Characterization of high glass transition temperature sugar-based epoxy resin composites with jute and carbon fibre reinforcement

Abstract The applicability of a newly synthesized glucose-based renewable epoxy resin component was tested in jute fibre and carbon fibre reinforced composites, respectively. Dynamic mechanical properties, glass transition temperature, tensile and bending strength and modulus was determined and compared to the properties of mineral oil based benchmark materials: aromatic bisphenol-A based, aliphatic glycerol and pentaerythritol based epoxy resin composites. For potential aircraft interior applications sandwich structures were prepared using jute fibre reinforcement and polymethacrylimide foam as core. According to the results the novel glucose-based epoxy monomer can be an alternative to the commonly used diglycidyl-ether of bisphenol-A (DGEBA), including high-temperature composites applications up to 160 °C.

[1]  R. Lobo,et al.  Renewable production of phthalic anhydride from biomass-derived furan and maleic anhydride , 2014 .

[2]  Sharif Ahmad,et al.  Modification of novel bio‐based resin‐epoxidized soybean oil by conventional epoxy resin , 2011 .

[3]  A. Behera,et al.  Physical and mechanical characterization of jute reinforced soy composites , 2013 .

[4]  M. A. Bustam,et al.  Blending of Epoxidised Palm Oil with Epoxy Resin: The Effect on Morphology, Thermal and Mechanical Properties , 2012, Journal of Polymers and the Environment.

[5]  A. Błędzki,et al.  Biocomposites reinforced with natural fibers: 2000–2010 , 2012 .

[6]  M. Litt,et al.  Sucrose-based epoxy monomers and their reactions with diethylenetriamine , 1998 .

[7]  Xiaoqing Liu Preparation of a bio-based epoxy with comparable properties to those of petroleum-based counterparts , 2012 .

[8]  Jiang Zhu,et al.  A strategy for improving mechanical properties of a fiber reinforced epoxy composite using functionalized carbon nanotubes , 2011 .

[9]  D. Srivastava,et al.  STUDIES ON CARDANOL-BASED EPOXIDIZED NOVOLAC RESIN AND ITS BLENDS , 2008 .

[10]  A. Toldy,et al.  Effect of epoxidized soybean oil on mechanical properties of woven jute fabric reinforced aromatic and aliphatic epoxy resin composites , 2017 .

[11]  Gábor Szebényi,et al.  Novel high glass temperature sugar-based epoxy resins: Characterization and comparison to mineral oil-based aliphatic and aromatic resins , 2015 .

[12]  G. Marosi,et al.  Synthesis and characterization of biobased epoxy monomers derived from d-glucose , 2015 .

[13]  Ramkrishna Sen,et al.  Enhancement of tensile strength of lignocellulosic jute fibers by alkali-steam treatment. , 2010, Bioresource technology.

[14]  Paul M. Weaver,et al.  Green composites: A review of material attributes and complementary applications , 2014 .

[15]  A. Toldy,et al.  Effect of Epoxidized Soybean Oil on Curing, Rheological, Mechanical and Thermal Properties of Aromatic and Aliphatic Epoxy Resins , 2014, Journal of Polymers and the Environment.

[16]  M. Misra,et al.  Fracture toughness and impact strength of anhydride‐cured biobased epoxy , 2005 .

[17]  Jianhua Li,et al.  Porous epoxy monolith prepared via chemically induced phase separation , 2009 .

[18]  M. Skrifvars,et al.  Effect of water absorption on mechanical properties of soybean oil thermosets reinforced with natural fibers , 2012 .

[19]  Soojin Park,et al.  Thermal and Rheological Properties of Vegetable Oil-based Epoxy Resins Cured with Thermally Latent Initiator , 2007 .

[20]  P. Stefani,et al.  Thermal and mechanical properties of anhydride‐cured epoxy resins with different contents of biobased epoxidized soybean oil , 2011 .

[21]  J. Karger‐Kocsis,et al.  Curing, gelling, thermomechanical, and thermal decomposition behaviors of anhydride‐cured epoxy (DGEBA)/epoxidized soybean oil compositions , 2014 .

[22]  W. Chow,et al.  Biobased Epoxidized Vegetable Oils and Its Greener Epoxy Blends: A Review , 2010 .

[23]  Hao Wang,et al.  Effects of chemical treatments on hemp fibre structure , 2013 .

[24]  J. Galy,et al.  Preparation and properties of bio-based epoxy networks derived from isosorbide diglycidyl ether , 2011 .

[25]  D. Srivastava,et al.  Studies on the blends of cardanol-based epoxidized novolac resin and CTPB , 2007 .

[26]  T. Schuman,et al.  Vegetable Oil-derived Epoxy Monomers and Polymer Blends: A Comparative Study with Review , 2013 .

[27]  Yusuf Yagci,et al.  Polymers from triglyceride oils , 2006 .

[28]  R. Lobo,et al.  List of reagents for analytical purposes with notes indicating the standards of purity regarded as necessary for analytical work , 1915 .

[29]  Jerry E. White,et al.  Amine-cured ω-epoxy fatty acid triglycerides: Fundamental structure–property relationships , 2007 .

[30]  Thiru Aravinthan,et al.  Thermo-mechanical properties of epoxidized hemp oil-based bioresins and biocomposites , 2013 .