An intrusion-related origin for Cu–Au mineralization in iron oxide–copper–gold (IOCG) provinces

Major Cu–Au deposits of iron oxide–copper–gold (IOCG) style are temporally associated with oxidized, potassic granitoids similar to those linked to major porphyry Cu–Au deposits. Stable and radiogenic isotope evidence indicates fluids and ore components were likely sourced from the intrusions. IOCG deposits form over a range of crustal levels because CO2-rich fluids separate from the magmas at higher pressures than in CO2-poor systems, thereby, promoting partitioning of H2O, Cl and metals to the fluid phase. At deep levels, the magma–fluid system cannot generate sufficient mechanical energy to fracture the host rocks as in porphyry systems and the IOCG deposits therefore form in a variety of fault-related structural traps where the magmatic fluids may mix with other fluids to promote ore formation. At shallow levels, the IOCG deposits form breccia and fracture-hosted mineralization styles similar to the hydrothermal intrusive breccias and sulphide vein systems that characterize many porphyry Cu–Au deposits. The fluids associated with IOCG deposits are typically H2O–CO2–salt fluids that evolve by unmixing of the carbonic phase and by mixing with fluids from other sources. In contrast, fluids in porphyry systems typically evolve by boiling of moderate salinity fluid to produce high salinity brine and a vapor phase commonly with input of externally derived fluids. These different fluid compositions and mechanisms of evolution lead to different alteration types and parageneses in porphyry and IOCG deposits. Porphyry Cu–Au deposits typically evolve through potassic, sericitic and (intermediate and/or advanced) argillic stages, while IOCG deposits typically evolve through sodic(–calcic), potassic and carbonate-rich stages, and at deeper levels, generally lack sericitic and argillic alteration. The common association of porphyry and IOCG Cu–Au deposits with potassic, oxidized intermediate to felsic granitoids, together with their contrasting fluid compositions, alteration styles and parageneses suggest that they should be considered as part of the broad family of intrusion-related systems but that they are typically not directly related to each other.

[1]  W. Gunter,et al.  The role of speciation in alkaline igneous fluids during fenite metasomatism , 1983 .

[2]  T. Baker,et al.  Modeling the Role of Sodic Alteration in the Genesis of Iron Oxide-Copper-Gold Deposits, Eastern Mount Isa Block, Australia , 2004 .

[3]  D. Groves,et al.  Geology and SHRIMP U-Pb Geochronology of the Igarapé Bahia Deposit, Carajás Copper-Gold Belt, Brazil: An Archean (2.57 Ga) Example of Iron-Oxide Cu-Au-(U-REE) Mineralization , 2005 .

[4]  Geordie Mark,et al.  Mineralogical and chemical evolution of the Ernest Henry Fe oxide–Cu–Au ore system, Cloncurry district, northwest Queensland, Australia , 2006 .

[5]  P. A. Cross,et al.  Lecture notes in Earth sciences: Vol. 12. S. Turner (Editor), Applied Geodesy VIII, Springer, Berlin, F.R.G., 1987, 393pp, DM78.00, ISBN 3 540 182195 , 1989 .

[6]  J. Lowenstern Carbon dioxide in magmas and implications for hydrothermal systems , 2001 .

[7]  C. Ryan,et al.  Geochemistry of hypersaline fluid inclusions from the Starra (Fe Oxide)-Au-Cu deposit, Cloncurry district, Queensland , 2001 .

[8]  M. Barton,et al.  Evaporitic-source model for igneous-related Fe oxide-(REE-Cu-Au-U) mineralization , 1996 .

[9]  M. Dardenne,et al.  The role of shoshonitic and calc-alkaline suites in the tectonic evolution of the Carajás District, Brazil , 1988 .

[10]  Geordie Mark,et al.  Geochemistry of post-1540 Ma granites in the Cloncurry District, Northwest Queensland , 1998 .

[11]  N. Oreskes,et al.  Origin of hydrothermal fluids at Olympic Dam; preliminary results from fluid inclusions and stable isotopes , 1992 .

[12]  P. Betts,et al.  Geophysical constraints of shear zones and geometry of the Hiltaba Suite granites in the western Gawler Craton, Australia , 2003 .

[13]  S. Taylor,et al.  Geochemistry of eocene calc-alkaline volcanic rocks from the Kastamonu area, Northern Turkey , 1976 .

[14]  L. Fontboté,et al.  Re–Os and Pb–Pb geochronology of the Archean Salobo iron oxide copper–gold deposit, Carajás mineral province, northern Brazil , 2003 .

[15]  R. Sillitoe Iron oxide-copper-gold deposits: an Andean view , 2003 .

[16]  D. Günther,et al.  The Evolution of a Porphyry Cu-Au Deposit, Based on LA-ICP-MS Analysis of Fluid Inclusions: Bajo de la Alumbrera, Argentina , 2001 .

[17]  Z. Lindenmayer,et al.  U-Pb geochronology of Archean magmatism and basement reactivation in the Carajás area, Amazon shield, Brazil , 1991 .

