Syndiotactic-specific polymerization of styrene: catalyst structure and polymerization mechanism

[1]  F. Laschi,et al.  Reactivity of the [(η5-C5Me5)TiCH3][RB(C6F5)3] Complexes Identified as Active Species in Syndiospecific Styrene Polymerization , 1998 .

[2]  T. Newman,et al.  Syndiospecific polymerization of styrene , 1998 .

[3]  A. Grassi,et al.  Syndiospecific styrene polymerization promoted by half-titanocene catalysts : A kinetic investigation providing a closer insight to the active species , 1997 .

[4]  D. Gillis,et al.  The formation and structures of the methyl-bridged complexes Cp∗TiMe2(μ-Me)B(C6F5)3 and [Cp∗TiMe2(μ-Me)TiMe2Cp∗][MeB(C6F5)3] , 1997 .

[5]  D. Gillis,et al.  Synthesis and Characterization of the Series of d0 Arene Complexes [Cp*MMe2(η6-arene)][MeB(C6F5)3] (M = Ti, Zr, Hf) , 1996 .

[6]  D. Gillis,et al.  Ethylene, Styrene, and α-Methylstyrene Polymerization by Mono(pentamethylcyclopentadienyl) (Cp*) Complexes of Titanium, Zirconium, and Hafnium: Roles of Cationic Complexes of the Type [Cp*MR2]+ (R = Alkyl) as both Coordination Polymerization Catalysts and Carbocationic Polymerization Initiators , 1996 .

[7]  F. Laschi,et al.  Reductive Decomposition of Cationic Half-Titanocene(IV) Complexes, Precursors of the Active Species in Syndiospecific Styrene Polymerization , 1996 .

[8]  R. Po',et al.  Synthesis of syndiotactic polystyrene: Reaction mechanisms and catalysis , 1996 .

[9]  P. Longo,et al.  Syndiotactic specific polymerization of styrene: driving energy of the steric control and reaction mechanism† , 1995 .

[10]  David Fischer,et al.  Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts , 1995 .

[11]  D. Pappalardo,et al.  .eta.5-C5Me5TiMe3-B(C6F5)3: A true Ziegler-Natta catalyst for the syndiotactic-specific polymerization of styrene , 1995 .

[12]  F. Laschi,et al.  A combined NMR and electron spin resonance investigation of the (C5(CH3)5)Ti(CH2C6H5)3/B(C6F5)3 catalytic system active in the syndiospecific styrene polymerization , 1995 .

[13]  D. Pappalardo,et al.  A Novel .eta.7 Coordination Mode of a Benzyl Ligand in a Cationic Zirconium Complex , 1994 .

[14]  D. Gillis,et al.  .eta.5-C5Me5TiMe3B(C6F5)3: A carbocationic olefin polymerization initiator masquerading as a Ziegler-Natta catalyst , 1994 .

[15]  C. Pellecchia,et al.  Base-free cationic mono(cyclopentadienyl)zirconium complexes: synthesis, structural characterization, and catalytic activity in olefin polymerization , 1993 .

[16]  D. Gillis,et al.  Novel arene complexes of titanium(IV), zirconium(IV), and hafnium(IV) , 1993 .

[17]  C. Pellecchia,et al.  Synthesis, crystal structure, and olefin polymerization activity of a zwitterionic .eta.6-arene zirconium tris(hydrocarbyl) , 1993 .

[18]  J. Chien,et al.  Syndiospecific polymerization of styrene. 3. Catalyst structure , 1992 .

[19]  P. Longo,et al.  Polymerization of ethylene and propene in the presence of organometillic compounds of titanium and zirconium activated with tris(pentafluorophenyl)boron , 1992 .

[20]  P. Longo,et al.  Novel Aluminoxane-free Catalysts For Syndiotactic-specific Polymerization of Styrene , 1992 .

[21]  P. Longo,et al.  Group 4 transition metal complex cations for olefin polymerization , 1991 .

[22]  Tobin J. Marks,et al.  CATION-LIKE HOMOGENEOUS OLEFIN POLYMERIZATION CATALYSTS BASED UPON ZIRCONOCENE ALKYLS AND TRIS(PENTAFLUOROPHENYL)BORANE , 1991 .

[23]  P. Longo,et al.  Catalysts for syndiotactic-specific polymerization of styrene: A tentative interpretation of some experimental data , 1991 .

[24]  A. Zambelli,et al.  Stereospecific polymerization of α-olefins: End groups, polymer structure and reaction mechanism☆ , 1991 .

[25]  C. Pellecchia,et al.  Soluble catalysts for syndiotactic polymerization of styrene , 1989 .

[26]  P. Cinquina,et al.  Preliminary kinetic investigation on syndiotactic polymerization of styrene , 1989 .

[27]  N. Ishihara,et al.  Stereospecific polymerization of styrene giving the syndiotactic polymer , 1988 .

[28]  P. Longo,et al.  Syndiotactic polymerization of styrene: mode of addition to the double bond , 1988 .

[29]  P. Longo,et al.  .beta.-Hydrogen abstraction and regiospecific insertion in syndiotactic polymerization of styrene , 1987 .

[30]  P. Longo,et al.  Synthesis of highly syndiotactic polystyrene with organometallic catalysts and monomer insertion , 1987 .

[31]  P. Longo,et al.  Polymerization of Vinyl Monomers With Achiral Titanocene Catalysts - From Like To Unlike 1,3 Asymmetric Induction , 1987 .

[32]  B. Scott,et al.  Ethylene polymerization by a cationic dicyclopentadienyl zirconium(IV) alkyl complex , 1986 .

[33]  Masahiko Kuramoto,et al.  Crystalline syndiotactic polystyrene , 1986 .

[34]  J. Ewen.  Mechanisms of stereochemical control in propylene polymerizations with soluble Group 4B metallocene/methylalumoxane catalysts , 1984 .

[35]  F. Bovey,et al.  Polymer NSR spectroscopy. II. The high resolution spectra of methyl methacrylate polymers prepared with free radical and anionic initiators , 1960 .

[36]  J. Leffler,et al.  The Behavior of Triphenylmethyl Chloride in Nitromethane , 1955 .

[37]  P. Corradini,et al.  CRYSTALLINE HIGH POLYMERS OF α-OLEFINS , 1955 .