Geology of the Don Manuel igneous complex, central Chile: Implications for igneous processes in porphyry copper systems

The Don Manuel igneous complex and associated porphyry copper mineralization in the Andean Cordillera of central Chile demonstrate similarities between intrusive complexes associated with porphyry copper deposits and arc volcanoes that generate porphyritic volcanics. The Don Manuel igneous complex intrusions progressed from quartz monzonite through rhyolite and biotite tonalite to intermediate porphyritic and basaltic andesite dikes, which intrude the older units. Mineralization is associated with the biotite tonalite and intermediate porphyries, which also contain the greatest abundance of mafic enclaves. Zoning patterns within plagioclase phenocrysts suggest that the later intermediate porphyries comprise a hybridized suite formed by magma mixing. New zircon U-Pb ages and whole-rock Ar-Ar ages indicate that the Don Manuel igneous complex was emplaced between ca. 4 and 3.6 Ma. The time scale for the episodic intrusion of the Don Manuel igneous complex units is similar to observed episodicity of eruption and degassing events in active arc volcanoes. Observations from the Don Manuel igneous complex are consistent with the close spatial and temporal association of mineralization with episodic intrusion and interaction between silicic and mafic magmas during emplacement. The observations are also consistent with the hypothesis that mafic magma provides a source of sulfur for porphyry copper deposit formation.

[1]  R. Sparks,et al.  Vertically extensive and unstable magmatic systems: A unified view of igneous processes , 2017, Science.

[2]  R. Sparks,et al.  Dynamic Magma Systems: Implications for Forecasting Volcanic Activity , 2017 .

[3]  M. Heap,et al.  Strain‐induced permeability increase in volcanic rock , 2016 .

[4]  C. Heinrich,et al.  From a long-lived upper-crustal magma chamber to rapid porphyry copper emplacement : reading the geochemistry of zircon crystals at Bajo de la Alumbrera (NW Argentina). , 2016 .

[5]  Willy P Aspinall,et al.  Similarities and differences in the historical records of lava dome-building volcanoes: Implications for understanding magmatic processes and eruption forecasting , 2016 .

[6]  J. Blundy,et al.  The effect of pressure on sulphur speciation in mid- to deep-crustal arc magmas and implications for the formation of porphyry copper deposits , 2016, Contributions to Mineralogy and Petrology.

[7]  A. D. Saunders,et al.  Rapid thermal rejuvenation of high-crystallinity magma linked to porphyry copper deposit formation; evidence from the Koloula Porphyry Prospect, Solomon Islands , 2016 .

[8]  B. Schoene,et al.  Evaluating the construction and evolution of upper crustal magma reservoirs with coupled U/Pb zircon geochronology and thermal modeling: A case study from the Mt. Capanne pluton (Elba, Italy) , 2015 .

[9]  D. Cooke,et al.  Structural Evolution of the Rio Blanco-Los Bronces District, Andes of Central Chile: Controls on Stratigraphy, Magmatism, and Mineralization , 2015 .

[10]  P. Cole,et al.  Crustal‐scale degassing due to magma system destabilization and magma‐gas decoupling at Soufrière Hills Volcano, Montserrat , 2015 .

[11]  R. Sparks,et al.  Construction and evolution of igneous bodies: Towards an integrated perspective of crustal magmatism , 2015 .

[12]  M. Reed,et al.  Time Scales of Porphyry Cu Deposit Formation: Insights from Titanium Diffusion in Quartz , 2015 .

[13]  C. Chelle-Michou,et al.  High-Resolution Geochronology of the Coroccohuayco Porphyry-Skarn Deposit, Peru: A Rapid Product of the Incaic Orogeny , 2015 .

[14]  R. Creaser,et al.  The Distribution and Timing of Molybdenite Mineralization at the El Teniente Cu-Mo Porphyry Deposit, Chile , 2015 .

[15]  M. Chiaradia Crustal thickness control on Sr/Y signatures of recent arc magmas: an Earth scale perspective , 2015, Scientific Reports.

[16]  A. Kent,et al.  ZIRCON COMPOSITIONAL EVIDENCE FOR SULFUR-DEGASSING FROM ORE-FORMING ARC MAGMAS , 2015 .

[17]  T. Rooney,et al.  Changes in magma storage conditions following caldera collapse at Okataina Volcanic Center, New Zealand , 2015, Contributions to Mineralogy and Petrology.

