Effect of nanoimprint on the elastic modulus of PMMA

This paper is focused on the understanding of the effect of the nanoimprint lithography process on the elastic modulus of thin, thermoplastic films. In particular, we present the comparison between the standard and an ultrafast thermal NIL technology as well as the way both processes affect the top surface of poly(methyl methacrylate) (PMMA). The PeakForce QNMź (Quantitative Nanomechanical Property Mapping) scanning probe technique was used to determine the Young's modulus of PMMA by comparison with a polystyrene standard. We demonstrate that imprinted PMMA, regardless of the used method, shows a 9-fold increase of Young's modulus compared to non-imprinted PMMA at least in the top 3-5nm thick surface layer. This important finding proves that the ultrafast process with much higher temperatures, but also with much shorter process times, leads to elastic surface properties that are comparable to those of PMMA imprinted with the standard process. We have confirmed that annealing alone does not significantly influence the Young's modulus. Display Omitted PeakForce QNM analysis of Young's modulus of imprinted PMMA by thermal and Pulsed NILPMMA undergoes 9-fold increase of Young's modulus upon imprinting.Thermal NIL and Pulsed-NIL affect similarly the mechanical properties of PMMA.