Improving the performance of fluidized bed biomass/waste gasifiers for distributed electricity: A new three-stage gasification system

Methods to increase the conversion of char and tar in fluidized bed gasifiers (FBG) are discussed, with the focus on small to medium-size biomass/waste gasifiers for power production (from 0.5 to 10 MWe). Optimization of such systems aims at (i) maximizing energy utilization of the fuel (maximizing char conversion), (ii) minimizing secondary treatment of the gas (by avoiding complex tar cleaning), and (iii) application in small biomass-to-electricity gasification plants. The efficiency of various measures to increase tar and char conversion within a gasification reactor (primary methods) is discussed. The optimization of FBG by using in-bed catalysts, by addition of steam and enriched air as gasification agent, and by secondary-air injection, although improving the process, is shown to be insufficient to attain the gas purity required for burning the gas in an engine to produce electricity. Staged gasification is identified as the only method capable of reaching the targets mentioned above with reasonable simplicity and cost, so it is ideal for power production. A promising new stage gasification process is presented. It is based on three stages: FB devolatilization, non-catalytic air/steam reforming of the gas coming from the devolatilizer, and chemical filtering of the gas and gasification of the char in a moving bed supplied with the char generated in the devolatilizer. Design considerations and comparison with one-stage FBG are discussed.

[1]  Susanna Nilsson,et al.  Devolatilization of wood and wastes in fluidized bed , 2010 .

[2]  Andrew Narvaez,et al.  Biomass gasification with air in an atmospheric bubbling fluidized bed. Effect of six operational variables on the quality of the produced raw gas , 1996 .

[3]  Pedro Ollero,et al.  Air–steam gasification of biomass in a fluidised bed: Process optimisation by enriched air , 2009 .

[4]  Pedro Ollero,et al.  Tar Reduction by Primary Measures in an Autothermal Air-Blown Fluidized Bed Biomass Gasifier , 2010 .

[5]  Kj Krzysztof Ptasinski,et al.  Primary measures to reduse tar formation in fluidised-bed biomass gasifiers , 2004 .

[6]  L. R. Glicksman,et al.  Dynamic similarity in fluidization , 1994 .

[7]  Pedro Ollero,et al.  Air—Steam Gasification of Biomass in a Fluidized Bed under Simulated Autothermal and Adiabatic Conditions , 2008 .

[8]  Wolfgang Krumm,et al.  Autothermal two-stage gasification of low-density waste-derived fuels. , 2007 .

[9]  Joachim Werther,et al.  Three-dimensional modeling of a circulating fluidized bed gasifier for sewage sludge , 2005 .

[10]  Pedro Ollero,et al.  The Effect of Temperature and Steam Concentration on the Yields of Tar Compounds in Fluidized Bed Pyrolysis , 2011 .

[11]  W. Blasiak,et al.  Effect of operating conditions on tar and gas composition in high temperature air/steam gasification (HTAG) of plastic containing waste , 2006 .

[12]  Jesper Ahrenfeldt,et al.  The design, construction and operation of a 75kW two-stage gasifier , 2006 .

[13]  Susanna Nilsson,et al.  Gasification reactivity of char from dried sewage sludge in a fluidized bed , 2012 .

[14]  Jun-ichiro Hayashi,et al.  Rapid conversion of tar and char from pyrolysis of a brown coal by reactions with steam in a drop-tube reactor , 2000 .

[15]  Kunio Yoshikawa,et al.  Performance optimization of two-staged gasification system for woody biomass , 2007 .

[16]  Pedro Ollero,et al.  Optimization of char and tar conversion in fluidized bed biomass gasifiers , 2013 .

[17]  A. Gómez-Barea,et al.  Gasification of biomass and waste in a staged fluidized bed gasifier: Modeling and comparison with one-stage units , 2012 .

[18]  Jun-ichiro Hayashi,et al.  Mechanism of decomposition of aromatics over charcoal and necessary condition for maintaining its activity , 2008 .

[19]  Jun-ichiro Hayashi,et al.  Roles of inherent metallic species in secondary reactions of tar and char during rapid pyrolysis of brown coals in a drop-tube reactor ☆ , 2002 .

[20]  H. den Uil CASST: A New and Advanced Process for Biomass Gasification , 2008 .

[21]  A. Gómez-Barea,et al.  Characterization and prediction of biomass pyrolysis products , 2011 .

[22]  Kj Krzysztof Ptasinski,et al.  A review of the primary measures for tar elimination in biomass gasification processes , 2003 .

[23]  S. C. Bhattacharya,et al.  Multi-stage reactor for thermal gasification of wood , 1994 .

[24]  B. Kelleher,et al.  Review of literature on catalysts for biomass gasification , 2001 .

[25]  Bo G Leckner,et al.  Gasification of Biomass and Waste , 2010 .

[26]  Herri Susanto,et al.  A moving-bed gasifier with internal recycle of pyrolysis gas , 1996 .

[27]  Esa Kurkela,et al.  Catalytic hot gas cleaning of gasification gas , 1996 .

[28]  J. T. Riley,et al.  A novel biomass air gasification process for producing tar-free higher heating value fuel gas , 2006 .

[29]  Luis Puigjaner,et al.  Removal of tar by secondary air in fluidised bed gasification of residual biomass and coal , 1999 .

[30]  T. Nussbaumer,et al.  Gas cleaning for IC engine applications from fixed bed biomass gasification , 1999 .

[31]  Gerrit Brem,et al.  Experimental comparison of biomass chars with other catalysts for tar reduction , 2008 .

[32]  A. Gómez-Barea,et al.  Modeling of biomass gasification in fluidized bed , 2010 .