Hydrogen-incorporation stabilization of metallic VO2(R) phase to room temperature, displaying promising low-temperature thermoelectric effect.

Regulation of electron-electron correlation has been found to be a new effective way to selectively control carrier concentration, which is a crucial step toward improving thermoelectric properties. The pure electronic behavior successfully stabilized the nonambient metallic VO(2)(R) to room temperature, giving excellent thermoelectric performance among the simple oxides with wider working temperature ranges.

[1]  J. Goodenough,et al.  Structures and a two-band model for the system V1-xCrxO2 , 1973 .

[2]  Jamie M Booth,et al.  Anisotropic structure deformation in the VO2 metal-insulator transition. , 2009, Physical review letters.

[3]  Clemens Burda,et al.  Enhancing thermoelectric performance of ternary nanocrystals through adjusting carrier concentration. , 2010, Journal of the American Chemical Society.

[4]  C. N. Berglund,et al.  Electronic Properties of V O 2 near the Semiconductor-Metal Transition , 1969 .

[5]  M. Kanatzidis,et al.  Nanostructures boost the thermoelectric performance of PbS. , 2011, Journal of the American Chemical Society.

[6]  Ziyu Wu,et al.  Understanding the nature of the kinetic process in a VO2 metal-insulator transition. , 2010, Physical review letters.

[7]  Genqiang Zhang,et al.  Enhanced Thermoelectric Properties of Core/Shell Heterostructure Nanowire Composites , 2008 .

[8]  Min Zhou,et al.  Nanostructured AgPb(m)SbTe(m+2) system bulk materials with enhanced thermoelectric performance. , 2008, Journal of the American Chemical Society.

[9]  Jinlong Yang,et al.  Direct hydrothermal synthesis of monoclinic VO2(M) single-domain nanorods on large scale displaying magnetocaloric effect , 2011 .

[10]  Andrea Cavalleri,et al.  All at Once , 2007, Science.

[11]  Jun-ichi Takimoto,et al.  Giant Reduction in Dynamic Modulus of κ-Carrageenan Magnetic Gels , 2006 .

[12]  G. J. Snyder,et al.  Enhancement of Thermoelectric Efficiency in PbTe by Distortion of the Electronic Density of States , 2008, Science.

[13]  C. Murray,et al.  Polymorphism in self-assembled AB6 binary nanocrystal superlattices. , 2011, Journal of the American Chemical Society.

[14]  Jonas Weissenrieder,et al.  Four-dimensional ultrafast electron microscopy of phase transitions , 2006, Proceedings of the National Academy of Sciences.

[15]  C. Burda,et al.  Nanostructured Bi2Se3 films and their thermoelectric transport properties. , 2006, Angewandte Chemie.

[16]  Ctirad Uher,et al.  A new thermoelectric material: CsBi4Te6. , 2004, Journal of the American Chemical Society.

[17]  Peter Gölitz Twitter, Facebook, and Open Access … , 2010 .

[18]  Slobodan Mitrovic,et al.  Reduction of thermal conductivity in phononic nanomesh structures. , 2010, Nature nanotechnology.

[19]  J. Gavarri,et al.  High efficiency thermochromic VO2(R) resulting from the irreversible transformation of VO2(B) , 1998 .