Recycling of Waelz slag and waste foundry sand in red clay bricks

Abstract Foundry sand and Waelz slag have been used to replace clay in the production of red clay bricks. These are both problematic wastes in Northern Spain that are currently landfilled. A semi-scale industrial trial incorporating 20–40 weight percent additions to bricks has been completed. Trial samples have been compared with control bricks containing no waste additions. The physico-chemical, mechanical and environmental properties have been evaluated. Incorporating Waelz slag and foundry sand in the mix allows the production of more resource efficient, lower cost bricks. Performance benefits included improved extrusion properties during forming, lower water absorption of the sintered brick due to reduced connected porosity, significant reductions in CO 2 and NOx emissions during firing and improvements in potential leachability of some pollutants in relation to samples containing only Waelz slag or foundry sand. However, it is necessary to limit the addition of Waelz slag to less than 30 wt.% in order to meet regulatory leaching limits for Mo. Other physico-chemical and mechanical parameters were not significantly affected by the addition of these industrial by-products.

[1]  Zoubeir Lafhaj,et al.  Polluted river sediments from the North region of France: Treatment with Novosol® process and valorization in clay bricks , 2008 .

[2]  J. Torralba,et al.  Optimization of the sintering process of raw material wastes , 1999 .

[3]  Zoubeir Lafhaj,et al.  Valorization of stabilized river sediments in fired clay bricks: factory scale experiment. , 2009, Journal of hazardous materials.

[4]  Kae‐Long Lin,et al.  Feasibility study of using brick made from municipal solid waste incinerator fly ash slag. , 2006, Journal of hazardous materials.

[5]  C. Cheeseman,et al.  Lightweight bricks manufactured from water treatment sludge and rice husks. , 2009, Journal of hazardous materials.

[6]  A. H. Yegneswaran,et al.  Thermal treatment of toxic metals of industrial hazardous wastes with fly ash and clay. , 2007, Journal of hazardous materials.

[7]  T Uslu,et al.  Use of boron waste as an additive in red bricks. , 2004, Waste management.

[8]  Javier R. Viguri,et al.  Sintering behaviour of ceramic bodies from contaminated marine sediments , 2008 .

[9]  A. Andrés,et al.  Valorization of Foundry Sand in Clay Bricks at Industrial Scale , 2010 .

[10]  Dachamir Hotza,et al.  Effect of marble and granite sludge in clay materials , 2006 .

[11]  Hans A. van der Sloot,et al.  Assessment of chemical sensitivity of Waelz slag , 2000 .

[12]  S. Maschio,et al.  Possible production of ceramic tiles from marine dredging spoils alone and mixed with other waste materials. , 2006, Journal of hazardous materials.

[13]  Javier R. Viguri,et al.  Physico-chemical characterisation of bricks all through the manufacture process in relation to efflorescence salts , 2009 .

[14]  Fang He,et al.  Low temperature pyrolysis characteristics of major components of biomass , 2009 .

[15]  J. Rincón,et al.  Application of sewage sludge in the manufacturing of ceramic tile bodies , 2005 .

[16]  Seija P. E. Forsmo Oxidation of magnetite concentrate powders during storage and drying , 2005 .

[17]  A. R. Boccaccini,et al.  Production of novel ceramic materials from coal fly ash and metal finishing wastes , 2008 .

[18]  Y. Pontikes,et al.  Use of boron wastes in the production of heavy clay ceramics , 2007 .

[19]  C. Nassaralla,et al.  Standard free energy of formation of calcium chromate , 2006 .

[20]  Carlos Perez Bergmann,et al.  Environmental and technical aspects of the utilisation of tannery sludge as a raw material for clay products , 2002 .

[21]  B Fabbri,et al.  A proposal for reducing F and Cl emission in the brick industry using new formulations , 2002 .

[22]  R. R. Menezes,et al.  Use of granite sawing wastes in the production of ceramic bricks and tiles , 2005 .

[23]  Pen-Chi Chiang,et al.  Utilization of sludge as brick materials , 2003 .

[24]  M. Anderson,et al.  The inclusion of alum-based waterworks sludge (WTR) in commercial clay building bricks , 2003 .

[25]  Deng-Fong Lin,et al.  Effect of heating temperature on the sintering characteristics of sewage sludge ash. , 2006, Journal of hazardous materials.

[26]  Sergio Neves Monteiro,et al.  Incorporation of fine steel sludge waste into red ceramic , 2006 .

[27]  L. Montanaro,et al.  Sintering behaviour of pressed red mud wastes from zinc hydrometallurgy , 2001 .

[28]  T. Kavas,et al.  Use of boron waste as a fluxing agent in production of red mud brick , 2006 .

[29]  C. Bergmann,et al.  Fly ash of mineral coal as ceramic tiles raw material. , 2007, Waste management.

[31]  J. Viguri,et al.  Leaching behaviour of sintered contaminated marine sediments , 2008 .

[32]  M. Raimondo,et al.  Orimulsion fly ash in clay bricks—part 3: chemical stability of ash-bearing products , 2002 .

[33]  J. Labrincha,et al.  Effect of experimental variables on the inertization of galvanic sludges in clay-based ceramics. , 2004, Journal of hazardous materials.

[34]  David Gibbs,et al.  Reflections on implementing industrial ecology through eco-industrial park development , 2007 .

[35]  Geert De Schutter,et al.  Effect of used-foundry sand on the mechanical properties of concrete , 2009 .

[36]  J R Viguri,et al.  Technological behaviour and recycling potential of spent foundry sands in clay bricks. , 2011, Journal of environmental management.

[37]  Christopher R. Cheeseman,et al.  Properties and microstructure of sintered incinerator bottom ash , 2002 .

[38]  H. Chiang,et al.  Characteristics of bricks made from waste steel slag. , 2004, Waste management.

[39]  M. Hernández-Crespo,et al.  The use of a calcium carbonate residue from the stone industry in manufacturing of ceramic tile bodies. , 2009 .