In recent years many studies concerning the monitoring of volcanic activity have been carried out to develop ever more accurate and refine methods which allow to face the emergencies related to an eruption event. In our work we present different approaches for the volcanic ash cloud detection and retrieval using Sentinel-3 Sea and Land Surface Temperature Radiometer (SLSTR) data. As test case the SLSTR image collected on Raikoke volcano the 22 June 2019 at 00:07 UTC has been considered. A neural network based algorithm able to detect and distinguish volcanic and meteorological clouds, and the underlying surfaces, has been implemented and compared with two consolidated approaches: the RGB (Red-Green-Blue) and the Brightness Temperature Difference procedures. For the ash retrieval parameters (aerosol optical depth, effective radius and ash mass), three different methods have been compared: the reliable and consolidated LUTp(Look Up Table) procedure, the very fast VPR (Volcanic Plume Retrieval) algorithm and a neural network based model.