Natural Cellulose Nanofibers As Sustainable Enhancers in Construction Cement

Cement is one of the mostly used construction materials due to its high durability and low cost, but it suffers from brittle fracture and facile crack initiation. This article describes the use of naturally-derived renewable cellulose nanofibers (CNFs) to reinforce cement. The effects of CNFs on the mechanical properties, degree of hydration (DOH), and microstructure of cement pastes have been studied. It is found that an addition of 0.15% by weight of CNFs leads to a 15% and 20% increase in the flexural and compressive strengths of cement paste. The enhancement in mechanical strength is attributed to high DOH and dense microstructure of cement pastes after adding CNFs.

[1]  H. Savastano,et al.  Microstructure and mechanical properties of waste fibre–cement composites , 2005 .

[2]  M. Kern,et al.  Effect of surface treatment on retention of glass-fiber endodontic posts. , 2006, The Journal of prosthetic dentistry.

[3]  K. Scrivener,et al.  Durability of alkali-sensitive sisal and coconut fibres in cement mortar composites , 2000 .

[4]  C. Meyer,et al.  Utilization of rice husk ash in green natural fiber-reinforced cement composites: Mitigating degradation of sisal fiber , 2016 .

[5]  V. A. Rybin,et al.  Corrosion of uncoated and oxide-coated basalt fibre in different alkaline media , 2016 .

[6]  K. Farzanian,et al.  The mechanical strength, degree of hydration, and electrical resistivity of cement pastes modified with superabsorbent polymers , 2016 .

[7]  M. S. Mohammed,et al.  Microcrystalline cellulose as a reinforcement agent to cement pastes , 2014 .

[8]  Will Hansen,et al.  Investigation of blended cement hydration by isothermal calorimetry and thermal analysis , 2005 .

[9]  Siqun Wang,et al.  A Novel Process to Isolate Fibrils from Cellulose Fibers by High-Intensity Ultrasonication, Part 1: Process Optimization , 2009 .

[10]  R. Olivito,et al.  Development of durable cementitious composites using sisal and flax fabrics for reinforcement of masonry structures , 2014 .

[11]  Tanja Zimmermann,et al.  Properties of nanofibrillated cellulose from different raw materials and its reinforcement potential , 2010 .

[12]  A. Pourjavadi,et al.  Interactions between superabsorbent polymers and cement-based composites incorporating colloidal silica nanoparticles , 2013 .

[13]  D. Chung Cement reinforced with short carbon fibers: a multifunctional material , 2000 .

[14]  A. Castela,et al.  Influence of GFRP Confinement of Reinforced Concrete Columns on the Corrosion of Reinforcing Steel in a Salt Water Environment , 2015 .

[15]  Aparna Roy,et al.  Effect of Jute as Fiber Reinforcement Controlling the Hydration Characteristics of Cement Matrix , 2013 .

[16]  Qianqian Wang,et al.  Tailoring the yield and characteristics of wood cellulose nanocrystals (CNC) using concentrated acid hydrolysis , 2015, Cellulose.

[17]  Akira Isogai,et al.  Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose. , 2007, Biomacromolecules.

[18]  E. Ganjian,et al.  Manufacturing of bacterial nano-cellulose reinforced fiber−cement composites , 2015 .

[19]  Shi-lang Xu,et al.  Mechanical properties and microstructure of multi-walled carbon nanotube-reinforced cement paste , 2015 .

[20]  Siwei Ma,et al.  Correlation between hydration of cement and durability of natural fiber-reinforced cement composites , 2016 .

[21]  S. F. Santos,et al.  Nano-scale hydrogen-bond network improves the durability of greener cements , 2013, Scientific Reports.

[22]  David Hui,et al.  Cellulosic fibers from rice straw and bamboo used as reinforcement of cement-based composites for remarkably improving mechanical properties , 2015 .

[23]  M. Vignon,et al.  TEMPO-mediated surface oxidation of cellulose whiskers , 2006 .

[24]  C. Poon,et al.  Degree of hydration and gel/space ratio of high-volume fly ash/cement systems , 2000 .

