Alkynylarsenic, -antimony, -bismuth, -boron, -silicon, -germanium, and Metal Compounds

[1]  E. Lukevics,,et al.  Synthesis, Structure and Chemical Transformations of Ethynylgermatranes , 2003 .

[2]  Jinhua Yang,et al.  Coupling of 3,8-Dibromo-1,10-phenanthroline with 3,5-Diethynylheptyloxybenzene: A Suzuki/Miyaura Versus a Sonogashira Perspective , 2003 .

[3]  Charlotte K. Williams,et al.  Metal alkynyl σ complexes: Synthesis and materials , 2003 .

[4]  E. Negishi,et al.  Highly satisfactory alkynylation of alkenyl halides via Pd-catalyzed cross-coupling with alkynylzincs and its critical comparison with the sonogashira alkynylation. , 2003, Organic letters.

[5]  E. Negishi,et al.  Palladium-catalyzed alkynylation. , 2003, Chemical reviews.

[6]  R. Tykwinski.  Evolution in the palladium-catalyzed cross-coupling of sp- and sp2-hybridized carbon atoms. , 2003, Angewandte Chemie.

[7]  J. Parr,et al.  Alkynyl germatranes as alternative reagents for the preparation of biarylethynes , 2003 .

[8]  De-Yu Yang,et al.  A Regio- and Stereoselective Route to (E)-Stannylenynes by Cross-Coupling of Stannyl Vinyldialkylboranes with Alkynyl(phenyl)iodonium Tosylates , 2003 .

[9]  R. Kultyshev,et al.  Palladium-catalyzed cross-coupling reactions of allyl, phenyl, alkenyl, and alkynyl germatranes with aryl iodides , 2002 .

[10]  Sambasivarao Kotha,et al.  Recent applications of the Suzuki–Miyaura cross-coupling reaction in organic synthesis , 2002 .

[11]  M. Yáñez,et al.  The gas-phase acidity of HCP, CH3CP, HCAs, and CH3CAs: an unexpected enhanced acidity of the methyl group. , 2002, Chemistry.

[12]  Fouzia Machrouhi,et al.  Development of the suzuki-miyaura cross-coupling reaction: use of air-stable potassium alkynyltrifluoroborates in aryl alkynylations. , 2002, The Journal of organic chemistry.

[13]  H. Seki,et al.  Synthesis of Sb-chiral organoantimony compounds having intramolecular Sb...N interaction and their separation into optically pure compounds via ortho-palladated benzylamine complexes , 2002 .

[14]  G. Molander,et al.  Palladium-catalyzed cross-alkynylation of aryl bromides by sodium tetraalkynylaluminates. , 2002, The Journal of organic chemistry.

[15]  M. J. Bayer,et al.  Synthesis, structures, and donor-acceptor adducts of tris(3,3‐dimethyl‐1‐butynyl)borane , 2002 .

[16]  H. Roesky,et al.  Alkynyl aluminium compounds: bonding modes and structures , 2002 .

[17]  K. Sonogashira,et al.  Development of Pd–Cu catalyzed cross-coupling of terminal acetylenes with sp2-carbon halides , 2002 .

[18]  A. Suzuki.  Cross-coupling reactions via organoboranes , 2002 .

[19]  Y. Matano,et al.  New Syntheses of Bismuthonium Salts, Bismuthonium Ylides and Bismuthane Imides Using Triarylbismuth(V)-Oxo and -Hydroxo Compounds , 2002 .

[20]  D. Mingos,et al.  Recent studies on alkynyl complexes of the Group 11 and 12 metals , 2002 .

[21]  S. Kusuda,et al.  Preparation of optically pure propargylic and allylic alcohols from 2-(trimethylsilyl)vinyl sulfoxides as a chiral ethynyl anion synthon: computational studies on elimination reaction of 2-(trimethylsilyl)vinyl sulfoxides. , 2002, The Journal of organic chemistry.

