Comparative study of coal, natural gas, and coke-oven gas based methanol to olefins processes in China

Abstract Traditional olefins production mainly depends on oil. In view of the short supply of oil, feedstocks are expanded to coal, natural gas, coke-oven gas, and methanol in China. In this paper, a comparative study of alternative olefins production is conducted from aspects of techno-economic feasibility and environmental friendliness. Results show that coal-to-olefins has a significant cost advantage. However, it suffers from low energy efficiency and serious CO2 emissions. To address these problems, this study proposes and analyses coal-to-olefins with CO2 capture, coal and natural gas-to-olefins, and coal and coke-oven gas-to-olefins. The two co-feed systems ensure great reduction of CO2 emissions and significant improving energy efficiency. They should be actively developed in regions with rich coal and gas. While in regions with rich coal and lean gas, coal-to-olefins with CO2 capture should be developed in large scale. This paper also provides several suggestions on planning these olefins production routes in China.

[1]  Li-Wang Su,et al.  The consumption, production and transportation of methanol in China: A review , 2013 .

[2]  Bin Chen,et al.  Proposal of a natural gas-based polygeneration system for power and methanol production , 2008 .

[3]  Martin Kumar Patel,et al.  Basic petrochemicals from natural gas, coal and biomass: energy use and CO2 emissions , 2009 .

[4]  Xunmin Ou,et al.  Alternative fuel buses currently in use in China: Life-cycle fossil energy use, GHG emissions and policy recommendations , 2010 .

[5]  Charles F. Harvey,et al.  The energy penalty of post-combustion CO2 capture & storage and its implications for retrofitting the U.S. installed base , 2009 .

[6]  Luo Wan Technical and Economic Evaluation and Production Practices on Coke Oven Gas to Methanol , 2012 .

[7]  Chonghun Han,et al.  Optimal Design and Decision for Combined Steam Reforming Process with Dry Methane Reforming to Reuse CO2 as a Raw Material , 2012 .

[8]  Suojiang Zhang,et al.  Coke oven gas: Availability, properties, purification, and utilization in China , 2013 .

[9]  Fu Xingguo Research of ethylene separation process simulation technology , 2011 .

[10]  Yong Jin,et al.  Study on Systems Based on Coal and Natural Gas for Producing Dimethyl Ether , 2009 .

[11]  Li Zheng,et al.  The necessity of and policy suggestions for implementing a limited number of large scale, fully integrated CCS demonstrations in China , 2011 .

[12]  Bing Zhu,et al.  Technoeconomic assessment of China’s indirect coal liquefaction projects with different CO2 capture alternatives , 2011 .

[13]  Martin Kumar Patel,et al.  Steam cracking and methane to olefins: Energy use, CO2 emissions and production costs , 2008 .

[14]  Wilhelm Kuckshinrichs,et al.  Worldwide innovations in the development of carbon capture technologies and the utilization of CO2 , 2012 .

[15]  Thomas A. Adams,et al.  Combining coal gasification and natural gas reforming for efficient polygeneration , 2011 .

[16]  G. Naterer,et al.  Cost analysis of a thermochemical Cu–Cl pilot plant for nuclear-based hydrogen production , 2008 .

[17]  Hong Dingyi,et al.  Progress of China's petrochemical industry in 2012 and outlook for 2013 , 2013 .

[18]  Yu Qian,et al.  Techno-economic performance of the coal-to-olefins process with CCS , 2014 .

[19]  Minghua Wang,et al.  Energy savings by co-production: A methanol/electricity case study , 2010 .

[20]  Hari C. Mantripragada,et al.  Techno-economic evaluation of coal-to-liquids (CTL) plants with carbon capture and sequestration , 2011 .

[21]  Yourun Li,et al.  Study on co-feed and co-production system based on coal and natural gas for producing DME and electricity , 2008 .

[22]  Yu Qian,et al.  Conceptual design of coke-oven gas assisted coal to olefins process for high energy efficiency and low CO2 emission , 2014 .

[23]  Qiang Xu,et al.  Simultaneous study on energy consumption and emission generation for an ethylene plant under different start-up strategies , 2013, Comput. Chem. Eng..

[24]  Y. Man,et al.  Techno-economic analysis of the coal-to-olefins process in comparison with the oil-to-olefins process , 2014 .

[25]  Xunmin Ou,et al.  Life-cycle energy consumption and greenhouse gas emissions for electricity generation and supply in China , 2011 .

[26]  J. A. Menéndez,et al.  An overview of novel technologies to valorise coke oven gas surplus , 2013 .