Simulating metals and mine discharges in river basins using a new integrated catchment model for metals: pollution impacts and restoration strategies in the Aries-Mures river system in Transylvania, Romania

The INtegrated CAtchment (INCA) model has been developed to simulate the impact of mine discharges on river systems. The model accounts for the key kinetic chemical processes operating as well as the dilution, mixing and redistribution of pollutants in rivers downstream of mine discharges or acid rock drainage sites. The model is dynamic and simulates the day-to-day behaviour of hydrology and eight metals (cadmium, mercury, copper, zinc, lead, arsenic, manganese and chromium) as well as cyanide and ammonia. The model is semi-distributed and can simulate catchments, sub-catchment and in-stream river behaviour. The model has been applied to the Rosia Montană Mine in Transylvania, Romania, and used to assess the impacts of old mine adits on the local catchments as well as on the downstream Aries and Mures river system. The question of mine restoration is investigated and a set of clean-up scenarios investigated. It is shown that the planned restoration will generate a much improved water quality from the mine and also alleviate the metal pollution of the river system.

[1]  William J. Mitsch,et al.  Treating coal mine drainage with an artificial wetland , 1998 .

[2]  S. Kotilainen,et al.  The importance of biological oxidation of iron in the aerobic cells of the Wheal Jane pilot passive treatment system. , 2005, The Science of the total environment.

[3]  W. Mitsch,et al.  Predicting metal retention in a constructed mine drainage wetland , 1994 .

[4]  A. Butturini,et al.  Calibration of the INCA model in a Mediterranean forested catchment: the effect of hydrological inter-annual variability in an intermittent stream , 2004 .

[5]  Andrew J. Wade,et al.  The Integrated Catchments model of Phosphorus dynamics (INCA-P), a new approach for multiple source assessment in heterogeneous river systems: model structure and equations , 2002 .

[6]  E. J. Wilson,et al.  A semi-distributed integrated flow and nitrogen model for multiple source assessment in catchments (INCA): Part II — application to large river basins in south Wales and eastern England , 1998 .

[7]  Véronique Beaujouan,et al.  A nitrogen model for European catchments: INCA, new model structure and equations , 2002 .

[8]  A. Wade,et al.  Monitoring and modelling the impacts of global change on European freshwater ecosystems. , 2006, The Science of the total environment.

[9]  C. W. Thornthwaite An Approach Toward a Rational Classification of Climate , 1948 .

[10]  S. Birkinshaw,et al.  Nitrogen transformation component for SHETRAN catchment nitrate transport modelling , 2000 .

[11]  D. Nordstrom,et al.  Negative pH and Extremely Acidic Mine Waters from Iron Mountain, California , 2000 .

[12]  M. Botz,et al.  Modeling of natural cyanide attenuation in tailings impoundments , 2000 .

[13]  P G Whitehead,et al.  Chemical behaviour of the Wheal Jane bioremediation system. , 2005, The Science of the total environment.

[14]  D Barrie Johnson,et al.  Biogeochemistry of the compost bioreactor components of a composite acid mine drainage passive remediation system. , 2005, The Science of the total environment.

[15]  S. Fennessy Design and use of wetlands for renovation of drainage from coal mines. , 1989 .

[16]  Ø. Kaste,et al.  Adaptation of the Integrated Nitrogen Model for Catchments (INCA) to seasonally snow-covered catchments , 2004 .

[17]  William J. Mitsch,et al.  Water quality, fate of metals, and predictive model validation of a constructed wetland treating acid mine drainage , 1998 .

[18]  George M. Hornberger,et al.  Modeling the Effects of Acid Deposition: Estimation of Long‐Term Water Quality Responses in a Small Forested Catchment , 1985 .

[19]  George M. Hornberger,et al.  On modeling the mechanisms that control in‐stream phosphorus, macrophyte, and epiphyte dynamics: An assessment of a new model using general sensitivity analysis , 2001 .

[20]  D. Ph.,et al.  Chemistry and Treatment of Cyanidation Wastes SECOND EDITION , 2006 .

[21]  B. Cosby,et al.  The Wheal Jane wetlands model for bioremediation of acid mine drainage. , 2005, The Science of the total environment.

[22]  P. Whitehead,et al.  Modelling impacts of pollution in river systems: a new dispersion model and a case study of mine discharges in the Abrud, Aries and Mures River System in Transylvania, Romania , 2009 .