2004 .

[61]  L. Thompson,et al.  Microparticle record in the Guliya ice core and its comparison with polar records since the last interglacial , 2004 .

[62]  Dongfang Wang,et al.  Characterization of soil dust aerosol in China and its transport and distribution during 2001 ACE‐Asia: 1. Network observations , 2003 .

[63]  Francis E. Grousset,et al.  Two distinct seasonal Asian source regions for mineral dust deposited in Greenland (NorthGRIP) , 2003 .

[64]  Jimin Sun Source Regions and Formation of the Loess Sediments on the High Mountain Regions of Northwestern China , 2002, Quaternary Research.

[65]  Weihong Qian,et al.  Variations of the Dust Storm in China and its Climatic Control , 2002 .

[66]  O. Torres,et al.  ENVIRONMENTAL CHARACTERIZATION OF GLOBAL SOURCES OF ATMOSPHERIC SOIL DUST IDENTIFIED WITH THE NIMBUS 7 TOTAL OZONE MAPPING SPECTROMETER (TOMS) ABSORBING AEROSOL PRODUCT , 2002 .

[67]  S. Gallet,et al.  Geochemistry of the Xining, Xifeng and Jixian sections, Loess Plateau of China: eolian dust provenance and paleosol evolution during the last 140 ka , 2001 .

[68]  Sandy P. Harrison,et al.  DIRTMAP: the geological record of dust , 2001 .

[69]  H. Shimizu,et al.  Sr and Nd isotope ratios and REE abundances of moraines in the mountain areas surrounding the Taklimakan Desert, NW China , 2000 .

[70]  K. Kreutz,et al.  Major element, rare earth element, and sulfur isotopic composition of a high‐elevation firn core: Sources and transport of mineral dust in central Asia , 2000 .

[71]  Kazuya Takahashi,et al.  JNdi-1: a neodymium isotopic reference in consistency with LaJolla neodymium , 2000 .

[72]  G. M. Young,et al.  Behavior of major and trace elements (including REE) during Paleoproterozoic pedogenesis and diagenetic alteration of an Archean granite near Ville Marie, Québec, Canada , 2000 .

[73]  F. Grousset,et al.  Characterization of late glacial continental dust in the Greenland Ice Core Project ice core , 2000 .

[74]  U. Schwertmann,et al.  Color Identification of Iron Oxides and Hydroxysulfates , 1999 .

[75]  A. Dia,et al.  Loess geochemistry and its implications for particle origin and composition of the upper continental crust , 1998 .

[76]  Francis E. Grousset,et al.  Asian provenance of glacial dust (stage 2) in the Greenland Ice Sheet Project 2 Ice Core , 1997 .

[77]  E. Mosley‐Thompson,et al.  Tropical Climate Instability: The Last Glacial Cycle from a Qinghai-Tibetan Ice Core , 1997 .

[78]  F. Grousset,et al.  Patagonian origin of glacial dust deposited in East Antarctica (Vostok and Dome C) during glacial stages 2, 4 and 6 , 1997 .

[79]  S. Taylor,et al.  The geochemical evolution of the continental crust , 1995 .

[80]  M. Angelis,et al.  Sources of continental dust over Antarctica during the last glacial cycle , 1992 .

[81]  A. Royer,et al.  Ice age aerosol content from East Antarctic ice core samples and past wind strength , 1981, Nature.

[82]  E. Mosley‐Thompson,et al.  Temporal variability of microparticle properties in polar ice sheets , 1981 .

[83]  G. Wasserburg,et al.  Sm-Nd isotopic evolution of chondrites , 1980 .

[84]  G. Pattenden,et al.  An Estimate of the Chemical Composition of the Canadian Precambrian Shield , 1967 .

[85]  John M. McArthur,et al.  Strontium isotope stratigraphy , 2012 .

[86]  L. Thompson,et al.  21st Century Asian air pollution impacts glacier in northwestern Tibet , 2019 .

[87]  Xuelei Zhang,et al.  The environmental implications for dust in high-alpine snow and ice cores in Asian mountains , 2015 .

[88]  R. Rudnick,et al.  Composition of the Continental Crust , 2014 .

[89]  D. Qin,et al.  Sr-Nd isotope evidence for modern aeolian dust sources in mountain glaciers of western China , 2012, Journal of Glaciology.

[90]  M. Frezzotti,et al.  Geographic provenance of aeolian dust in East Antarctica during Pleistocene glaciations: preliminary results from Talos Dome and comparison with East Antarctic and new Andean ice core data , 2010 .

[91]  Thomas Wichard,et al.  Storage and bioavailability of molybdenum in soils increased by organic matter complexation , 2009 .

[92]  U. Herzschuh Palaeo-moisture evolution in monsoonal Central Asia during the last 50,000 years , 2006 .

[93]  J. Hatfield,et al.  Encyclopedia of Soils in The Environment , 2004 .

[94]  J. Griffioen,et al.  Fluoride in groundwater: Probability of occurrence of excessive concentration on global scale , 2004 .

[95]  L. Thompson,et al.  Ice core evidence for climate change in the Tropics: implications for our future , 2000 .

[96]  L. Thompson,et al.  High resolution record of paleoclimate since the Little Ice Age from the Tibetan ice cores , 1997 .

[97]  Raymond S. Bradley,et al.  Are there optimum sites for global paleotemperature reconstruction , 1996 .

[98]  K. Condie,et al.  Behavior of rare earth elements in a paleoweathering profile on granodiorite in the Front Range, Colorado, USA , 1995 .

[99]  N. Grevesse,et al.  Abundances of the elements: Meteoritic and solar , 1989 .

[100]  G. Michard,et al.  Chemical study of geothermal waters of Central Tibet (China) , 1985 .

[101]  S. Taylor,et al.  The continental crust: Its composition and evolution , 1985 .

[102]  R. Keays,et al.  Additional estimates of continental surface Precambrian shield composition in Canada , 1976 .

[103]  S. Gloss,et al.  Geochemical speciation as related to the mobility of F , Mo and Se in soil leachates , 2022 .