Incorporation of Sb in InAs∕GaAs quantum dots

The formation of a quaternary InGaAsSb alloy is shown to occur in the core of epitaxial GaSb capped InAs∕GaAs quantum dots emitting at 1.3μm. The existence of the four constituent elements is demonstrated by using spatially resolved low-loss electron energy loss spectroscopy and aberration-corrected high angle annular dark field scanning transmission electron microscopy. The intermixing process giving rise to the formation of this quaternary alloy takes place despite the large miscibility gap between InAs and GaSb binary compounds, and is probably driven by the existence of strain in the quantum dots.

[1]  B. Alén,et al.  Enhancement of the room temperature luminescence of InAs quantum dots by GaSb capping , 2007 .

[2]  Pm Paul Koenraad,et al.  Suppression of InAs∕GaAs quantum dot decomposition by the incorporation of a GaAsSb capping layer , 2007 .

[3]  M. Patrini,et al.  Quantum dot strain engineering of InAs/InGaAs nanostructures , 2007 .

[4]  Yasuhiko Arakawa,et al.  1.55μm emission from InAs∕GaAs quantum dots grown by metal organic chemical vapor deposition via antimony incorporation , 2006 .

[5]  John P. R. David,et al.  Room-temperature 1.6μm light emission from InAs∕GaAs quantum dots with a thin GaAsSb cap layer , 2006 .

[6]  Daniel Granados,et al.  Room temperature emission at 1.6μm from InGaAs quantum dots capped with GaAsSb , 2005 .

[7]  N. Yamamoto,et al.  Strong photoluminescence and laser operation of InAs quantum dots covered by a GaAsSb strain-reducing layer , 2005 .

[8]  A. Papworth,et al.  Elemental mapping using the Ga 3d and In 4d transitions in the ε2 absorption spectra derived from EELS , 2004 .

[9]  P. Ruterana,et al.  Nanoscale EELS analysis of InGaN/GaN heterostructures , 2004 .

[10]  R. Asomoza,et al.  The miscibility gap of InxGa1?xSbyAs1?y alloys , 2004 .

[11]  Gilles Patriarche,et al.  GaInAs/GaAs quantum-well growth assisted by Sb surfactant: Toward 1.3 μm emission , 2004 .

[12]  P. Werner,et al.  Ripening of self-organized InAs quantum dots , 2004 .

[13]  Dieter Bimberg,et al.  450 meV hole localization in GaSb/GaAs quantum dots , 2003 .

[14]  Alexey E. Zhukov,et al.  GaAs-based long-wavelength lasers , 2000 .

[15]  S. M. Chen,et al.  Measurement of AlInAsSb/GaInAsSb heterojunction band offset by photoluminescence spectroscopy , 1999 .

[16]  M. Inoue,et al.  Surface reaction of III V compound semiconductors irradiated by As and Sb molecular beams , 1991 .

[17]  G. B. Stringfellow Miscibility gaps in quaternary III/V alloys , 1982 .