Experimental Study of Fire Hazards of Thermal-Insulation Material in Diesel Locomotive: Aluminum-Polyurethane

This work investigated experimentally and theoretically the fire hazards of thermal-insulation materials used in diesel locomotives under different radiation heat fluxes. Based on the experimental results, the critical heat flux for ignition was determined to be 6.15 kW/m2 and 16.39 kW/m2 for pure polyurethane and aluminum-polyurethane respectively. A theoretical model was established for both to predict the fire behaviors under different circumstances. The fire behavior of the materials was evaluated based on the flashover and the total heat release rate (HRR). The fire hazards levels were classified based on different experimental results. It was found that the fire resistance performance of aluminum-polyurethane is much better than that of pure-polyurethane under various external heat fluxes. The concentration of toxic pyrolysis volatiles generated from aluminum-polyurethane materials is much higher than that of pure polyurethane materials, especially when the heat flux is below 50 kW/m2. The hazard index HI during peak width time was proposed based on the comprehensive impact of time and concentrations. The predicted HI in this model coincides with the existed N-gas and FED models which are generally used to evaluate the fire gas hazard in previous researches. The integrated model named HNF was proposed as well to estimate the fire hazards of materials by interpolation and weighted average calculation.

[1]  G. Rein,et al.  Analysis of principal gas products during combustion of polyether polyurethane foam at different irradiance levels , 2009 .

[2]  Vytenis Babrauskas Sandwich panel performance in full-scale and bench-scale fire tests , 1997 .

[3]  Colomba Di Blasi,et al.  Modeling chemical and physical processes of wood and biomass pyrolysis , 2008 .

[4]  Anna A. Stec,et al.  Assessment of the fire toxicity of building insulation materials , 2011 .

[5]  Arvind Atreya,et al.  Ignition of fires , 1998, Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences.

[6]  Marc Janssens,et al.  Piloted ignition of wood: A review , 1991 .

[7]  M. A. Delichatsios,et al.  Ignition Times For Thermally Thick And Intermediate Conditions In Flat And Cylindrical Geometries , 2000 .

[8]  Arvind Atreya,et al.  Effect Of Sample Orientation On Piloted Ignition And Flame Spread , 1986 .

[9]  Wan Ki Chow,et al.  Studies on fire behaviour of video compact disc (VCD) materials with a cone calorimeter , 2004 .

[10]  Vytenis Babrauskas,et al.  Toxic potency measurement for fire hazard analysis , 1992 .

[11]  Charles A. Harper,et al.  Handbook of Building Materials for Fire Protection , 2003 .

[12]  D. H. Malan,et al.  The combustion of wood. Part I , 1946, Mathematical Proceedings of the Cambridge Philosophical Society.

[13]  James G. Quintiere A theoretical basis for flammability properties , 2006 .

[14]  Michael Spearpoint,et al.  Ignition of New Zealand Wood Products in the LIFT, RIFT and ISO 5657 Apparatus using the ASTM E 1321-97 Protocol , 2008 .

[15]  Kuang-Chung Tsai,et al.  Orientation effect on cone calorimeter test results to assess fire hazard of materials. , 2009, Journal of hazardous materials.

[16]  T. R. Hull,et al.  Bench-scale assessment of combustion toxicity—A critical analysis of current protocols , 2007 .

[17]  G. W. H. Silcock,et al.  The effects of geometry and ignition mode on ignition times obtained using a cone calorimeter and ISO ignitability apparatus , 1993 .

[18]  R. V. Petrella,et al.  The Assessment of Full-Scale Fire Hazards from Cone Calorimeter Data , 1994 .

[19]  Vytenis Babrauskas,et al.  A methodology for obtaining and using toxic potency data for fire hazard analysis , 1998 .

[20]  Michael A. Delichatsios,et al.  Flammability properties for charring materials , 2003 .

[21]  É. Guillaume,et al.  Characterization of thermal properties and analysis of combustion behavior of PMMA in a cone calorim , 2011 .

[22]  B. T. Rhodes,et al.  Burning rate and flame heat flux for PMMA in a cone calorimeter , 1996 .

[23]  Vytenis Babrauskas,et al.  Ignition of Wood: A Review of the State of the Art , 2002 .

[24]  Michael A. Delichatsios,et al.  The use of time to ignition data for characterizing the thermal inertia and the minimum (critical) heat flux for ignition or pyrolysis , 1991 .

[25]  H. Biteau,et al.  Ability of the Fire Propagation Apparatus to characterise the heat release rate of energetic materials. , 2009, Journal of hazardous materials.

[26]  Takashi Kashiwagi,et al.  Effects of sample orientation on nonpiloted ignition of thin poly(methyl methacrylate) sheet by a laser. 1. Theoretical prediction , 2005 .