The Removal of Bisphenol A in Water Treatment Plant Using Ultrafiltration Membrane System

Bisphenol A (BPA) is one of the recalcitrant contaminants that are detected in drinking water sources, as the conventional water treatment plant is incapable of removing it completely. This study was conducted to explore the performance of ultrafiltration (UF) membrane system for the BPA removal in which BPA was spiked in water sample collected from a treatment plant. The effects of process conditions that may influence the removal and flux performance of the membrane including operating pressure, feed pH and BPA concentration, and backwash cleaning were investigated. The results showed that an applied pressure of 1 bar was the optimum pressure for achieving good balance of BPA removal (95 %) and water flux (109 L m−2 h−1) compared to operating pressure of 0.5 and 1.5 bar. The variation of feed pH showed significant impact on BPA elimination with the highest rejection (90 %) achieved at pH 7 while the lowest removal (20 %) at pH 10. BPA concentration had no significant impact on BPA removal as high removal rate (>95 %) was observed regardless of feed concentration (between 10 and 100 μg L−1). The normalized flux showed decreasing trend with filtration cycle due to increased membrane resistance of BPA adsorption onto the membrane. The membrane cleaning via backwash was able to recover 90 % BPA removal even after three consecutive cycles of filtration. This indicated the promising performance of UF membrane system for industrial water treatment.

[1]  Wang Lin,et al.  The removal of bisphenol A by hollow fiber microfiltration membrane , 2010 .

[2]  W. Gao,et al.  Membrane fouling control in ultrafiltration technology for drinking water production: A review , 2011 .

[3]  K. Clark,et al.  Relevance of drinking water as a source of human exposure to bisphenol A , 2012, Journal of Exposure Science and Environmental Epidemiology.

[4]  Pengli Bai,et al.  Preparation and characterization of pH-sensitive polyethersulfone hollow fiber membrane for flux control , 2009 .

[5]  W. Lau,et al.  Removal of bisphenol A by adsorption mechanism using PES–SiO2 composite membranes , 2016, Environmental technology.

[6]  Yue Jia,et al.  Membrane Technology: Past, Present and Future , 2011 .

[7]  K. Choo,et al.  Selective adsorption of bisphenol A by organic–inorganic hybrid mesoporous silicas , 2011 .

[8]  Y. Yoon,et al.  Occurrence and removal of selected micropollutants in a water treatment plant. , 2014, Chemosphere.

[9]  Ş. Sungur,et al.  Determinatıon of bisphenol a migrating from canned food and beverages in markets. , 2014, Food chemistry.

[10]  Shelby A. Flint,et al.  Bisphenol A exposure, effects, and policy: a wildlife perspective. , 2012, Journal of environmental management.

[11]  S. Saponaro,et al.  Bisphenol A, nonylphenols, benzophenones, and benzotriazoles in soils, groundwater, surface water, sediments, and food: a review , 2014, Environmental Science and Pollution Research.

[12]  T. Kubo,et al.  LC/MS determination of bisphenol A in river water using a surface-modified molecularly-imprinted polymer as an on-line pretreatment device , 2005, Analytical and bioanalytical chemistry.

[13]  P. Bérubé,et al.  Surface shear stress and retention of emerging contaminants during ultrafiltration for drinking water treatment , 2014 .

[14]  Soria Eladak,et al.  A new chapter in the bisphenol A story: bisphenol S and bisphenol F are not safe alternatives to this compound. , 2015, Fertility and sterility.

[15]  K. Kimura,et al.  Adsorption of hydrophobic compounds onto NF/RO membranes: an artifact leading to overestimation of rejection , 2003 .

[16]  Laura N. Vandenberg,et al.  Human exposure to bisphenol A (BPA). , 2007, Reproductive toxicology.

[17]  J. Cravedi,et al.  Removal of bisphenol A by a nanofiltration membrane in view of drinking water production. , 2006, Water research.

