Modeling of EUV emission from xenon and tin plasma sources for nanolithography

Abstract Over the last decade there has been a major effort devoted to the development of efficient extreme UV sources designed for nanolithography, operating in the 13.5-nm range. Possible sources include laser-produced plasmas and discharge-produced plasmas. This paper, devoted to the modeling of such emission, emphasizes the atomic physics effects and particularly the effects of configuration interaction. Two types of theoretical approaches are presented, one involving the detailed computation with the parametric potential code H ullac , the other based on the superconfiguration code SCO. Computations of emission spectra in xenon and tin are presented. The possible influence of non-local thermodynamic equilibrium (NLTE) effects is investigated using populations given by the simple collisional-radiative formulas from Colombant and Tonon. Convergence to LTE is analyzed in the tin case.

[1]  Joseph Reader,et al.  4p64d8–(4d75p + 4d74f + 4p54d9) Transitions in Xe XI , 2004 .

[2]  E. B. Saloman,et al.  Energy Levels and Observed Spectral Lines of Xenon, Xe I through Xe LIV , 2004 .

[3]  J. B. Dance,et al.  X-Rays From Laser Plasmas: Generation and Applications , 1998 .

[4]  H. Furth,et al.  Plasma diagnostic techniques , 1965 .

[5]  Joseph Reader,et al.  High-resolution spectrum of xenon ions at 13.4 nm. , 2003, Optics letters.

[6]  I. Fomenkov,et al.  Extreme ultraviolet emission spectra of highly ionized xenon and their comparison with model calculations , 2004 .

[7]  G. Tonon,et al.  X‐ray emission in laser‐produced plasmas , 1973 .

[8]  Larissa Juschkin,et al.  Comparison of different source concepts for EUVL , 2001, SPIE Advanced Lithography.

[9]  Gerry O'Sullivan,et al.  4d–4f emission resonances in laser-produced plasmas , 1981 .

[10]  R. D. Cowan,et al.  The Theory of Atomic Structure and Spectra , 1981 .

[11]  D. Attwood Soft X-Rays and Extreme Ultraviolet Radiation , 1999 .

[12]  J. Bauche,et al.  Recent progress in the global description of atomic transitions , 1996 .

[13]  Katsunobu Nishihara,et al.  Conversion efficiency of LPP sources , 2006 .

[14]  A. Bar-Shalom,et al.  Configuration interaction in LTE spectra of heavy elements , 1992 .

[15]  Thomas Blenski,et al.  A superconfiguration code based on the local density approximation , 2000 .

[16]  Klapisch,et al.  Interpretation of the quasicontinuum band emitted by highly ionized rare-earth elements in the 70-100-Å range. , 1987, Physical review. A, General physics.

[17]  M. Klapisch,et al.  HULLAC, an integrated computer package for atomic processes in plasmas , 2001 .

[18]  T. Ceccotti,et al.  Emissive properties of xenon ions from a laser-produced plasma in the 100–140 Å spectral range: Atomic-physics analysis of the experimental data , 2003 .

[19]  Tiberio Ceccotti EUV lithography development in Europe: present status and perspectives , 2004, SPIE Optics + Photonics.

[20]  Goldstein,et al.  Super-transition-arrays: A model for the spectral analysis of hot, dense plasma. , 1989, Physical review. A, General physics.

[21]  G. Dattoli,et al.  Extreme Ultraviolet (EUV) Sources for Lithography based on Synchrotron Radiation , 2001, physics/0103055.

[22]  J. Bauche,et al.  Breakdown of jj coupling in spin–orbit-split atomic transition arrays , 1991 .

[23]  Gerry O'Sullivan,et al.  Charge-dependent wavefunction collapse in ionised xenon , 1982 .