Synthesis of highly monodispersed Ga-soc-MOF hollow cubes, colloidosomes and nanocomposites.

Ga-soc-MOF hollow cubes with an average size of about 300 nm were prepared by a polyvinylpyrrolidone (PVP) assisted acid etching process. Colloidosomes with sizes of around 5-10 μm composed of single-layer tetrakaidecahedron building blocks (BBs) were synthesized for the first time. Au@Ga-soc-MOF nanocomposites with excellent catalytic properties were obtained.

[1]  Jun Lin,et al.  Facile Synthesis of Highly Uniform Fe-MIL-88B Particles , 2016 .

[2]  Kang Liang,et al.  Bioactive MIL-88A Framework Hollow Spheres via Interfacial Reaction In-Droplet Microfluidics for Enzyme and Nanoparticle Encapsulation , 2015 .

[3]  A. Emwas,et al.  MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH4, O2, and CO2 Storage , 2015, Journal of the American Chemical Society.

[4]  Yadong Li,et al.  Hollow Zn/Co ZIF Particles Derived from Core-Shell ZIF-67@ZIF-8 as Selective Catalyst for the Semi-Hydrogenation of Acetylene. , 2015, Angewandte Chemie.

[5]  I. Pinnau,et al.  Quest for anionic MOF membranes: continuous sod-ZMOF membrane with CO2 adsorption-driven selectivity. , 2015, Journal of the American Chemical Society.

[6]  Sidney R. Cohen,et al.  Metal-organic microstructures: from rectangular to stellated and interpenetrating polyhedra. , 2015, Journal of the American Chemical Society.

[7]  Xun Wang,et al.  Hierarchical Zn/Ni-MOF-2 nanosheet-assembled hollow nanocubes for multicomponent catalytic reactions. , 2014, Angewandte Chemie.

[8]  Yunhui Huang,et al.  MOF‐Derived Porous ZnO/ZnFe2O4/C Octahedra with Hollow Interiors for High‐Rate Lithium‐Ion Batteries , 2014, Advanced materials.

[9]  Qiang Xu,et al.  Metal-organic framework composites. , 2014, Chemical Society reviews.

[10]  S. Kitagawa,et al.  Structuring of metal-organic frameworks at the mesoscopic/macroscopic scale. , 2014, Chemical Society reviews.

[11]  Demin Liu,et al.  Nanoscale Metal–Organic Frameworks for the Co-Delivery of Cisplatin and Pooled siRNAs to Enhance Therapeutic Efficacy in Drug-Resistant Ovarian Cancer Cells , 2014, Journal of the American Chemical Society.

[12]  Wei He,et al.  Well-defined metal-organic framework hollow nanocages. , 2014, Angewandte Chemie.

[13]  X. Jiao,et al.  LDH nanocages synthesized with MOF templates and their high performance as supercapacitors. , 2013, Nanoscale.

[14]  Michael O’Keeffe,et al.  The Chemistry and Applications of Metal-Organic Frameworks , 2013, Science.

[15]  X. Lou,et al.  Metal-organic-frameworks-derived general formation of hollow structures with high complexity. , 2013, Journal of the American Chemical Society.

[16]  Amy J. Cairns,et al.  Synthesis and integration of Fe-soc-MOF cubes into colloidosomes via a single-step emulsion-based approach. , 2013, Journal of the American Chemical Society.

[17]  M. Marcello,et al.  MOF‐Polymer Composite Microcapsules Derived from Pickering Emulsions , 2013, Advanced materials.

[18]  H. Zeng,et al.  Surface and Bulk Integrations of Single-Layered Au or Ag Nanoparticles onto Designated Crystal Planes {110} or {100} of ZIF-8 , 2013 .

[19]  Subi J. George,et al.  Shape assisted fabrication of fluorescent cages of squarate based metal-organic coordination frameworks. , 2013, Chemical communications.

[20]  Inhar Imaz,et al.  A spray-drying strategy for synthesis of nanoscale metal-organic frameworks and their assembly into hollow superstructures. , 2013, Nature chemistry.

[21]  Y. Yamauchi,et al.  Tailored design of multiple nanoarchitectures in metal-cyanide hybrid coordination polymers. , 2013, Journal of the American Chemical Society.

[22]  S. Granick,et al.  Electric field-induced assembly of monodisperse polyhedral metal-organic framework crystals. , 2013, Journal of the American Chemical Society.

[23]  Yayuan Liu,et al.  Synthesis and self-assembly of monodispersed metal-organic framework microcrystals. , 2013, Chemistry, an Asian journal.

[24]  H. Zeng,et al.  Self-generated etchant for synthetic sculpturing of Cu2O-Au, Cu2O@Au, Au/Cu2O, and 3D-Au nanostructures. , 2012, Chemistry.

[25]  H. García,et al.  Commercial metal-organic frameworks as heterogeneous catalysts. , 2012, Chemical communications.

[26]  C. Téllez,et al.  Ordered mesoporous silica-(ZIF-8) core-shell spheres. , 2012, Chemical communications.

[27]  Amy J. Cairns,et al.  Highly monodisperse M(III)-based soc-MOFs (M = In and Ga) with cubic and truncated cubic morphologies. , 2012, Journal of the American Chemical Society.

[28]  Steve Granick,et al.  Directional self-assembly of a colloidal metal-organic framework. , 2012, Angewandte Chemie.

[29]  Shyam Biswas,et al.  Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. , 2012, Chemical reviews.

[30]  Y. Yamauchi,et al.  Synthesis of Prussian blue nanoparticles with a hollow interior by controlled chemical etching. , 2012, Angewandte Chemie.

[31]  M. Oh,et al.  Advanced fabrication of metal-organic frameworks: template-directed formation of polystyrene@ZIF-8 core-shell and hollow ZIF-8 microspheres. , 2012, Chemical communications.

[32]  S. Kitagawa,et al.  Morphology design of porous coordination polymer crystals by coordination modulation. , 2011, Journal of the American Chemical Society.

[33]  H. Zeng Synthesis and self-assembly of complex hollow materials , 2011 .

[34]  M. Roeffaers,et al.  Interfacial synthesis of hollow metal–organic framework capsules demonstrating selective permeability , 2011, Nature Chemistry.

[35]  Klaus Huber,et al.  Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering , 2011 .

[36]  T. Akita,et al.  Synergistic catalysis of Au@Ag core-shell nanoparticles stabilized on metal-organic framework. , 2011, Journal of the American Chemical Society.

[37]  A. Corma,et al.  Engineering metal organic frameworks for heterogeneous catalysis. , 2010, Chemical reviews.

[38]  Peidong Yang,et al.  Anisotropic etching of silver nanoparticles for plasmonic structures capable of single-particle SERS. , 2010, Journal of the American Chemical Society.

[39]  Younan Xia,et al.  Etching and growth: an intertwined pathway to silver nanocrystals with exotic shapes. , 2009, Angewandte Chemie.

[40]  Hong-Cai Zhou,et al.  Selective gas adsorption and separation in metal-organic frameworks. , 2009, Chemical Society reviews.

[41]  Omar K Farha,et al.  Metal-organic framework materials as catalysts. , 2009, Chemical Society reviews.

[42]  Tierui Zhang,et al.  Permeable silica shell through surface-protected etching. , 2008, Nano letters.

[43]  S. Aloni,et al.  Formation of hollow silica colloids through a spontaneous dissolution-regrowth process. , 2008, Angewandte Chemie.