[18]  J. Kynický,et al.  Experimental study of REE, Ba, Sr, Mo and W partitioning between carbonatitic melt and aqueous fluid with implications for rare metal mineralization , 2015, Contributions to Mineralogy and Petrology.

[19]  G. Nolet,et al.  Flat versus normal subduction zones: a comparison based on 3-D regional traveltime tomography and petrological modelling of central Chile and western Argentina (29°–35°S) , 2014 .

[20]  S. Sparks,et al.  Generation of porphyry copper deposits by gas–brine reaction in volcanic arcs , 2014 .

[21]  R. Loucks Distinctive composition of copper-ore-forming arcmagmas , 2014 .

[22]  D. Cooke,et al.  Geochemistry of Porphyry Deposits , 2014 .

[23]  J. Palandri,et al.  The Butte Magmatic-Hydrothermal System: One Fluid Yields All Alteration and Veins , 2013 .

[24]  J. Dilles,et al.  Amphibole Geochemistry of the Yanacocha Volcanics, Peru: Evidence for Diverse Sources of Magmatic Volatiles Related to Gold Ores , 2013 .

[25]  T. Driesner,et al.  Porphyry-Copper Ore Shells Form at Stable Pressure-Temperature Fronts Within Dynamic Fluid Plumes , 2012, Science.

[26]  A. Rust,et al.  Insights into the mechanisms and timescales of pluton assembly from deformation patterns of mafic enclaves , 2012 .

[27]  A. Parmigiani,et al.  A physical model for metal extraction and transport in shallow magmatic systems , 2012 .

[28]  Patricia Sruoga,et al.  Complejo Caldera Diamante-volcán Maipo (34°10'S, 69º50'O): Evolución volcanológica y geoquímica e implicancias en su peligrosidad , 2012 .

[29]  K. Deckart,et al.  Zircon Trace Element and O–Hf Isotope Analyses of Mineralized Intrusions from El Teniente Ore Deposit, Chilean Andes: Constraints on the Source and Magmatic Evolution of Porphyry Cu–Mo Related Magmas , 2012 .

[30]  L. Baumgartner,et al.  Time resolved construction of a bimodal laccolith (Torres del Paine, Patagonia) , 2012 .

[31]  J. Richards,et al.  High Sr/Y Magmas Reflect Arc Maturity, High Magmatic Water Content, and Porphyry Cu ± Mo ± Au Potential: Examples from the Tethyan Arcs of Central and Eastern Iran and Western Pakistan , 2012 .

[32]  M. Reed,et al.  Porphyry Cu-Mo Stockwork Formation by Dynamic, Transient Hydrothermal Pulses: Mineralogic Insights from the Deposit at Butte, Montana , 2011 .

[33]  G. Zellmer,et al.  Lower crustal H2O controls on the formation of adakitic melts , 2011 .

[34]  J. Richards HIGH Sr/Y ARC MAGMAS AND PORPHYRY Cu ± Mo ± Au DEPOSITS: JUST ADD WATER , 2011 .

[35]  P. Renne,et al.  Response to the comment by W.H. Schwarz et al. on Joint determination of 40K decay constants and 40 , 2011 .

[36]  C. Heinrich,et al.  Zircon crystallization and the lifetimes of ore-forming magmatic-hydrothermal systems , 2011 .

[37]  M. Franchini,et al.  Petrology of the Miocene igneous rocks in the Altar region, main Cordillera of San Juan, Argentina. A geodynamic model within the context of the Andean flat-slab segment and metallogenesis , 2011 .

[38]  D. Furbish,et al.  Growth of plutons by incremental emplacement of sheets in crystal-rich host: Evidence from Miocene intrusions of the Colorado River region, Nevada, USA , 2011 .

[39]  C. Stern,et al.  Magmatic Evolution of the Giant El Teniente Cu–Mo Deposit, Central Chile , 2011 .

[40]  R. Duncan,et al.  Evolution of Calc-Alkaline Volcanism and Associated Hydrothermal Gold Deposits at Yanacocha, Peru** , 2010 .

[41]  S. Hynek,et al.  Composition, pre-eruptive zonation, and geochronologic significance of the ∼450ka Diamante Tuff, Andean Cordillera (34°S), Argentina , 2010 .

[42]  P. Renne,et al.  Joint determination of 40K decay constants and 40Ar∗/40K for the Fish Canyon sanidine standard, and improved accuracy for 40Ar/39Ar geochronology , 2010 .

