Absorption of Sulphur Dioxide with Sodium Citrate Buffer Solution in a Rotating Packed Bed

Abstract Absorption of SO 2 from a SO 2 /air mixture with sodium citrate buffer solution was investigated using a rotating packed bed (RPB) in laboratory scale. The effects of operating parameters, such as the rotation speed of RPB, liquid-gas ratio, inlet gas flow rate, inlet concentration of SO 2 in flue gas, sodium citrate buffer concentration and initial pH of absorption solution, on the SO 2 concentration in the absorption solution or removal efficiency of SO 2 were examined. Incremental rate of sulfate radical ions in the absorption solution was also examined. Experimental results indicate that the efficiency of this regenerative process will be improved by using RPB under appropriate operating conditions, and the generation of SO 2− 4 will be restrained in the process in RPB.

[1]  Chung-Sung Tan,et al.  Reduction of CO2 concentration in a zinc/air battery by absorption in a rotating packed bed , 2006 .

[2]  Y. Wu,et al.  Desulfurization in the gas-continuous impinging stream gas–liquid reactor , 2007 .

[3]  Jianfeng Chen,et al.  Facile Preparation of Danazol Nanoparticles by High-Gravity Anti-solvent Precipitation (HGAP) Method , 2009 .

[4]  E. Békássy-Molnár,et al.  Sulphur dioxide absorption in air-lift-tube absorbers by sodium citrate buffer solution , 2005 .

[5]  Lei Shao,et al.  Modeling of the Precipitation Process in a Rotating Packed Bed and Its Experimental Validation , 2010 .

[6]  Wei Wu,et al.  Synthesis of Petroleum Sulfonate Surfactant by Different Sulfonating Agent with Application of HIGEE Technology , 2010 .

[7]  R. Aguado,et al.  Absorption of SO2 into tribasic sodium citrate solutions , 1993 .

[8]  Xiuping Li,et al.  Continuous Distillation Experiment with Rotating Packed Bed , 2008 .

[9]  Xiuping Li,et al.  Characteristics of Fin Baffle Packing Used in Rotating Packed Bed , 2010 .

[10]  Zhongbiao Wu,et al.  [Sodium-enhanced limestone wet FGD in rotating-stream tray scrubber]. , 2002, Huan jing ke xue= Huanjing kexue.

[11]  L. Akyalçın,et al.  Flue gas desulfurization by citrate process and optimization of working parameters , 2010 .

[12]  Lei Shao,et al.  Synthesis of nano-fibers of aluminum hydroxide in novel rotating packed bed reactor , 2003 .

[13]  Jianfeng Chen,et al.  SYNTHESIS AND APPLICATION OF NANOPARTICLES BY A HIGH GRAVITY METHOD , 2005 .

[14]  Luyao Zhang,et al.  Absorption of NOx into Nitric Acid Solution in Rotating Packed Bed , 2010 .

[15]  X. Lan,et al.  Study on Desorbing Sulfur Dioxide from Citrate Solution by Ultrasonification , 2007 .

[16]  Olav Erga Sulfur dioxide recovery by means of adipic acid buffers , 1986 .

[17]  Partha S. Goswami,et al.  Process Intensification in Rotating Packed Beds (HIGEE): An Appraisal , 2004 .

[18]  B. K. Dutta,et al.  Absorption of sulfur dioxide in citric acid-sodium citrate buffer solutions , 1987 .

[19]  Liu Laishuan Flue Gas Desulfurization by Rotating Packed Bed , 2001 .

[20]  Kim Dam-Johansen,et al.  Experimental investigation and modeling of a wet flue gas desulfurization pilot plant , 1998 .

[21]  S. Weiss,et al.  The kinetics of the absorption of sulfur dioxide in calcium hydroxide suspensions , 1991 .

[22]  Abraham Tamir,et al.  Modeling and experimental studies of SO2 absorption in coaxial cylinders with impinging streams: Part I , 2000 .

[23]  Rob Klaassen,et al.  Achieving flue gas desulphurization with membrane gas absorption , 2003 .

[24]  W. Juan Hydroxyl ammonium ionic liquids: synthesis and flue gas desulfurization , 2009 .