论文信息 - New systems based on 2,2’-dipyridyl-6,6’-dicarboxylic acid diamides for Am–Eu separation - 字舞流文

New systems based on 2,2’-dipyridyl-6,6’-dicarboxylic acid diamides for Am–Eu separation

New synergistic extraction mixtures based on 2,2’-dipyridyl-6,6’-dicarboxylic acid diamides and chlorinated cobalt dicarbolide were proposed as highly effective for americium–europium separation in acidic media.

Nataliya E. Borisova | D. V. Safronov | Marina D. Reshetova | M. Alyapyshev | V. Babain | M. Reshetova | N. Borisova | Vasily Babain | Mikhail Alyapyshev | Rimma N. Kiseleva | Dmitry V. Safronov | R. N. Kiseleva

[1] M. Drew,et al. Solvent extraction of metal ions from nitric acid solution usingN,N′-substituted malonamides.Experimental and crystallographic evidence for two mechanisms ofextraction, metal complexation and ion-pair formation , 1997 .

[2] E. Mowafy. Evaluation of selectivity and radiolysis behavior of some promising isonicotinamids and dipicolinamides as extractants , 2007 .

[3] V. Babain,et al. Radionuclide Extraction by 2,6‐Pyridinedicarboxylamide Derivatives and Chlorinated Cobalt Dicarbollide , 2006 .

[4] D. Reinhoudt,et al. Multicoordinate ligands for actinide/lanthanide separations. , 2007, Chemical Society reviews.

[5] F. Vögtle,et al. Wittig-Synthese und Röntgen-Struktur eines 26-gliedrigen, zwei Bipyridin-Einheiten enthaltenden Makrocyclus , 1990 .

[6] Z. Kolarik,et al. Selective extraction of Am(III) over Eu(III) by 2,6-ditriazolyl- and 2,6,-ditriazinylpyridines , 1999 .

[7] S. Tachimori,et al. Extraction Separation of Tervalent Americium and Lanthanides in the Presence of Some Soft and Hard Donors and Dicarbollide , 1994 .

[8] Z. Kolarik,et al. EXTRACTION OF Am(lll) AND Eu(lll) NITRATES BY 2-6-DI-(5,6-DIPROPYL-1,2,4-TRIAZIN-3-YL)PYRIDINES 1 , 1999 .