[22]  A. Churakov,et al.  New approach to 1-(phenylethynyl)germatranes and 1-(phenylethynyl)-3,7,10-trimethylgermatrane. Reactions of 1-(phenylethynyl)germatrane with N-bromosuccinimide and bromine , 2001 .

[23]  K. Osakada,et al.  Reaction of alkynylsilanes with CuCl in polar solvents leading to alkynyl group transfer from Si to Cu , 2001 .

[24]  H. Pritzkow,et al.  Synthesis and Reactivity of Monoborylacetylene Derivatives , 2001 .

[25]  A. Fürstner,et al.  Alkyne cross metathesis reactions of extended scope. , 2001, Organic letters.

[26]  H. Yamashita,et al.  Thermally Stable Borazine-Based Polymer , 2001 .

[27]  D. B. Collum,et al.  BF3-Mediated Addition of Lithium Phenylacetylide to an Imine: Correlations of Structures and Reactivities. BF3·R3N Derivatives as Substitutes for BF3·Et2O , 2000 .

[28]  C. Oh,et al.  Efficient coupling reactions of lithium alkynyl(triisopropoxy)borates with aryl halides: application to the antifungal terbinafine synthesis , 2000 .

[29]  E. Negishi,et al.  A strictly "pair"-selective synthesis of conjugated diynes via Pd-catalyzed cross coupling of 1,3-diynylzincs: a superior alternative to the Cadiot-Chodkiewicz reaction. , 2000, Organic letters.

[30]  Castanet,et al.  Suzuki-miyaura coupling of alkynylboronic esters generated in situ from acetylenic derivatives , 2000, Organic letters.

[31]  Diederich,et al.  Acetylenic Coupling: A Powerful Tool in Molecular Construction. , 2000, Angewandte Chemie.

[32]  E. Carreira,et al.  The discovery of novel reactivity in the development of C-C bond-forming reactions: in situ generation of zinc acetylides with Zn(II)/R(3)N. , 2000, Accounts of chemical research.

[33]  T. Tsuchiya,et al.  Palladium-catalyzed cross-coupling reactions between 1-alkynylstibines and acyl chlorides , 2000 .

[34]  J. Soderquist,et al.  A versatile synthesis of 9-BBN derivatives from organometallic reagents and 9-(triisopropylsilyl)thio-9-borabicyclo[3.3.1]nonane , 2000 .

[35]  U. Mäeorg,et al.  On the in situ trimethylsilylation of zinc acetylides , 2000 .

[36]  T. Hiyama,et al.  Coupling Reactions of Alkynylsilanes Mediated by a Cu(I) Salt: Novel Syntheses of Conjugate Diynes and Disubstituted Ethynes. , 2000, The Journal of organic chemistry.

[37]  N. Taylor,et al.  Asymmetric Conjugate Addition of Alkynylboronates to Enones , 2000 .

[38]  R. Shimizu,et al.  Dehydrogenative silylation of terminal alkynes by iridium catalyst , 2000 .

[39]  Y. Matano.  First synthesis of alkynyltriphenylbismuthonium salts and their dual reaction modes in sulfonylation , 2000 .

[40]  W. Saak,et al.  Silylene Reactions with Buta‐1,3‐diynes: Cycloadditions, Insertions, and Rearrangements , 1999 .

[41]  C. Silvestru,et al.  Structural chemistry of bismuth compounds. I. Organobismuth derivatives. , 1999, Chemical reviews.

[42]  L. Brandsma,et al.  Simple Procedures for Ethynylmagnesium Bromide, Ethynyltrialkylsilanes and Ethynyltrialkylstannanes , 1999 .

[43]  D. Brauer,et al.  FLUORINE EFFECTS IN ORGANOBORANES; FORMATION OF CYANOALKYL-BIS(TRIFLUOROMETHYL)-ORGANOBORATES , 1999 .

[44]  J. Genêt,et al.  Potassium Organotrifluoroborates: New Partners in Palladium‐Catalysed Cross‐Coupling Reactions , 1999 .