[43]  C. Stern,et al.  PETROCHEMISTRY AND AGE OF RHYOLITIC PYROCLASTIC FLOWS WHICH OCCUR ALONG THE DRAINAGE VALLEYS OF THE RIO MAIPO AND RIO CACHAPOAL (CHILE) AND THE RIO YAUCHA ANO RIO PAPAGAYOS (ARGENTINA) , 2010 .

[44]  J. Stix,et al.  Sulphide magma as a source of metals in arc-related magmatic hydrothermal ore fluids , 2010 .

[45]  M. Farías,et al.  Crustal‐scale structural architecture in central Chile based on seismicity and surface geology: Implications for Andean mountain building , 2010 .

[46]  R. Sillitoe Porphyry Copper Systems , 2010 .

[47]  J. Wilkinson,et al.  Multistage Intrusion, Brecciation, and Veining at El Teniente, Chile: Evolution of a Nested Porphyry System , 2010 .

[48]  K. Hodges,et al.  Data reporting norms for 40Ar/39Ar geochronology , 2009 .

[49]  Elizabeth Cottrell,et al.  Water and the Oxidation State of Subduction Zone Magmas , 2009, Science.

[50]  C. Annen From plutons to magma chambers: Thermal constraints on the accumulation of eruptible silicic magma in the upper crust , 2009 .

[51]  Z. Zajacz,et al.  Copper transport by high temperature, sulfur-rich magmatic vapor: Evidence from silicate melt and vapor inclusions in a basaltic andesite from the Villarrica volcano (Chile) , 2009 .

[52]  T. Christopher,et al.  Microlite transfer by disaggregation of mafic inclusions following magma mixing at Soufrière Hills volcano, Montserrat , 2009 .

[53]  A. Kent,et al.  Anhydrite-bearing andesite and dacite as a source for sulfur in magmatic-hydrothermal mineral deposits , 2008 .

[54]  M. Barton,et al.  Root Zones of Porphyry Systems: Extending the Porphyry Model to Depth , 2008 .

[55]  K. Uto,et al.  Character and origin of lithofacies in the conduit of Unzen volcano, Japan , 2008 .

[56]  L. Baumgartner,et al.  Incremental growth of the Patagonian Torres del Paine laccolith over 90 k.y , 2008 .

[57]  S. Carretier,et al.  Late Miocene high and rapid surface uplift and its erosional response in the Andes of central Chile (33°–35°S) , 2008 .

[58]  R. Sparks,et al.  Late Pleistocene tephrochronology of marine sediments adjacent to Montserrat, Lesser Antilles volcanic arc , 2008, Journal of the Geological Society.

[59]  Martin J. Streck,et al.  Mineral Textures and Zoning as Evidence for Open System Processes , 2008 .

[60]  C. Stern,et al.  MAGMATIC ANHYDRITE IN PLUTONIC ROCKS AT THE EL TENIENTE Cu-Mo DEPOSIT, CHILE, AND THE ROLE OF SULFUR- AND COPPER-RICH MAGMAS IN ITS FORMATION , 2007 .

[61]  L. Cathles,et al.  How potassium silicate alteration suggests the formation of porphyry ore deposits begins with the nearly explosive but barren expulsion of large volumes of magmatic water , 2007 .

[62]  J. Walshe,et al.  Geology, Mineralization, Alteration, and Structural Evolution of the El Teniente Porphyry Cu-Mo Deposit , 2007 .

[63]  Richard J. Brown,et al.  Mechanically disrupted and chemically weakened zones in segmented dike systems cause vent localization: Evidence from kimberlite volcanic systems , 2007 .

[64]  C. Macpherson,et al.  Amphibole “sponge” in arc crust? , 2007 .

[65]  J. Richards,et al.  Special Paper: Adakite-Like Rocks: Their Diverse Origins and Questionable Role in Metallogenesis , 2007 .

[66]  A. Crawford,et al.  Shoshonitic magmatism and the formation of the Northparkes porphyry Cu – Au deposits, New South Wales , 2007 .

[67]  P. Lipman Incremental assembly and prolonged consolidation of Cordilleran magma chambers: Evidence from the Southern Rocky Mountain volcanic field , 2007 .

[68]  R. Charrier,et al.  Tectonostratigraphic evolution of the Andean Orogen in Chile , 2007 .

[69]  S. Malone,et al.  Magma Ascent and the Style of Volcanic Eruptions , 2006 .

[70]  P. Wallace,et al.  Storage and interaction of compositionally heterogeneous magmas from the 1986 eruption of Augustine Volcano, Alaska , 2006 .

