A Thermoporometry Study of Fumed Silica/aerogel Composites

The porous texture of fumed silica/aerogel composite materials is studied by thermoporometry. The effect of fumed silica (Aerosil) powder in aerogels, added during the sol-gel processing is investigated. The textural change due to the autoclave drying process as a function of the fumed silica/aerogel ratio of the systems is investigated. The meso- and macro porosity of the fumed silica/aerogel composites is mainly influenced by the ratio fumed silica/aerogel and only slightly by the autoclave drying process. Addition of fumed silica powder results in an increase of the mean pore radius of the system and in a decrease of the meso- and macro-pore volume. By contrast, the micro-porosity is hardly affected by the addition of the fumed silica powder; it is only influenced by the autoclave drying process.