Cesium-containing triple cation perovskite solar cells: improved stability, reproducibility and high efficiency† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c5ee03874j Click here for additional data file.

Today's best perovskite solar cells use a mixture of formamidinium and methylammonium as the monovalent cations. Adding cesium improves the compositions greatly.

[1]  Laura M. Herz,et al.  Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber , 2013, Science.

[2]  Felix Deschler,et al.  Bright light-emitting diodes based on organometal halide perovskite. , 2014, Nature nanotechnology.

[3]  T. Ma,et al.  CH3NH3SnxPb(1-x)I3 Perovskite Solar Cells Covering up to 1060 nm. , 2014, The journal of physical chemistry letters.

[4]  Peng Gao,et al.  A molecularly engineered hole-transporting material for efficient perovskite solar cells , 2016, Nature Energy.

[5]  Jinsong Huang,et al.  High‐Gain and Low‐Driving‐Voltage Photodetectors Based on Organolead Triiodide Perovskites , 2015, Advanced materials.

[6]  U. Jeng,et al.  Intermixing-seeded growth for high-performance planar heterojunction perovskite solar cells assisted by precursor-capped nanoparticles , 2016 .

[7]  Peng Gao,et al.  Efficient luminescent solar cells based on tailored mixed-cation perovskites , 2016, Science Advances.

[8]  S. Ogale,et al.  CH₃NH₃PbI(3-x)(BF₄)x: molecular ion substituted hybrid perovskite. , 2014, Chemical communications.

[9]  Jay B. Patel,et al.  Structured Organic–Inorganic Perovskite toward a Distributed Feedback Laser , 2016, Advanced materials.

[10]  Iris Visoly-Fisher,et al.  Temperature- and Component-Dependent Degradation of Perovskite Photovoltaic Materials under Concentrated Sunlight. , 2015, The journal of physical chemistry letters.

[11]  Wei Chen,et al.  Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers , 2015, Science.

[12]  Sang Il Seok,et al.  High-performance photovoltaic perovskite layers fabricated through intramolecular exchange , 2015, Science.

[13]  A Paul Alivisatos,et al.  Highly Luminescent Colloidal Nanoplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies. , 2015, Journal of the American Chemical Society.

[14]  Eric T. Hoke,et al.  Hysteresis and transient behavior in current–voltage measurements of hybrid-perovskite absorber solar cells , 2014 .

[15]  Peng Gao,et al.  Mixed-organic-cation perovskite photovoltaics for enhanced solar-light harvesting. , 2014, Angewandte Chemie.

[16]  Nam-Gyu Park,et al.  High‐Efficiency Perovskite Solar Cells Based on the Black Polymorph of HC(NH2)2PbI3 , 2014, Advanced materials.

[17]  C. Brabec,et al.  Detection of X-ray photons by solution-processed lead halide perovskites , 2015, Nature Photonics.

[18]  B. Rech,et al.  Monolithic perovskite/silicon-heterojunction tandem solar cells processed at low temperature , 2016 .

[19]  Prashant V Kamat,et al.  Best Practices in Perovskite Solar Cell Efficiency Measurements. Avoiding the Error of Making Bad Cells Look Good. , 2015, The journal of physical chemistry letters.

[20]  Qi Chen,et al.  Planar heterojunction perovskite solar cells via vapor-assisted solution process. , 2014, Journal of the American Chemical Society.

[21]  Robert P. H. Chang,et al.  Lead-free solid-state organic–inorganic halide perovskite solar cells , 2014, Nature Photonics.

[22]  A. Goriely,et al.  Plasmonic‐Induced Photon Recycling in Metal Halide Perovskite Solar Cells , 2015 .

[23]  Tao Xu,et al.  Pseudohalide-induced moisture tolerance in perovskite CH3 NH3 Pb(SCN)2 I thin films. , 2015, Angewandte Chemie.

[24]  Aslihan Babayigit,et al.  Intrinsic Thermal Instability of Methylammonium Lead Trihalide Perovskite , 2015 .

[25]  Mercouri G Kanatzidis,et al.  Semiconducting tin and lead iodide perovskites with organic cations: phase transitions, high mobilities, and near-infrared photoluminescent properties. , 2013, Inorganic chemistry.

[26]  Nripan Mathews,et al.  Formamidinium-Containing Metal-Halide: An Alternative Material for Near-IR Absorption Perovskite Solar Cells , 2014 .

[27]  Eric T. Hoke,et al.  Reversible photo-induced trap formation in mixed-halide hybrid perovskites for photovoltaics† †Electronic supplementary information (ESI) available: Experimental details, PL, PDS spectra and XRD patterns. See DOI: 10.1039/c4sc03141e Click here for additional data file. , 2014, Chemical science.

[28]  Dae Ho Song,et al.  Planar CH3NH3PbBr3 Hybrid Solar Cells with 10.4% Power Conversion Efficiency, Fabricated by Controlled Crystallization in the Spin‐Coating Process , 2014, Advanced materials.

[29]  David Cahen,et al.  How Important Is the Organic Part of Lead Halide Perovskite Photovoltaic Cells? Efficient CsPbBr3 Cells. , 2015, The journal of physical chemistry letters.