[71]  T. Pettke,et al.  Evolution of a Porphyry-Cu Mineralized Magma System at Santa Rita, New Mexico (USA) , 2006 .

[72]  K. Viljoen,et al.  Platinum-group element geochemistry of mantle eclogites: A reconnaissance study of xenoliths from the Orapa kimberlite, Botswana , 2006 .

[73]  K. Cashman,et al.  The origin of volcano-tectonic earthquake swarms , 2006 .

[74]  P. Sruoga,et al.  Volcanological and geochemical evolution of the Diamante Caldera–Maipo volcano complex in the southern Andes of Argentina (34°10′S) , 2005 .

[75]  Roger G. Taylor,et al.  Ages of Intrusion, Alteration, and Mineralization at the Grasberg Cu-Au Deposit, Papua, Indonesia , 2005 .

[76]  K. Deckart,et al.  Magmatic and Hydrothermal Chronology of the Giant Río Blanco Porphyry Copper Deposit, Central Chile: Implications of an Integrated U-Pb and 40Ar/39Ar Database , 2005 .

[77]  D. Cooke,et al.  Regional Geochemistry of Tertiary Igneous Rocks in Central Chile: Implications for the Geodynamic Environment of Giant Porphyry Copper and Epithermal Gold Mineralization , 2005 .

[78]  J. Mattinson Zircon U–Pb chemical abrasion (“CA-TIMS”) method: Combined annealing and multi-step partial dissolution analysis for improved precision and accuracy of zircon ages , 2005 .

[79]  K. Kunze,et al.  Copper deposition during quartz dissolution by cooling magmatic–hydrothermal fluids: The Bingham porphyry , 2005 .

[80]  T. Pettke,et al.  Magma evolution and the formation of porphyry Cu–Au ore fluids: evidence from silicate and sulfide melt inclusions , 2005 .

[81]  P. Candela,et al.  Magmatic Processes in the Development of Porphyry-Type Ore Systems , 2005 .

[82]  M. Barton,et al.  Porphyry deposits; characteristics and origin of hypogene features , 2005 .

[83]  S. Kay,et al.  Episodic arc migration, crustal thickening, subduction erosion, and magmatism in the south-central Andes , 2005 .

[84]  T. Pettke,et al.  The formation of economic porphyry copper (-gold) deposits: constraints from microanalysis of fluid and melt inclusions , 2005, Geological Society, London, Special Publications.

[85]  C. Stern Active Andean volcanism: its geologic and tectonic setting , 2004 .

[86]  K. Becker,et al.  From andesitic volcanism to the formation of a porphyry Cu-Au mineralizing magma chamber: the Farallón Negro Volcanic Complex, northwestern Argentina , 2004 .

[87]  R. Sparks,et al.  Evolution and volcanic hazards of Taapaca Volcanic Complex, Central Andes of Northern Chile , 2004, Journal of the Geological Society.

[88]  C. Heinrich,et al.  Copper deposition by fluid cooling in intrusion-centered systems: New insights from the Bingham porphyry ore deposit, Utah , 2004 .

[89]  R. Hoblitt,et al.  Oxidized sulfur-rich mafic magma at Mount Pinatubo, Philippines , 2004 .

[90]  R. Mathur,et al.  New Chronology for El Teniente, Chilean Andes, from U-Pb, 40 Ar/ 39 Ar, Re-Os, and Fission-Track Dating: Implications for the Evolution of a Supergiant Porphyry Cu-Mo Deposit , 2004 .

[91]  D. Morata,et al.  Tertiary volcanism during extension in the Andean foothills of central Chile (33°15′–33°45′S) , 2003 .

[92]  M. Parada,et al.  Adakite-like signature of Late Miocene intrusions at the Los Pelambres giant porphyry copper deposit in the Andes of central Chile: metallogenic implications , 2003 .

[93]  W. Hildreth,et al.  Eruptive history and geochronology of the Mount Baker volcanic field, Washington , 2003 .

[94]  L. Giambiagi,et al.  Structural evolution of the Andes in a transitional zone between flat and normal subduction (33°30′–33°45′S), Argentina and Chile , 2002 .

[95]  S. Kay,et al.  Evidence for Cenozoic extensional basin development and tectonic inversion south of the flat-slab segment, southern Central Andes, Chile (33°–36°S.L.) , 2002 .

[96]  J. Cembrano,et al.  The Challenger–Juan Fernández–Maipo major tectonic transition of the Nazca–Andean subduction system at 33–34°S: geodynamic evidence and implications , 2002 .