[45]  Akira Suzuki,et al.  Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998 , 1999 .

[46]  B. Neumann,et al.  SYNTHESIS AND STRUCTURE OF 2-HYDRO-, 2-ALKYL-, 2-ALKYNYL-, AND 2-STANNYL-2,3-DIHYDRO-1H-1,3,2-DIAZABOROLES , 1999 .

[47]  A. Sekiguchi,et al.  Silylacetylene dendrimers: synthesis and characterization , 1999 .

[48]  A. Vasella,et al.  Oligosaccharide Analogues of Polysaccharides. Part 15. Oligomers of Cellobiose-Derived Dialkynes and First Crystal Structure of an Anomeric Pair of Trichloroacetimidates. , 1999 .

[49]  G. Pfister-guillouzo,et al.  Photoelectron spectra of vinyl- and 1-alkynylgermanes and stannanes , 1998 .

[50]  A. Spek,et al.  Synthesis of Alkynyl-Substituted 9,10-Dimetallatriptycenes of Group 14 and Their Application in the Preparation of a Novel Class of Organometallic Oligomers. , 1998 .

[51]  M. Vaultier,et al.  Lithium Bis-(diisopropylamino)boracetylide [LiCCB(NiPr2)2]. A new reagent for the preparation of terminal alkynes , 1997 .

[52]  E. Negishi,et al.  Direct Synthesis of Terminal Alkynes via Pd-Catalyzed Cross Coupling of Aryl and Alkenyl Halides with Ethynylmetals Containing Zn, Mg, and Sn. Critical Comparison of Countercations , 1997 .

[53]  T. Hiyama,et al.  Cu(I)/Pd(0)-Catalyzed Cross-Coupling Reaction of Alkynylsilanes with Aryl or Alkenyl Triflates: “Sila”-Sonogashira-Hagihara Coupling , 1997 .

[54]  R. Bürli,et al.  Oligosaccharide analogues of polysaccharides. Part 14:. Carbocyclic cyclodextrin analogues. Synthesis of all trimeric and tetrameric isomers by homo‐ and heterocoupling of 1,4‐cis‐diethynylated 1,5‐anhydroglucitols , 1997 .

[55]  R. Bürli,et al.  Oligosaccharide Analogues of Polysaccharides. Part 12. Synthesis of ‘acetyleno‐saccharide’‐derived cyclodextrin analogues , 1997 .

[56]  Hajime Ito,et al.  Direct alkynyl group transfer from silicon to copper: New preparation method of alkynylcopper (I) reagents , 1997 .

[57]  Y. Matano,et al.  Bismuth in Organic Transformations , 1997 .

[58]  A. Varvoglis.  Chemical Transformations Induced by Hypervalent Iodine Reagents , 1997 .

[59]  J. Davies,et al.  REACTION OF AN ALKYNYLLITHIUM REAGENT WITH BORON TRIFLUORIDE : THE STRUCTURE OF A LIKELY INTERMEDIATE IN ALKYNYL ANION CHEMISTRY , 1997 .

[60]  A. Fürstner,et al.  Ethynylation of Aryl Halides by a Modified Suzuki Reaction: Application to the Syntheses of Combretastatin A-4, A-5 and Lunularic Acid , 1996 .

[61]  T. Dittmar,et al.  Reactions of (CF3)2BNMe2 with Grignard and related reagents. Crystal and molecular structure of (CF3)(Mes)FBFCNMe2 and Ph3PCH2(CF3)2BNMe2 , 1996 .

[62]  A. Vasella,et al.  Orthogonally protected dialkynes , 1996 .

[63]  W. Kitching,et al.  Alkynylarsenic, ‐Antimony, ‐Bismuth, ‐Boron, ‐Silicon, ‐Germanium, and ‐Metal Compounds , 1996 .