[18]  C. Rosin,et al.  Is Drinking Water a Major Route of Human Exposure to Alkylphenol and Bisphenol Contaminants in France? , 2013, Archives of Environmental Contamination and Toxicology.

[19]  M. Wong,et al.  Bisphenol A (BPA) in China: a review of sources, environmental levels, and potential human health impacts. , 2012, Environment international.

[20]  Huu Hao Ngo,et al.  Fouling of ultrafiltration membrane by effluent organic matter: A detailed characterization using different organic fractions in wastewater , 2006 .

[21]  Benjamin D. Stanford,et al.  Pharmaceuticals and endocrine disrupting compounds in U.S. drinking water. , 2009, Environmental science & technology.

[22]  J. Michałowicz Bisphenol A--sources, toxicity and biotransformation. , 2014, Environmental toxicology and pharmacology.

[23]  A. Kargari,et al.  Application of low-pressure reverse osmosis for effective recovery of bisphenol A from aqueous wastes , 2014 .

[24]  L. T. Son,et al.  Hollow-fiber membrane absorbents embedded molecularly imprinted polymeric spheres for bisphenol A target , 2011 .

[25]  Paulo Henrique Pereira,et al.  A perspective on the potential risks of emerging contaminants to human and environmental health , 2015, Environmental Science and Pollution Research.

[26]  Wang Lin,et al.  THE REMOVAL OF BISPHENOL A BY ULTRAFILTRATION , 2008 .

[27]  W. Lau,et al.  Surface modification of SiO2 nanoparticles and its impact on the properties of PES-based hollow fiber membrane , 2015 .

[28]  L. R. Harris,et al.  A review of the environmental fate, effects, and exposures of bisphenol A. , 1998, Chemosphere.

[29]  H. Yu,et al.  Adsorption of bisphenol A by polysulphone membrane. , 2010 .

[30]  Jacob Gibs,et al.  Efficiency of conventional drinking-water-treatment processes in removal of pharmaceuticals and other organic compounds. , 2007, The Science of the total environment.

[31]  P. Chiang,et al.  Occurrence and assessment of treatment efficiency of nonylphenol, octylphenol and bisphenol-A in drinking water in Taiwan. , 2013, The Science of the total environment.

[32]  Dimitra Voutsa,et al.  Alkylphenols and phthalates in bottled waters. , 2011, Journal of hazardous materials.

[33]  W. Lau,et al.  A review on bisphenol A occurrences, health effects and treatment process via membrane technology for drinking water , 2016, Environmental Science and Pollution Research.

[34]  Yong-Gyun Park,et al.  Removal of bisphenol A and 17β-estradiol in single walled carbon nanotubes–ultrafiltration (SWNTs–UF) membrane systems , 2012 .

[35]  Robert C. Andrews,et al.  Membrane adsorption of endocrine disrupting compounds and pharmaceutically active compounds , 2007 .

[36]  K. Kimura,et al.  Rejection of neutral endocrine disrupting compounds (EDCs) and pharmaceutical active compounds (PhACs) by RO membranes , 2004 .

[37]  A. Szymański,et al.  Method Based on Solid Phase Extraction, LC and GC for Analysis of Bisphenol A in Drinking Water , 2004 .

[38]  Yu Tian,et al.  Transportation characteristics of bisphenol A on ultrafiltration membrane with low molecule weight cut-off , 2015 .

[39]  A. Grayson,et al.  Biologically directed environmental monitoring, fate, and transport of estrogenic endocrine disrupting compounds in water: A review. , 2006, Chemosphere.

[40]  Lokesh P. Padhye,et al.  Year-long evaluation on the occurrence and fate of pharmaceuticals, personal care products, and endocrine disrupting chemicals in an urban drinking water treatment plant. , 2014, Water research.

[41]  Long D. Nghiem,et al.  Bisphenol A retention in the direct ultrafiltration of greywater , 2006 .

[42]  M. Yüksel,et al.  Removal of bisphenol A (BPA) from water by various nanofiltration (NF) and reverse osmosis (RO) membranes. , 2013, Journal of hazardous materials.