[97]  M. Pardo,et al.  Seismotectonic and stress distribution in the central Chile subduction zone , 2002 .

[98]  E. Christiansen,et al.  Contributions from mafic alkaline magmas to the Bingham porphyry Cu–Au–Mo deposit, Utah, USA , 2002 .

[99]  R. W. Le Maitre,et al.  Igneous Rocks: A Classification and Glossary of Terms , 2002 .

[100]  R. Sparks,et al.  The volcanic evolution of Montserrat using 40Ar/39Ar geochronology , 2002, Geological Society, London, Memoirs.

[101]  J. Lillo,et al.  Giant versus small porphyry copper deposits of Cenozoic age in northern Chile: adakitic versus normal calc-alkaline magmatism , 2001 .

[102]  K. Hattori,et al.  Contribution of mafic melt to porphyry copper mineralization: evidence from Mount Pinatubo, Philippines, and Bingham Canyon, Utah, USA , 2001 .

[103]  M. Bishop,et al.  Erosion, Himalayan geodynamics, and the geomorphology of metamorphism , 2001 .

[104]  P. Kelemen,et al.  The role of H2O during crystallization of primitive arc magmas under uppermost mantle conditions and genesis of igneous pyroxenites: an experimental study , 2001 .

[105]  R. Sparks,et al.  Mineral disequilibrium in lavas explained by convective self-mixing in open magma chambers , 2001, Nature.

[106]  G. Yáñez,et al.  Magnetic anomaly interpretation across the southern central Andes (32°–34°S): The role of the Juan Fernández Ridge in the late Tertiary evolution of the margin , 2001 .

[107]  M. Cloos Bubbling Magma Chambers, Cupolas, and Porphyry Copper Deposits , 2001 .

[108]  Ren A. Thompson,et al.  Eruptive Stratigraphy of the Tatara–San Pedro Complex, 36°S, Southern Volcanic Zone, Chilean Andes: Reconstruction Method and Implications for Magma Evolution at Long-lived Arc Volcanic Centers , 2001 .

[109]  S. Kay,et al.  Central Andean Ore Deposits Linked to Evolving Shallow Subduction Systems and Thickening Crust , 2001 .

[110]  R. Tilling,et al.  Magma Mixing, Recharge and Eruption Histories Recorded in Plagioclase Phenocrysts from El Chichón Volcano, Mexico , 2000 .

[111]  Stephen Blake,et al.  On the deformation and freezing of enclaves during magma mixing , 2000 .

[112]  G. Yáñez,et al.  Inversion of an Oligocene volcano-tectonic basin and uplifting of its superimposed Miocene magmatic arc in the Chilean Central Andes: first seismic and gravity evidences , 1999 .

[113]  K. Uto,et al.  Geology and eruptive history of Unzen volcano, Shimabara Peninsula, Kyushu, SW Japan , 1999 .

[114]  R. Solidum,et al.  Petrology and geochemistry of Camiguin Island, southern Philippines: insights to the source of adakites and other lavas in a complex arc setting , 1999 .

[115]  B. W. Evans,et al.  Redox control of sulfur degassing in silicic magmas , 1998 .

[116]  M. D. Murphy,et al.  The role of magma mixing in triggering the current eruption at the Soufriere Hills Volcano, Montserrat, West Indies , 1998 .

[117]  I. Carmichael,et al.  The hydrous phase equilibria (to 3 kbar) of an andesite and basaltic andesite from western Mexico: constraints on water content and conditions of phenocryst growth , 1998 .

[118]  E. Christiansen,et al.  The Role of Magmatic Sulfides and Mafic Alkaline Magmas in the Bingham and Tintic Mining Districts, Utah , 1997 .

[119]  R. Sparks,et al.  Causes and consequences of pressurisation in lava dome eruptions , 1997 .

[120]  S. Kay,et al.  Geochronology of Miocene plutons and exhumation history of the El Teniente region, Central Chile (34-35°8) , 1997 .

[121]  M. Novacek,et al.  New evidence for late mesozoic-early Cenozoic evolution of the Chilean Andes in the upper Tinguiririca valley (35 °S), central Chile , 1996 .

[122]  H. Damme,et al.  Non-Newtonian effects during injection in partially crystallised magmas , 1996 .

[123]  C. Stern,et al.  Miocene to present magmatic evolution at the northern end of the Andean Southern Volcanic Zone, Central Chile , 1995 .

[124]  C. Stern,et al.  Genesis of the Giant Late Miocene to Pliocene Copper Deposits of Central Chile in the Context of Andean Magmatic and Tectonic Evolution , 1995 .