[64]  A. Vasella,et al.  Oligosaccharide Analogues of Polysaccharides. Part 8. Orthogonally Protected Cellobiose‐Derived Dialkynes. A Convenient Method for the Regioselective Bromo‐ and Protodegermylation of Trimethylgermyl‐ and Trimethylsilyl‐protected Dialkynes , 1996 .

[65]  T. Hiyama,et al.  A Convenient Synthesis of Alkynylsilanes by Silylation of Copper(I) Alkynides , 1996 .

[66]  A. Vasella,et al.  Oligosaccharide Analogues of Polysaccharides. Part 6. Orthogonal protecting/activating groups in an improved binomial synthesis of ‘acetyleno‐oligosaccharides’ , 1996 .

[67]  E. Framery,et al.  AN EFFICIENT ACCESS TO ALKYNYLBORONATES FROM ALKYNYLDIAMINOBORANES , 1996 .

[68]  A. Fürstner,et al.  Palladium-Catalyzed Arylation of Polar Organometallics Mediated by 9-Methoxy-9-Borabicyclo[3.3.1]nonane: Suzuki Reactions of Extended Scope , 1995 .

[69]  J. Guillemin,et al.  Synthesis and Characterization of Primary and Secondary Allenyl- and Alkynylarsines , 1995 .

[70]  J. Soderquist,et al.  Alkynylborinates in organoborane conversions , 1995 .

[71]  C. Rücker,et al.  The Triisopropylsilyl Group in Organic Chemistry: Just a Protective Group, or More? , 1995 .

[72]  J. Soderquist,et al.  Alkynylboranes in the Suzuki-Miyaura coupling , 1995 .

[73]  G. Pfister-guillouzo,et al.  PRIMARY VINYL- AND ALKYNYLSTIBINES : PREPARATION AND CHARACTERIZATION , 1995 .

[74]  M. Ochiai,et al.  An onium transfer reaction of 1-alkynyl(phenyl)iodonium tetrafluoroborates with triphenylarsine; Synthesis of 1-alkynyl(triphenyl)arsonium tetrafluoroborates , 1995 .

[75]  J. Guillemin,et al.  Synthesis of allenyl- and alkynyl-stannanes by reduction of allenyl- and alkynyl-chlorostannanes , 1995 .

[76]  G. Wlodarczak,et al.  Synthesis and Spectroscopic Characterization of Ethylidynearsine , 1994 .

[77]  P. Knochel,et al.  Preparation and reactions of polyfunctional organozinc reagents in organic synthesis , 1993 .

[78]  W. Siebert,et al.  Synthesen und Struktur von Diborylacetylenen , 1993 .

[79]  Yohsuke Yamamoto,et al.  Synthesis halogenolysis, and crystal structure of hypervalent organobismuth compounds (10-Bi-5) , 1993 .

[80]  Hitomi Suzuki,et al.  Synthesis and reactions of some new heterocyclic bismuth-(III) and -(V) compounds. 5,10-Dihydrodibenzo[b,e]bismine and related systems , 1992 .

[81]  M. Srebnik,et al.  A simple, general synthesis of 1-alkynyldiisopropoxyboranes , 1988 .

[82]  J. Soderquist,et al.  Selective oxidation of organoboranes with anhydrous trimethylamine N-oxide , 1986 .

[83]  R. B. Wetherill,et al.  Improved highly efficient synthesis of α,β-acetylenic ketones. Nature of the intermediate from the reaction of lithium acetylide with boron trifluoride etherate , 1984 .

[84]  E. Keinan,et al.  Organotin nucleophiles. 5. Palladium-catalyzed allylic propargylation with allenylstannane , 1983 .

[85]  R. Hanson,et al.  Simple and direct synthesis of trans-1,2-bis(tributylstannyl)ethylene , 1981 .

[86]  H. Brown,et al.  Organoboranes : XVIII. Reaction of lithium alkynes with methyl dialkylborinates: The synthesis of B-1-alkynyldialkylboranes , 1977 .