Very Low-Pressure Pyrolysis (VLPP); A Versatile Kinetic Tool

The theory and applications of the very low-pressure pyrolysis technique to the study of the rates and mechanisms of unimolecular reactions, radical-radical, and radical-molecule bimolecular reactions, surface recombination of atoms, heterogeneous reactions, and vibrational energy transfer are reviewed.

[1]  D. Golden,et al.  The kinetics of reaction of the by-products of ablative materials at high temperatures and the rate of heat transfer between hot surfaces and reactive gases , 1971 .

[2]  W. Tsang Hydrocarbon decomposition. 6. Thermal decomposition of 3,4-dimethylhexane, 2,2,3-trimethylpentane, tert-butylcyclohexane, and related hydrocarbons , 1972 .

[3]  D. Golden,et al.  Very low‐pressure pyrolysis. VIII. The decomposition of Di‐t‐amyl peroxide , 1973 .

[4]  D. Golden,et al.  Very low‐pressure pyrolysis. IX. The decomposition of azoethane, azoisopropane, and 2,2′‐azoisobutane , 1973 .

[5]  D. Golden,et al.  Very low‐pressure pyrolysis: VI. The decomposition of ethyl acetate , 1972 .

[6]  D. Golden,et al.  Ver low pressure pyrolysis. V. Benzylamine, N-methylbenzylamine, and N,N-dimethylbenzylamine and the heat of formation of the amino, methylamino, and dimethylamino radicals , 1972 .

[7]  D. Golden,et al.  Absolute rate constants for radical-molecule reactions over a wide temperature range. The heat of formation and entropy of the methyl radical , 1969 .

[8]  D. Golden,et al.  Equilibrium constant for allyl radical recombination. Direct measurement of "allyl resonance energy" , 1969 .

[9]  D. Golden,et al.  Very low‐pressure pyrolysis. IV. The decomposition of i‐propyl iodide and n‐propyl iodide , 1971 .

[10]  W. Tsang Thermal Decomposition of 2,3‐Dimethylbutane in a Single‐Pulse Shock Tube , 1965 .

[11]  A. U. Blackham,et al.  Thermal Decomposition of 1,1"-Azobutane, 1,1"-Azoisobutane, 2,2"-Azobutane and 2,2"-Azoisobutane1-3 , 1962 .

[12]  S. Benson,et al.  Very low pressure pyrolysis. II. Decomposition of nitropropanes , 1967 .

[13]  J. R. Pierce,et al.  Scientific foundations of vacuum technique , 1949 .

[14]  D. Barton,et al.  The kinetics of the dehydrochlorination of substituted hydrocarbons. Part V.—The mechanism of the thermal decompositions of 2-chloropropane and 1 : 2-dichloropropane , 1950 .

[15]  W. Tsang Thermal Decomposition of Hexamethylethane, 2,2,3‐Trimethylbutane, and Neopentane in a Single‐Pulse Shock Tube , 1966 .

[16]  A. Czanderna Fundamentals of gas-surface interactions: Edited by H. Saltsburg, J. N. Smith, and M. Rogers. Academic Press, New York and London, August 1967 , 1968 .

[17]  S. Benson foundations of chemical kinetics , 1960 .

[18]  D. Golden,et al.  Very low‐pressure pyrolysis. VII. The decomposition of methylhydrazine, 1,1‐dimethylhydrazine, 1,2‐dimethylhydrazine, and tetramethylhydrazine. Concerted deamination and dehydrogenation of methylhydrazine , 1972 .

[19]  D. Golden,et al.  Pyrolysis of cyclobutane , 1972 .

[20]  Samuel Glasstone,et al.  The Theory Of Rate Processes , 1941 .

[21]  S. Benson,et al.  Kinetic Data on Gas Phase Unimolecular Reactions , 1970 .

[22]  S. Benson,et al.  Very low pressure pyrolysis. III. tert-Butyl hydroperoxide in fused silica and stainless steel reactors , 1968 .

[23]  J. Levy,et al.  The Thermal Decomposition of 2,2'-Azoisobutane1 , 1960 .