[125]  D. Peate,et al.  Tectonic Implications of the Composition of Volcanic Arc Magmas , 1995 .

[126]  W. Hildreth,et al.  Potassium-argon geochronology of a basalt-andesite-dacite arc system: The Mount Adams volcanic field, Cascade Range of southern Washington , 1994 .

[127]  J. Lowenstern,et al.  The role of magmas in the formation of hydrothermal ore deposits , 1994, Nature.

[128]  M. Drummond,et al.  Mount St. Helens: Potential example of the partial melting of the subducted lithosphere in a volcanic arc , 1993 .

[129]  J. Dilles,et al.  Wall-rock alteration and hydrothermal flow paths about the Ann-Mason porphyry copper deposit, Nevada; a 6-km vertical reconstruction , 1992 .

[130]  I. Wendt,et al.  The statistical distribution of the mean squared weighted deviation , 1992 .

[131]  R. Bodnar,et al.  Can economic porphyry copper mineralization be generated by a typical calc‐alkaline melt? , 1991 .

[132]  S. Kay,et al.  Magma source variations for mid–late Tertiary magmatic rocks associated with a shallowing subduction zone and a thickening crust in the central Andes (28 to 33°S) , 1991 .

[133]  J. Luhr Experimental Phase Relations of Water- and Sulfur-Saturated Arc Magmas and the 1982 Eruptions of El Chichón Volcano , 1990 .

[134]  M. Drummond,et al.  Derivation of some modern arc magmas by melting of young subducted lithosphere , 1990, Nature.

[135]  Y. Tatsumi Migration of fluid phases and genesis of basalt magmas in subduction zones , 1989 .

[136]  W. McDonough,et al.  Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes , 1989, Geological Society, London, Special Publications.

[137]  R. W. Le Maitre,et al.  A Classification of igneous rocks and glossary of terms : recommendations of the International Union of Geological Sciences Subcommission on the Systematics of Igneous Rocks , 1989 .

[138]  W. Hildreth,et al.  Crustal contributions to arc magmatism in the Andes of Central Chile , 1988 .

[139]  R. Drake,et al.  Miocene volcanism in the central Chilean Andes (31°30′S–34°35′S) , 1988 .

[140]  J. Dilles Petrology of the Yerington Batholith, Nevada; evidence for evolution of porphyry copper ore fluids , 1987 .

[141]  M. Rutherford,et al.  The stability of igneous anhydrite - Experimental results and implications for sulfur behavior in the 1982 El Chichon trachyandesite and other evolved magmas , 1987 .

[142]  R. Sparks,et al.  Thermal and mechanical constraints on mixing between mafic and silicic magmas , 1986 .

[143]  C. Bacon Magmatic inclusions in silicic and intermediate volcanic rocks , 1986 .

[144]  F. Barassi,et al.  Porphyry copper and tourmaline breccias at Los Bronces-Rio Blanco, Chile , 1985 .

[145]  T. Furman,et al.  Co-mingling of acid and basic magma with implications for the origin of mafic I-type xenoliths: Field and petrochemical relations of an unusual dike complex at eagle lake, Sequoia National Park, California, U.S.A. , 1985 .

[146]  T. Grove,et al.  Coupled CaAl-NaSi diffusion in plagioclase feldspar: Experiments and applications to cooling rate speedometry , 1984 .

[147]  R. Vernon Microgranitoid enclaves in granites—globules of hybrid magma quenched in a plutonic environment , 1984, Nature.

[148]  H. D. Holland,et al.  The partitioning of copper and molybdenum between silicate melts and aqueous fluids , 1984 .

[149]  M. T. Naney Phase equilibria of rock-forming ferromagnesian silicates in granitic systems , 1983 .

[150]  R. Kay Aleutian magnesian andesites: Melts from subducted Pacific ocean crust , 1978 .

[151]  L. B. Gustafson,et al.  The porphyry copper deposit at El Salvador, Chile , 1975 .

[152]  R. Sillitoe The tops and bottoms of porphyry copper deposits , 1973 .

[153]  T. Irvine,et al.  A Guide to the Chemical Classification of the Common Volcanic Rocks , 1971 .

[154]  A. H. Jaffey,et al.  Precision Measurement of Half-Lives and Specific Activities of U-235 and U238 , 1971 .

[155]  I. Gibson,et al.  Some relationships resulting from the intimate association of acid and basic magmas , 1965, Quarterly Journal of the Geological Society of London.