Direct growth of the multi-walled carbon nanotubes as a tool to detect ammonia at room temperature

In this work, we report on the application of multi-walled carbon nanotubes as gas sensors. We use the vertical growth of aligned carbon nanotubes on structure surfaces composed by a set of Ni electrodes and SiO2 surfaces fraction. The results show that carbon nanotubes could be efficient in terms of sensibility for detection of pollutant species like NH3 even at ambient temperature. The determination of the adsorption energies for various species on the basis of a semi-empirical potential approach show that gases, particularly the polar one, are able to bind strongly on carbon nanotubes surfaces and could explain at least qualitatively the experimental results.

[1]  M. W. Cole,et al.  Quasi-one- and two-dimensional transitions of gases adsorbed on nanotube bundles , 2000, cond-mat/0008206.

[2]  David E. Williams Semiconducting oxides as gas-sensitive resistors , 1999 .

[3]  N. Dupont-Pavlovsky,et al.  Where are the molecules adsorbed on single-walled nanotubes? , 2001 .

[4]  Kong,et al.  Nanotube molecular wires as chemical sensors , 2000, Science.

[5]  S. Iijima Helical microtubules of graphitic carbon , 1991, Nature.

[6]  Jijun Zhao,et al.  Gas molecule adsorption in carbon nanotubes and nanotube bundles , 2002 .

[7]  P. Bernier,et al.  OPENING OF SINGLE-WALLED CARBON NANOTUBES: EVIDENCE GIVEN BY KRYPTON AND XENON ADSORPTION , 2003 .

[8]  Mica Grujicic,et al.  The effect of topological defects and oxygen adsorption on the electronic transport properties of single-walled carbon-nanotubes , 2003 .

[9]  S. Ciraci,et al.  A comparative study of O2 adsorbed carbon nanotubes , 2003 .

[10]  C. Reynaud,et al.  Growth of multiwalled carbon nanotubes during the initial stages of aerosol-assisted CCVD , 2005 .

[11]  M. Terrones,et al.  Fabrication of vapor and gas sensors using films of aligned CNx nanotubes , 2004 .

[12]  Jose Maria Kenny,et al.  Sensitivity to NO2 and cross-sensitivity analysis to NH3, ethanol and humidity of carbon nanotubes thin film prepared by PECVD , 2003 .

[13]  Michele Penza,et al.  Carbon nanotubes-based surface acoustic waves oscillating sensor for vapour detection , 2005 .

[14]  J. Kenny,et al.  Effects of oxygen annealing on cross sensitivity of carbon nanotubes thin films for gas sensing applications , 2004 .

[15]  Saurabh Chopra,et al.  Selective gas detection using a carbon nanotube sensor , 2003 .

[16]  Saurabh Chopra,et al.  Carbon-nanotube-based resonant-circuit sensor for ammonia , 2002 .

[17]  F. Picaud,et al.  Influence of molecular adsorption on the dielectric properties of a single wall nanotube: a model sensor. , 2004, The Journal of chemical physics.

[18]  S. Tans,et al.  Room-temperature transistor based on a single carbon nanotube , 1998, Nature.

[19]  C. Ramseyer,et al.  Molecular selectivity due to adsorption properties in nanotubes , 2004 .

[20]  Interaction of O2 with a (9,0) carbon nanotube , 2002 .

[21]  Gerhard Wiegleb,et al.  Semiconductor gas sensor for detecting NO and CO traces in ambient air of road traffic , 1994 .

[22]  Jose Maria Kenny,et al.  Sensors for inorganic vapor detection based on carbon nanotubes and poly(o-anisidine) nanocomposite material , 2004 .

[23]  Jose Maria Kenny,et al.  Highly sensitive and selective sensors based on carbon nanotubes thin films for molecular detection , 2004 .

[24]  Yoshinori Ando,et al.  Electrical conductivities of multi-wall carbon nano tubes , 1999 .

[25]  M. Grujicic,et al.  A computational analysis of the carbon-nanotube-based resonant-circuit sensors , 2004 .

[26]  J. Rouzaud,et al.  Carbon nanotubes produced by aerosol pyrolysis: growth mechanisms and post-annealing effects , 2004 .

[27]  C. Quate,et al.  Integrated nanotube circuits: Controlled growth and ohmic contacting of single-walled carbon nanotubes , 1999 .

[28]  Herbert Shea,et al.  Single- and multi-wall carbon nanotube field-effect transistors , 1998 .