Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process
暂无分享,去创建一个
A. Dikhtiarenko | J. Gascón | Sang-Ho Chung | E. Abou‐hamad | A. Ramírez | Sarah Komaty | T. Shoinkhorova | S. Telalović | Teng Li | G. Shterk | B. Weckhuysen | I. Mukhambetov | Xinqi Tang | Javier Ruiz-Martínez | Bart Sirks | Polina Lavrik | Pieter C. A. Bruijnicx
[1] Mingbo Wu,et al. Direct Conversion of CO2 to Ethanol Boosted by Intimacy-Sensitive Multifunctional Catalysts , 2021, ACS Catalysis.
[2] J. Gascón,et al. The Importance of Thermal Treatment on Wet-Kneaded Silica–Magnesia Catalyst and Lebedev Ethanol-to-Butadiene Process , 2021, Nanomaterials.
[3] E. Benhelal,et al. Insights into chemical stability of Mg-silicates and silica in aqueous systems using 25Mg and 29Si solid-state MAS NMR spectroscopy: Applications for CO2 capture and utilisation , 2020 .
[4] Hongwei Zhang,et al. Recent advances in catalysts for the conversion of ethanol to butadiene. , 2020, Chemistry, an Asian journal.
[5] Z. Pászti,et al. MgO−SiO2 Catalysts for the Ethanol to Butadiene Reaction: The Effect of Lewis Acid Promoters , 2020, ChemCatChem.
[6] M. Capron,et al. Ethanol-to-butadiene: the reaction and its catalysts , 2020, Catalysis Science & Technology.
[7] J. Valyon,et al. Conversion of ethanol to butadiene over mesoporous In2O3-promoted MgO-SiO2 catalysts , 2020 .
[8] A. Bell,et al. Ethanol Conversion to Butadiene over Isolated Zinc and Yttrium Sites Grafted onto Dealuminated Beta Zeolite. , 2020, Journal of the American Chemical Society.
[9] J. Schweitzer,et al. New insights of butadiene production from ethanol: Elucidation of concurrent reaction pathways and kinetic study , 2020, Chemical Engineering Journal.
[10] Christine M. Gabardo,et al. Efficient electrically powered CO2-to-ethanol via suppression of deoxygenation , 2020, Nature Energy.
[11] Thomas J. Schwartz,et al. Reaction Kinetics Analysis of Ethanol Dehydrogenation Catalyzed by MgO–SiO2 , 2020 .
[12] R. Salomão,et al. Synthesis, Dehydroxylation and Sintering of Porous Mg(OH)2-MgO Clusters: Evolution of Microstructure and Physical Properties , 2020, Interceram - International Ceramic Review.
[13] Christine M. Gabardo,et al. Cooperative CO2-to-ethanol conversion via enriched intermediates at molecule–metal catalyst interfaces , 2019, Nature Catalysis.
[14] Stacy Gates-Rector,et al. The Powder Diffraction File: a quality materials characterization database , 2019, Powder Diffraction.
[15] P. Concepción,et al. Ethanol conversion into 1,3-butadiene over a mixed Hf-Zn catalyst: Effect of reaction conditions and water content in ethanol , 2019, Fuel Processing Technology.
[16] J. Gascón,et al. Surface enhanced dynamic nuclear polarization solid-state NMR spectroscopy sheds light on Brønsted–Lewis acid synergy during the zeolite catalyzed methanol-to-hydrocarbon process† †Electronic supplementary information (ESI) available: Complete experimental procedure, supplementary NMR figures and an , 2019, Chemical science.
[17] B. Wichterlová,et al. Enhancement of propene oligomerization and aromatization by proximate protons in zeolites; FTIR study of the reaction pathway in ZSM-5 , 2019, Catalysis Science & Technology.
[18] W. Zhan,et al. A novel method for surface wettability modification of talc through thermal treatment , 2019, Applied Clay Science.
[19] Minhua Zhang,et al. Insight into the effect of promoters (M = Cu, Ag, Zn, Zr) on aldol condensation reaction based on MgO surface in the process of ethanol to 1, 3-butadiene: A comparative DFT study , 2019, Applied Surface Science.
[20] Shuang Liu,et al. Morphological control of inverted MgO-SiO2 composite catalysts for efficient conversion of ethanol to 1,3-butadiene , 2019, Applied Catalysis A: General.
[21] B. Lothenbach,et al. Characterization of magnesium silicate hydrate ( MSH ) 2 , 2019 .