[25]  Ildiko Merta,et al.  Fracture energy of natural fibre reinforced concrete , 2013 .

[26]  D. Chung Interface engineering for cement-matrix composites , 2000 .

[27]  J. Balatinecz,et al.  Aging mechanisms in cellulose fiber reinforced cement composites , 1999 .

[28]  Guowei Ma,et al.  Compressive behaviour of fibre-reinforced cemented paste backfill , 2015 .

[29]  S. Chakraborty,et al.  A mild alkali treated jute fibre controlling the hydration behaviour of greener cement paste , 2015, Scientific Reports.

[30]  Kristiina Oksman,et al.  Optimization of the isolation of nanocrystals from microcrystalline cellulose by acid hydrolysis , 2006 .

[31]  Dieter Klemm,et al.  Nanocelluloses: a new family of nature-based materials. , 2011, Angewandte Chemie.

[32]  B. Guilhot,et al.  Effect of polysaccharides on the hydration of cement suspension , 2006 .

[33]  C. Pagnoux,et al.  Mechanical properties of hemp fibre reinforced cement: Influence of the fibre/matrix interaction , 2008 .

[34]  A. Vázquez,et al.  Effect of cellulose microcrystalline particles on properties of cement based composites , 2013 .

[35]  Robert J. Moon,et al.  The influence of cellulose nanocrystal additions on the performance of cement paste , 2015 .

[36]  Akira Isogai,et al.  Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. , 2006, Biomacromolecules.

[37]  René Guyonnet,et al.  EFFECT OF POLYSACCHARIDES ON THE HYDRATION OF CEMENT PASTE AT EARLY AGES , 2004 .

[38]  A. Govin,et al.  Influence of the polysaccharide addition method on the properties of fresh mortars , 2015 .

[39]  Akira Isogai,et al.  TEMPO-oxidized cellulose nanofibers. , 2011, Nanoscale.

[40]  J. Sharp,et al.  The microstructure and mechanical properties of blended cements hydrated at various temperatures , 2001 .

[41]  H. Y. Kordkheili,et al.  Effect of carbon nanotube on physical and mechanical properties of natural fiber/glass fiber/cement composites , 2015, Journal of Forestry Research.

[42]  Akira Isogai,et al.  Elastic modulus of single cellulose microfibrils from tunicate measured by atomic force microscopy. , 2009, Biomacromolecules.

[43]  M. Jonoobi,et al.  Mechanical properties of cellulose nanofiber (CNF) reinforced polylactic acid (PLA) prepared by twin screw extrusion , 2010 .

[44]  Dale P. Bentz,et al.  Early-Age Properties of Cement-Based Materials. II: Influence of Water-to-Cement Ratio , 2009 .

[45]  A. Isogai,et al.  Preparation and characterization of TEMPO-oxidized cellulose nanofibril films with free carboxyl groups , 2011 .

[46]  Hjh Jos Brouwers,et al.  Mix design and properties assessment of Ultra-High-Performance Fibre Reinforced Concrete (UHPFRC) , 2014 .

[47]  João Marciano Laredo dos Reis,et al.  FRACTURE AND FLEXURAL CHARACTERIZATION OF NATURAL FIBER-REINFORCED POLYMER CONCRETE , 2006 .

[48]  Nemkumar Banthia,et al.  Plant-based natural fibre reinforced cement composites: A review , 2016 .

[49]  Tara H McHugh,et al.  Nanocellulose reinforced chitosan composite films as affected by nanofiller loading and plasticizer content. , 2010, Journal of food science.

[50]  N. Neithalath,et al.  Flexural fracture response of a novel iron carbonate matrix – Glass fiber composite and its comparison to Portland cement-based composites , 2015 .

[51]  Dale P. Bentz,et al.  Influence of Water-to-Cement Ratio on Hydration Kinetics: Simple Models Based on Spatial Considerations , 2006 .

[52]  Dale P Bentz,et al.  On the Relation of Setting and Early-Age Strength Development to Porosity and Hydration in Cement-Based Materials. , 2016, Cement & concrete composites.