[30]  P. Umari,et al.  Cation-induced band-gap tuning in organohalide perovskites: interplay of spin-orbit coupling and octahedra tilting. , 2014, Nano letters.

[31]  L. Christophorou Science , 2018, Emerging Dynamics: Science, Energy, Society and Values.

[32]  Qingfeng Dong,et al.  Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals , 2015, Science.

[33]  H. Queisser,et al.  Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells , 1961 .

[34]  Henry J. Snaith,et al.  Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites , 2015, 1504.07025.

[35]  Ursula Rothlisberger,et al.  Entropic stabilization of mixed A-cation ABX3 metal halide perovskites for high performance perovskite solar cells , 2016 .

[36]  C. K. Møller Crystal Structure and Photoconductivity of Cæsium Plumbohalides , 1958 .

[37]  Jin Young Kim,et al.  Cesium-doped methylammonium lead iodide perovskite light absorber for hybrid solar cells , 2014 .

[38]  Ye Chen,et al.  Thermal and environmental stability of semi-transparent perovskite solar cells for tandems by a solution-processed nanoparticle buffer layer and sputtered ITO electrode , 2016, 2016 IEEE 43rd Photovoltaic Specialists Conference (PVSC).

[39]  M. Grätzel,et al.  Sequential deposition as a route to high-performance perovskite-sensitized solar cells , 2013, Nature.

[40]  Henry J. Snaith,et al.  Efficient planar heterojunction perovskite solar cells by vapour deposition , 2013, Nature.

[41]  M. Grätzel,et al.  Title: Long-Range Balanced Electron and Hole Transport Lengths in Organic-Inorganic CH3NH3PbI3 , 2017 .

[42]  Peng Gao,et al.  Silolothiophene-linked triphenylamines as stable hole transporting materials for high efficiency perovskite solar cells , 2015 .

[43]  Young Chan Kim,et al.  Compositional engineering of perovskite materials for high-performance solar cells , 2015, Nature.

[44]  Shihe Yang,et al.  Inkjet printing and instant chemical transformation of a CH3NH3PbI3/nanocarbon electrode and interface for planar perovskite solar cells. , 2014, Angewandte Chemie.

[45]  Aron Walsh,et al.  Assessment of polyanion (BF4− and PF6−) substitutions in hybrid halide perovskites , 2015 .

[46]  Alan D. F. Dunbar,et al.  Efficient planar heterojunction mixed-halide perovskite solar cells deposited via spray-deposition , 2014 .

[47]  Yao Sun,et al.  Enhancement of perovskite-based solar cells employing core-shell metal nanoparticles. , 2013, Nano letters.

[48]  Tsutomu Miyasaka,et al.  Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. , 2009, Journal of the American Chemical Society.

[49]  Paul L. Burn,et al.  Electro-optics of perovskite solar cells , 2014, Nature Photonics.

[50]  R. Sarpong,et al.  Bio-inspired synthesis of xishacorenes A, B, and C, and a new congener from fuscol† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc02572c , 2019, Chemical science.

[51]  Henk J. Bolink,et al.  Perovskite solar cells employing organic charge-transport layers , 2013, Nature Photonics.

[52]  N. Park,et al.  Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% , 2012, Scientific Reports.

[53]  T. Dittrich,et al.  Precipitation of CH3NH3PbCl3 in CH3NH3PbI3 and Its Impact on Modulated Charge Separation , 2015 .

[54]  J. Berry,et al.  Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys , 2016 .

[55]  M. Grätzel,et al.  Working Principles of Perovskite Photodetectors: Analyzing the Interplay Between Photoconductivity and Voltage‐Driven Energy‐Level Alignment , 2015 .

[56]  Bernd Rech,et al.  A mixed-cation lead mixed-halide perovskite absorber for tandem solar cells , 2016, Science.

[57]  Oleksandr Voznyy,et al.  Perovskite Thin Films via Atomic Layer Deposition , 2015, Advanced materials.

[58]  M. Johnston,et al.  Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells , 2014 .

[59]  V. M. Goldschmidt,et al.  Die Gesetze der Krystallochemie , 1926, Naturwissenschaften.

[60]  Nripan Mathews,et al.  Low-temperature solution-processed wavelength-tunable perovskites for lasing. , 2014, Nature materials.

[61]  J. Noh,et al.  Chemical management for colorful, efficient, and stable inorganic-organic hybrid nanostructured solar cells. , 2013, Nano letters.

[62]  F. Giordano,et al.  Enhanced electronic properties in mesoporous TiO2 via lithium doping for high-efficiency perovskite solar cells , 2016, Nature Communications.

[63]  Sung Min Cho,et al.  Formamidinium and Cesium Hybridization for Photo‐ and Moisture‐Stable Perovskite Solar Cell , 2015 .

[64]  Qingfeng Dong,et al.  Efficient, high yield perovskite photovoltaic devices grown by interdiffusion of solution-processed precursor stacking layers , 2014 .

[65]  Michael Grätzel,et al.  Highly efficient planar perovskite solar cells through band alignment engineering , 2015 .

[66]  J. Teuscher,et al.  Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites , 2012, Science.