[22] B. Sels,et al. Functionalised heterogeneous catalysts for sustainable biomass valorisation. , 2018, Chemical Society reviews.
[23] A. Corma,et al. Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol-to-Olefin Performance. , 2018, Chemistry.
[24] J. Baltrusaitis,et al. In Situ Spectroscopic Insights on the Molecular Structure of the MgO/SiO2 Catalytic Active Sites during Ethanol Conversion to 1,3-Butadiene , 2018, The Journal of Physical Chemistry C.
[25] F. Kapteijn,et al. Structure–performance descriptors and the role of Lewis acidity in the methanol-to-propylene process , 2018, Nature Chemistry.
[26] Landong Li,et al. Mechanistic Insights into One-Step Catalytic Conversion of Ethanol to Butadiene over Bifunctional Zn–Y/Beta Zeolite , 2018 .
[27] Encyclopedia of Geochemistry: A Comprehensive Reference Source on the Chemistry of the Earth , 2018 .
[28] J. Baltrusaitis,et al. Surface chemistry of MgO/SiO2 catalyst during the ethanol catalytic conversion to 1,3-butadiene: in-situ DRIFTS and DFT study , 2017 .
[29] I. Ivanova,et al. Mechanistic Study of Ethanol Conversion into Butadiene over Silver promoted Zirconia Catalysts , 2017 .
[30] Minhua Zhang,et al. A DFT study on the aldol condensation reaction on MgO in the process of ethanol to 1,3-butadiene: understanding the structure-activity relationship. , 2017, Physical chemistry chemical physics : PCCP.
[31] Rajamani Gounder,et al. Introducing Catalytic Diversity into Single-Site Chabazite Zeolites of Fixed Composition via Synthetic Control of Active Site Proximity , 2017 .
[32] F. Cavani,et al. Understanding the Role of Gallium as a Promoter of Magnesium Silicate Catalysts for the Conversion of Ethanol into Butadiene , 2017 .
[33] T. Bučko,et al. Catalytic conversion of ethanol to 1,3-butadiene on MgO: A comprehensive mechanism elucidation using DFT calculations , 2017 .
[34] Xiaoxiong Huang,et al. Highly active and selective binary MgO–SiO2 catalysts for the production of 1,3-butadiene from ethanol , 2017 .
[35] M. Capron,et al. Recent Breakthroughs in the Conversion of Ethanol to Butadiene , 2016 .
[36] Z. Sobalík,et al. Proton proximity – New key parameter controlling adsorption, desorption and activity in propene oligomerization over H-ZSM-5 zeolites , 2016 .
[37] T. Baba,et al. Experimental and computational studies of the roles of MgO and Zn in talc for the selective formation of 1,3-butadiene in the conversion of ethanol. , 2016, Physical chemistry chemical physics : PCCP.
[38] Takahiko Moteki,et al. Mechanistic Insight to C–C Bond Formation and Predictive Models for Cascade Reactions among Alcohols on Ca- and Sr-Hydroxyapatites , 2016 .
[39] R. Fort,et al. TEM-HRTEM study on the dehydration process of nanostructured Mg–Ca hydroxide into Mg–Ca oxide , 2016 .
[40] B. Weckhuysen,et al. Role of Magnesium Silicates in Wet-Kneaded Silica-Magnesia Catalysts for the Lebedev Ethanol-to-Butadiene Process , 2016 .
[41] R. Palkovits,et al. Formation of 1,3-butadiene from ethanol in a two-step process using modified zeolite-β catalysts , 2016 .
[42] R. Flatt,et al. Understanding silicate hydration from quantitative analyses of hydrating tricalcium silicates , 2016, Nature Communications.
[43] A. Chieregato,et al. An analysis of the chemical, physical and reactivity features of MgO–SiO2 catalysts for butadiene synthesis with the Lebedev process , 2016 .
[44] P. Baglioni,et al. Structural characterization of magnesium silicate hydrate: towards the design of eco-sustainable cements. , 2016, Dalton transactions.
[45] Mark E. Davis,et al. Effect of Heteroatom Concentration in SSZ-13 on the Methanol-to-Olefins Reaction , 2016 .
[46] B. Lothenbach,et al. Properties of magnesium silicate hydrates (M-S-H) , 2016 .
[47] Takeshi Kobayashi,et al. Dynamic Nuclear Polarization Solid-State NMR in Heterogeneous Catalysis Research , 2015 .
[48] B. Lothenbach,et al. Crystal structure of magnesium silicate hydrates (M-S-H): The relation with 2:1 Mg–Si phyllosilicates , 2015 .
