Preparation and Performance of Novel Biodegradable Polymeric Materials Based on Hydrolyzed Proteins for Agricultural Application

Aim of the research is the development of biodegradable polymeric materials based on hydrolyzed proteins, derived from waste products of the leather industry. Particular attention has been devoted to evaluate the application of such biobased materials in the agricultural practice of mulching. Biobased mulching films were generated in situ by low-pressure spraying of polymeric water dispersion on the soil; the mulches were tested in an ornamental cultivation carried out inside a greenhouse. The innovative spray films based on biodegradable components lasted in the field up to 12 months, keeping their mulching effect, thus guarantying weed suppression and preserving soil aggregates.

[1]  M. Malinconico,et al.  Physical behavior of biodegradable alginate–poly(vinyl alcohol) blend films , 2005 .

[2]  K. Réczey,et al.  Reducing water absorption in compostable starch-based plastics , 2005 .

[3]  F. Mantia,et al.  Durability of a starch-based biodegradable polymer , 2007 .

[4]  Giuliano Vox,et al.  Effects of Solar Radiation on the Radiometric Properties of Biodegradable Films for Agricultural Applications , 2004 .

[5]  Thitisilp Kijchavengkul,et al.  Assessment of aliphatic-aromatic copolyester biodegradable mulch films. Part II: laboratory simulated conditions. , 2008, Chemosphere.

[6]  E. Chiellini,et al.  Characterization of Biodegradable Composite Films Prepared from Blends of Poly(Vinyl Alcohol), Cornstarch, and Lignocellulosic Fiber , 2005 .

[7]  Gabriella Santagata,et al.  Addition of glycerol plasticizer to seaweeds derived alginates : Influence of microstructure on chemical-physical properties , 2007 .

[8]  Giuliano Vox,et al.  Effects of the radiometric properties of innovative biodegradable mulching materials on snapdragon cultivation , 2007 .

[9]  Alberto Pardossi,et al.  Sustainable Greenhouse Systems. , 2010 .

[10]  E. Chiellini,et al.  Composite films based on waste gelatin: thermal–mechanical properties and biodegradation testing , 2001 .

[11]  Mathieu Ngouajio,et al.  Polyethylene and biodegradable mulches for agricultural applications: a review , 2012, Agronomy for Sustainable Development.

[12]  P. Caliceti,et al.  Enzyme modification by MPEG with an amino acid or peptide as spacer arms , 1991, Applied Biochemistry and Biotechnology.

[13]  E. Schettini,et al.  Evaluation of the radiometric properties of starch-based biodegradable films for crop protection , 2007 .

[14]  R. Chandra,et al.  Biodegradation of maleated linear low-density polyethylene and starch blends , 1997 .

[15]  S. Magni,et al.  Fluid Biomulching Based on Poly(vinyl alcohol) and Fillers from Renewable Resources , 2008 .

[16]  Giuliano Vox,et al.  Performance and Environmental Impact of Biodegradable Films in Agriculture: A Field Study on Protected Cultivation , 2008 .

[17]  G. Vox,et al.  Radiometric properties of photoselective and photoluminescent greenhouse plastic films and their effects on peach and cherry tree growth , 2011 .

[18]  J. Lawton Effect of starch type on the properties of starch containing films , 1996 .

[19]  D. Briassoulis Mechanical behaviour of biodegradable agricultural films under real field conditions , 2006 .

[20]  Gabriella Santagata,et al.  Biodegradable films of natural polysaccharides blends , 2003 .

[21]  Alberto Pardossi,et al.  Chapter 1: Sustainable Greenhouse Systems. in “Sustainable Agriculture: Technology, Planning and Management”, Augusto Salazar e Ismael Rios Editors, Nova Science Publishers, Inc. NY USA , 2010 .

[22]  D. Briassoulis,et al.  Biodegradation of Agricultural Plastic Films: A Critical Review , 2007 .

[23]  P. Mormile,et al.  Blends of polyvinylalcohol and functionalised polycaprolactone. A study on the melt extrusion and post-cure of films suitable for protected cultivation , 2002 .

[24]  A. Pelacho,et al.  PROPERTIES OF NEW BIODEGRADABLE PLASTICS FOR MULCHING, AND CHARACTERIZATION OF THEIR DEGRADATION IN THE LABORATORY AND IN THE FIELD , 2008 .

[25]  Demetres Briassoulis,et al.  Critical Review of Norms and Standards for Biodegradable Agricultural Plastics Part II: Composting , 2010 .

[26]  James J Stapleton,et al.  Influence of sprayable mulch colour on yield of eggplant (Solanum melongena L. cv. Millionaire) , 1997 .

[27]  Giuliano Vox,et al.  Preparation, characterisation and field-testing of a biodegradable sodium alginate-based spray mulch , 2009 .

[28]  L. Sartore,et al.  Hydrolyzed protein based materials for biodegradable spray mulching coatings , 2012 .

[29]  Giuliano Vox,et al.  Mechanical properties decay and morphological behaviour of biodegradable films for agricultural mulching in real scale experiment , 2006 .

[30]  P. Halley,et al.  Developing Biodegradable Mulch Films from Starch-Based Polymers , 2001 .

[31]  R. T. Fernandez,et al.  Assessment of aliphatic-aromatic copolyester biodegradable mulch films. Part I: field study. , 2008, Chemosphere.

[32]  D. Briassoulis Mechanical Performance and Design Criteria of Biodegradable Low-tunnel Films , 2006 .

[33]  Demetres Briassoulis Mechanical Design Requirements for Low Tunnel Biodegradable and Conventional Films , 2004 .

[34]  D. Briassoulis Analysis of the mechanical and degradation performances of optimised agricultural biodegradable films , 2007 .

[35]  V. Soldi,et al.  Thermal properties and stability of cassava starch films cross-linked with tetraethylene glycol diacrylate , 2006 .

[36]  Giacomo Scarascia Mugnozza,et al.  Recycled wastes of tomato and hemp fibres for biodegradable pots: Physico-chemical characterization and field performance , 2013 .

[37]  C. Bastioli Properties and applications of Mater-Bi starch-based materials , 1998 .

[38]  Demetres Briassoulis,et al.  An Overview on the Mechanical Behaviour of Biodegradable Agricultural Films , 2004 .