Production of bio-fuels by high temperature pyrolysis of sewage sludge using conventional and microwave heating.

The pyrolysis of sewage sludge was investigated using microwave and electrical ovens as the sources of heat, and graphite and char as microwave absorbers. The main objective of this work was to maximize the gas yield and to assess its quality as a fuel and as a source of hydrogen or syngas (H2 + CO). Both gases were produced in a higher proportion by microwave pyrolysis than by conventional pyrolysis, with a maximum value of 38% for H2 and 66% for H2 + CO. The oils obtained were also characterized using FTIR and GC-MS. The use of conventional electrical heating in the pyrolysis of sewage sludge produced an oil that could have a significant environmental and toxicological impact. Conversely, microwave pyrolysis still preserved some of the functional groups of the initial sludge such as aliphatic and oxygenated compounds, whereas no heavy PACs were detected.

[1]  Waichi Iwasaki,et al.  A consideration of the economic efficiency of hydrogen production from biomass , 2003 .

[2]  G. Socrates,et al.  Infrared Characteristic Group Frequencies , 1980 .

[3]  Lilly Shen,et al.  An experimental study of oil recovery from sewage sludge by low-temperature pyrolysis in a fluidised-bed , 2003 .

[4]  Donald S. Scott,et al.  Flash pyrolysis of sewage sludge , 1986 .

[5]  B. Krieger-Brockett Microwave pyrolysis of biomass , 1994 .

[6]  C. Roy,et al.  Hydrocarbon content of liquid products and tar from pyrolysis and gasification of wood , 1991 .

[7]  G. Mills,et al.  Status and future opportunities for conversion of synthesis gas to liquid fuels , 1994 .

[8]  Don W. Green,et al.  Perry's Chemical Engineers' Handbook , 2007 .

[9]  Thomas Nussbaumer,et al.  Mechanisms and kinetics of homogeneous secondary reactions of tar from continuous pyrolysis of wood chips , 2002 .

[10]  W. McWhinnie,et al.  Rapid microwave pyrolysis of coal: Methodology and examination of the residual and volatile phases , 1995 .

[11]  Mohammad Asadullah,et al.  Biomass Gasification to Hydrogen and Syngas at Low Temperature: Novel Catalytic System Using Fluidized-Bed Reactor , 2002 .

[12]  Paul T. Williams,et al.  Influence of temperature on the products from the flash pyrolysis of biomass , 1996 .

[13]  H. Y Kim,et al.  A low cost production of hydrogen from carbonaceous wastes , 2003 .

[14]  G. Lu,et al.  Characterisation of sewage sludge-derived adsorbents for H2S removal. Part 2: Surface and pore structural evolution in chemical activation , 1996 .

[15]  J. A. Menéndez,et al.  Gas chromatographic-mass spectrometric study of the oil fractions produced by microwave-assisted pyrolysis of different sewage sludges. , 2003, Journal of chromatography. A.

[16]  A. Bridgwater,et al.  An overview of fast pyrolysis of biomass , 1999 .

[17]  J. Werther,et al.  Sewage sludge combustion , 1999 .

[18]  M. Lallemant,et al.  Pyrolysis of Timahdit, Morocco, oil shales under microwave field , 1994 .

[19]  G. Lu,et al.  Surface area development of sewage sludge during pyrolysis , 1995 .

[20]  K. E. Harfi Pyrolysis of the Moroccan (Tarfaya) oil shales under microwave irradiation , 2000 .

[21]  Andrzej Zlotorzynski The Application of Microwave Radiation to Analytical and Environmental Chemistry , 1995 .

[22]  Thomas A. Milne,et al.  Molecular characterization of the pyrolysis of biomass , 1987 .

[23]  José A. Caballero,et al.  Characterization of sewage sludges by primary and secondary pyrolysis , 1997 .

[24]  J. A. Menéndez,et al.  On the pyrolysis of sewage sludge: the influence of pyrolysis conditions on solid, liquid and gas fractions , 2002 .

[25]  J. Weber,et al.  Co-pyrolysis of wood biomass and synthetic polymer mixtures. Part I: influence of experimental conditions on the evolution of solids, liquids and gases , 2002 .

[26]  Juan A. Conesa,et al.  Evolution of gases in the primary pyrolysis of different sewage sludges , 1998 .

[27]  J. J. Pis,et al.  Microwave-induced pyrolysis of sewage sludge. , 2002, Water research.

[28]  E. Jardé,et al.  Characterization of humic substances in highly polluted river sediments by pyrolysis methylation–gas chromatography–mass spectrometry , 2001 .

[29]  Hartmut Spliethoff,et al.  Catalytic pyrolysis of biomass for hydrogen rich fuel gas production , 2003 .

[30]  Paul T. Williams,et al.  Composition of oils derived from the batch pyrolysis of tyres , 1998 .