[49] B. Weckhuysen,et al. Influence of acid–base properties on the Lebedev ethanol-to-butadiene process catalyzed by SiO2–MgO materials , 2015 .
[50] J. Provis,et al. Structure and properties of binder gels formed in the system Mg(OH)2-SiO2-H2O for immobilisation of Magnox sludge. , 2015, Dalton transactions.
[51] E. Makshina,et al. Ternary Ag/MgO-SiO2 catalysts for the conversion of ethanol into butadiene. , 2015, ChemSusChem.
[52] Gabriel dos Passos Gomes,et al. Orbital hybridization: a key electronic factor in control of structure and reactivity , 2015 .
[53] A. Chieregato,et al. On the chemistry of ethanol on basic oxides: revising mechanisms and intermediates in the Lebedev and Guerbet reactions. , 2015, ChemSusChem.
[54] J. Degrève,et al. Review of old chemistry and new catalytic advances in the on-purpose synthesis of butadiene. , 2014, Chemical Society reviews.
[55] Matthew D Jones,et al. Catalytic transformation of ethanol into 1,3-butadiene , 2014, Chemistry Central Journal.
[56] B. Weckhuysen,et al. Effect of preparation method and CuO promotion in the conversion of ethanol into 1,3-butadiene over SiO₂-MgO catalysts. , 2014, ChemSusChem.
[57] Esben Taarning,et al. Design of a metal-promoted oxide catalyst for the selective synthesis of butadiene from ethanol. , 2014, ChemSusChem.
[58] D. Mattia,et al. Investigations into the conversion of ethanol to 1,3-butadiene using MgO:SiO2 supported catalysts , 2014 .
[59] B. Weckhuysen,et al. Shale gas revolution: an opportunity for the production of biobased chemicals? , 2013, Angewandte Chemie.
[60] Sung Keun Lee,et al. Atomic structure and dehydration mechanism of amorphous silica: Insights from 29Si and 1H solid-state MAS NMR study of SiO2 nanoparticles , 2013 .
[61] B. Weckhuysen,et al. Chemocatalytic conversion of ethanol into butadiene and other bulk chemicals. , 2013, ChemSusChem.
[62] Robert J. Davis,et al. Heterogeneous Catalysts for the Guerbet Coupling of Alcohols , 2013 .
[63] Robert J. Davis,et al. Isotopic transient analysis of the ethanol coupling reaction over magnesia , 2013 .
[64] Mark E. Smith,et al. Magnesium analogues of aluminosilicate inorganic polymers (geopolymers) from magnesium minerals , 2013, Journal of Materials Science.
[65] Mark E. Smith,et al. Recent advances in solid-state 25mg NMR spectroscopy , 2012 .
[66] Michel Waroquier,et al. Experimental and theoretical IR study of methanol and ethanol conversion over H-SAPO-34 , 2011 .
[67] C. Grey,et al. Defects in doped LaGaO3 anionic conductors: linking NMR spectral features, local environments, and defect thermodynamics. , 2011, Journal of the American Chemical Society.
[68] C. Cheeseman,et al. Development of low pH cement systems forming magnesium silicate hydrate (M-S-H) , 2011 .
[69] C. Marichal,et al. Functionalization of synthetic talc-like phyllosilicates by alkoxyorganosilane grafting , 2010 .
[70] Peter J. Pallister,et al. Mg-25 ultra-high field solid state NMR spectroscopy and first principles calculations of magnesium compounds. , 2009, Physical chemistry chemical physics : PCCP.
[71] D. Frost,et al. Forsterite, hydrous and anhydrous wadsleyite and ringwoodite (Mg2SiO4): 29Si NMR results for chemical shift anisotropy, spin-lattice relaxation, and mechanism of hydration , 2009 .
[72] K. Klabunde,et al. IR spectral evidence of aldol condensation : Acetaldehyde adsorption over TiO2 surface , 2008 .
[73] T. Tsuchida,et al. Reaction of ethanol over hydroxyapatite affected by Ca/P ratio of catalyst , 2008 .
[74] A. Julbe,et al. SILICA MEMBRANES - BASIC PRINCIPLES , 2006 .
[75] K. Kanehashi,et al. Natural Abundance Solid-state 25Mg MQMAS NMR Studies on Inorganic Solids at a High Magnetic Field of 16.4 T , 2005 .
