Magnesium Borohydride: From Hydrogen Storage to Magnesium Battery**

Beyond hydrogen storage: The first example of reversible magnesium deposition/stripping onto/from an inorganic salt was seen for a magnesium borohydride electrolyte. High coulombic efficiency of up to 94 % was achieved in dimethoxyethane solvent. This Mg(BH(4))(2) electrolyte was utilized in a rechargeable magnesium battery.

[1]  M. Hackert,et al.  Coordination chemistry of alkali and alkaline earth cations: Synthesis and crystal structure of potassium(benzo-15-crown-5)2 [3,5-dinitrobenzoate(3,5-dinitrobenzoic acid)2] , 1985 .

[2]  P. Bird,et al.  Spectroscopic studies on derivatives of aluminium borohydride , 1968 .

[3]  W. Price The Infra‐Red Absorption Spectra of Some Metal Borohydrides , 1949 .

[4]  B. Bogdanovic,et al.  Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials , 1997 .

[5]  D. Shriver,et al.  Solvent and cation dependence of the tetrahydroborate, BH4-, Raman spectrum , 1973 .

[6]  M. Armand,et al.  Building better batteries , 2008, Nature.

[7]  Allen G. Oliver,et al.  Electrolyte roadblocks to a magnesium rechargeable battery , 2012 .

[8]  R. Zidan,et al.  Spectroscopic Evidence for Atmospheric Stabilization of Aluminum Borohydride in Polydimethylsiloxane Grease , 2012, Applied Spectroscopy.

[9]  D. Aurbach,et al.  Molten salt synthesis (MSS) of Cu2Mo6S8—New way for large-scale production of Chevrel phases , 2006 .

[10]  E. Levi,et al.  Prototype systems for rechargeable magnesium batteries , 2000, Nature.

[11]  R. Zidan,et al.  Alanate–borohydride material systems for hydrogen storage applications , 2012 .

[12]  H. Hagemann,et al.  Insight into Mg(BH4)2 with synchrotron X-ray diffraction: Structure revision, crystal chemistry, and anomalous thermal expansion , 2009 .

[13]  H. Nöth,et al.  The Structure of Some Amine Solvates of Magnesium Bis(tetrahydroborate) and DFT Calculations on Solvates of Lithium Tetrahydroborate , 2003 .

[14]  Allen G. Oliver,et al.  Structure and compatibility of a magnesium electrolyte with a sulphur cathode , 2011, Nature communications.

[15]  Hans-Rudolf Hagemann,et al.  Porous and Dense Magnesium Borohydride Frameworks: Synthesis, Stability, and Reversible Absorption of Guest Species. , 2012 .

[16]  A. Züttel,et al.  Recent Progress in Metal Borohydrides for Hydrogen Storage , 2011 .

[17]  M. Fichtner,et al.  Synthesis and properties of magnesium tetrahydroborate, Mg(BH4)2 , 2007 .

[18]  D. Aurbach,et al.  Progress in nonaqueous magnesium electrochemistry , 2007 .

[19]  H. Nöth Metalltetrahydridoborate und Tetrahydridometallate, 11 [1] Zur Kristall- und Molekülstruktur von Magnesiumtetrahydridoborat Mg(BH4)2 • 3 THF / Metal Tetrahydridoborates and Tetrahydridoborato Metallates, 11 [1] The Crystal and Molecular Structure of Magnesium Tetrahydridoborate Mg(BH4)2 • 3 THF , 1982 .