Enhancement of silicon solar cell efficiency by using back surface field in comparison of different antireflective coatings

Abstract Back surface field (BSF) (n+–p–p+) silicon (Si) solar cells were fabricated with and without TiO2 or SiO2 single layer antireflection (SLAR) coatings. The two cell types were obtained with non-texturized surfaces and compared with each other, as well as with an as-grown Si solar cell. The effective aluminium–BSF was fabricated through a simple thermal evaporation and alloying (850 °C, 50 min) technique. The effect of BSF and AR coatings on the performance of the solar cells were characterized through electrical (AM 1.5 G, 100 mW/cm2), optical, and morphological measurements. The BSF Si solar cells with TiO2 and SiO2 AR coatings and without AR coatings demonstrated increased efficiencies of about 168%, 115%, and 50%, respectively, compared with the as-grown Si solar cell. The addition of the TiO2 (AR) layer initiated 24% improvement in the efficiency of the monocrystalline BSF Si solar cells, compared with 6.9% of the SiO2 (AR) coated BSF Si solar cell. The results indicate the potential of combining the TiO2 SLAR coating with BSF in the improved production of high-efficiency, low-cost Si solar cells.

[1]  H. Hovel,et al.  Comparison of back interface structure alternatives using two sided optical excitation , 2010, 2010 35th IEEE Photovoltaic Specialists Conference.

[2]  K. Drabczyk,et al.  A comparative study of SiO2 deposited by PECVD and thermal method as passivation for multicrystalline silicon solar cells , 2009 .

[3]  D. Leinen,et al.  XPS in‐depth composition study on commercial monocrystalline silicon solar cells , 2003 .

[4]  Mario Tucci,et al.  17% Efficiency heterostructure solar cell based on p-type crystalline silicon , 2004 .

[5]  H. Branz,et al.  Excellent passivation and low reflectivity Al2O3 /TiO2 bilayer coatings for n-wafer silicon solar cells , 2012, 2012 38th IEEE Photovoltaic Specialists Conference.

[6]  Kamarulazizi Ibrahim,et al.  The effect of porosity on the properties of silicon solar cell , 2010 .

[7]  M. S. Belkaid,et al.  Improved efficiency of multicrystalline silicon solar cells by TiO2 antireflection coatings derived by APCVD process , 2013 .

[8]  Bryce S. Richards,et al.  Potential cost reduction of buried-contact solar cells through the use of titanium dioxide thin films , 2004 .

[9]  Á. Morales,et al.  Sol-gel TiO2 antireflective films for textured monocrystalline silicon solar cells , 2002 .

[10]  A. Morales-Acevedo,et al.  Silicon solar cells using low cost TiO/sub 2/ thin layers prepared by chemical spray pyrolysis , 2005, 2005 2nd International Conference on Electrical and Electronics Engineering.

[11]  J. Majewski,et al.  Screen-printed titanium dioxide anti-reflection coating for silicon solar cells , 1989 .

[12]  Theoretical Analysis of Spectral Selective Transmission Coatings for Solar Energy PV System , 2013 .

[13]  V. Aroutiounian,et al.  Calculation of reflectance of porous silicon double‐layer antireflection coating for silicon solar cells , 2007 .

[14]  A. Morales-Acevedo,et al.  Double anti-reflection layers for silicon solar cells obtained by spin-on , 2002, Conference Record of the Twenty-Ninth IEEE Photovoltaic Specialists Conference, 2002..

[15]  Vladimir M. Aroutiounian,et al.  Almost zero reflectance of a silicon oxynitride/porous silicon double layer antireflection coating for silicon photovoltaic cells , 2006 .

[16]  H. Rogalla,et al.  Passivating TiO2 coatings for silicon solar cells by pulsed laser deposition , 1999 .

[17]  Bryce S. Richards,et al.  Single-material TiO2 double-layer antireflection coatings , 2003 .

[18]  S. Pellicori Wide band wide angle reflection-reducing coatings for silicon cells , 1981 .

[19]  Claude Lévy-Clément,et al.  Optimization of porous silicon reflectance for silicon photovoltaic cells , 1999 .

[20]  J. Tandon,et al.  Stable silicon solar cells with high temperature survivability , 1987 .

[21]  E Fred Schubert,et al.  Enhanced broadband and omni-directional performance of polycrystalline Si solar cells by using discrete multilayer antireflection coatings. , 2013, Optics express.

[22]  Wei Xu,et al.  Design, preparation, and durability of TiO2/SiO2 and ZrO2/SiO2 double-layer antireflective coatings in crystalline silicon solar modules , 2013 .

[23]  Dong-Sing Wuu,et al.  Tri-layer antireflection coatings (SiO2/SiO2–TiO2/TiO2) for silicon solar cells using a sol–gel technique , 2006 .