[76] J. Llorca,et al. Microcalorimetric and infrared studies of ethanol and acetaldehyde adsorption to investigate the ethanol steam reforming on supported cobalt catalysts. , 2005, The journal of physical chemistry. B.
[77] G. Hoatson,et al. Modelling one‐ and two‐dimensional solid‐state NMR spectra , 2002 .
[78] H. Spiess,et al. High-resolution 1H NMR spectroscopy in the solid state: very fast sample rotation and multiple-quantum coherences. , 2001, Journal of magnetic resonance.
[79] P. Aken,et al. Nanocrystalline, porous periclase aggregates as product of brucite dehydration , 2001 .
[80] J. I. D. Cosimo,et al. Acid–base properties and active site requirements for elimination reactions on alkali-promoted MgO catalysts , 2000 .
[81] S. Weiner,et al. Diagenesis in Prehistoric Caves: the Use of Minerals that Form In Situ to Assess the Completeness of the Archaeological Record , 2000 .
[82] N. Nielsen,et al. Solid-State QCPMG NMR of Low-γ Quadrupolar Metal Nuclei in Natural Abundance , 2000 .
[83] R. D. Foltz. CRC Handbook of Chemistry and Physics:A Ready-Reference Book of Chemical and Physical Data , 2000 .
[84] M. Alba,et al. High-resolution 1H MAS NMR spectra of 2∶1 phyllosilicates , 2000 .
[85] E. Iglesia,et al. Structure and Surface and Catalytic Properties of Mg-Al Basic Oxides , 1998 .
[86] K. Okada,et al. Role of Water in the Mechanochemical Reactions of MgO–SiO2Systems , 1998 .
[87] E. Iglesia,et al. Bifunctional condensation reactions of alcohols on basic oxides modified by copper and potassium , 1998 .
[88] J. Sauer,et al. 29Si NMR Chemical Shifts of Silicate Species: Ab Initio Study of Environment and Structure Effects , 1996 .
[89] Steuernagel,et al. Z Filtering in MQMAS NMR , 1996, Journal of magnetic resonance. Series A.
[90] J. L. Caillerie,et al. 29SI NMR OBSERVATION OF AN AMORPHOUS MAGNESIUM SILICATE FORMED DURING IMPREGNATION OF SILICA WITH MG(II) IN AQUEOUS SOLUTION , 1995 .
[91] J. Fripiat,et al. Catalytic properties of aluminated sepiolite in ethanol conversion , 1995 .
[92] A. Kiennemann,et al. Reactions of Acetaldehyde on CeO2 and CeO2-Supported Catalysts , 1995 .
[93] R. Černý,et al. Empirical Texture Corrections for Asymmetric Diffraction and Inclined Textures , 1995 .
[94] K. MacKenzie,et al. Thermal reactions of chrysotile revisited; a 29 Si and 25 Mg MAS NMR study , 1994 .
[95] G. Scheler,et al. Determination of distributions of the quadrupole interaction in amorphous solids by 27Al satellite transition spectroscopy. , 1993, Solid state nuclear magnetic resonance.
[96] S. Locatelli,et al. Acetaldehyde adsorption on HZSM-5 studied by infrared spectroscopy , 1992 .
[97] L. Facchini,et al. Silicon-29 NMR study of silica , 1992 .
[98] J. S. Hartman,et al. Gel synthesis of magnesium silicates: A 29Si magic angle spinning NMR study , 1990 .
[99] Alina Agüero,et al. Transformation of ethanol into 1,3-butadiene over magnesium oxide/silica catalysts , 1988 .
[100] R. Gorte,et al. An infrared spectroscopy study of simple alcohols adsorbed on H-ZSM-5 , 1987 .
[101] É. Lippmaa,et al. Solid-state high-resolution silicon-29 chemical shifts in silicates , 1984 .
[102] J. Green. Calcination of precipitated Mg(OH)2 to active MgO in the production of refractory and chemical grade MgO , 1983 .
[103] G. Maciel,et al. Cross-polarization magic-angle-spinning silicon-29 nuclear magnetic resonance study of silica gel using trimethylsilane bonding as a probe of surface geometry and reactivity , 1982 .
[104] É. Lippmaa,et al. Structural studies of silicates by solid-state high-resolution silicon-29 NMR , 1980 .
[105] R. Iler. The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties and Biochemistry of Silica , 1979 .
[106] R. D. Shannon. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides , 1976 .
[107] W. Cole. A Crystalline Hydrated Magnesium Silicate formed in the Breakdown of a Concrete Sea-wall , 1953, Nature.