[18]  Shiqi Wang,et al.  Geochemistry and origin of Proterozoic skarns at the Mount Elliott Cu–Au(–Co–Ni) deposit, Cloncurry district, NW Queensland, Australia , 2001 .

[19]  R. Creaser,et al.  A-type granites revisited: Assessment of a residual-source model , 1991 .

[20]  Robert Marschik,et al.  Geochemical and Sr–Nd–Pb–O isotope composition of granitoids of the Early Cretaceous Copiapó plutonic complex (27°30′S), Chile , 2003 .

[21]  R. Holdsworth,et al.  The anatomy of shallow-crustal transpressional structures: insights from the Archaean Carajás fault zone, Amazon, Brazil , 2000 .

[22]  R. Creaser Petrogenesis of a Mesoproterozoic quartz latite-granitoid suite from the Roxby Downs area, South Australia , 1996 .

[23]  B. Lehmann Metallogeny of Tin , 1991 .

[24]  N. Oreskes,et al.  Origin of rare earth element-enriched hematite breccias at the Olympic Dam Cu-U-Au-Ag deposit, Roxby Downs, South Australia , 1990 .

[25]  H. Keppler Influence of fluorine on the enrichment of high field strength trace elements in granitic rocks , 1993 .

[26]  P. Barbey,et al.  Geochemistry of the Estrela Granite Complex, Carajás region, Brazil: an example of an Archaean A-type granitoid , 1997 .

[27]  R. Page,et al.  Aspects of geochronology and crustal evolution in the Eastern Fold Belt, Mt Isa Inlier∗ , 1998 .

[28]  I. Cartwright,et al.  Stable isotope evidence for the origin of the Mesoproterozoic Starra Au-Cu deposit, Cloncurry District, Northwest Queensland , 1998 .

[29]  R. Creaser,et al.  U-Pb geochronology of middle Proterozoic felsic magmatism surrounding the Olympic Dam Cu-U-Au-Ag and Moonta Cu-Au-Ag deposits, South Australia , 1993 .

[30]  Michael D. Brown,et al.  Mesozoic Magmatic and Tectonic Events within the Andean Plate Boundary Zone, 26°-27°30'S, North Chile: Constraints from 40Ar/39Ar Mineral Ages , 1996, The Journal of Geology.

[31]  L. Fontboté,et al.  The Candelaria-Punta del Cobre Iron Oxide Cu-Au(-Zn-Ag) Deposits, Chile , 2001 .

[32]  M. Barton,et al.  Porphyry deposits; characteristics and origin of hypogene features , 2005 .

[33]  K. Blake,et al.  The Lightning Creek Sill Complex, Cloncurry District, Northwest Queensland: A Source of Fluids for Fe Oxide Cu-Au Mineralization and Sodic-Calcic Alteration , 2000 .

[34]  P. Pollard Sodic(–calcic) alteration in Fe-oxide–Cu–Au districts: an origin via unmixing of magmatic H2O–CO2–NaCl ± CaCl2–KCl fluids , 2001 .

[35]  T. Vila Geology of the Manto Verde copper deposit, northern Chile : a speculariterich, hydrothermal-tectonic breccia related to the Atacama fault zone , 1996 .

[36]  P. Blevin,et al.  Chemistry, origin, and evolution of mineralized granites in the Lachlan fold belt, Australia; the metallogeny of I- and S-type granites , 1995 .

[37]  R. Valenta,et al.  The evolution of the Ernest Henry Fe-OXIDE-(Cu-Au) hydrothermal system , 2000 .

[38]  A. Tindle,et al.  Trace Element Discrimination Diagrams for the Tectonic Interpretation of Granitic Rocks , 1984 .

[39]  P. Betts,et al.  Evolution of the Australian lithosphere , 2002 .

[40]  Robert Marschik,et al.  Age of Mineralization of the Candelaria Fe Oxide Cu-Au Deposit and the Origin of the Chilean Iron Belt, Based on Re-Os Isotopes , 2003 .

[41]  P. Pollard,et al.  Australian Proterozoic Iron Oxide-Cu-Au Deposits: An Overview with New Metallogenic and Exploration Data from the Cloncurry District, Northwest Queensland , 2001 .

[42]  J. Richards,et al.  Review of the application of isotopic studies to the genesis of Cu-Au mineralisation at Olympic Dam and Au mineralisation at Porgera, the Tennant Creek district and Yilgarn Craton , 1998 .

[43]  Patrick J. Williams,et al.  Stable isotope evidence for magmatic fluid input during large‐scale Na–Ca alteration in the Cloncurry Fe oxide Cu–Au district, NW Queensland, Australia , 2004 .

[44]  M. Barton,et al.  Iron oxide copper-gold deposits: geology, space-time distribution, and possible modes of origin , 2005 .

[45]  R. Petersen,et al.  Andean Copper Deposits: New Discoveries, Mineralization, Styles and Metallogeny , 1998 .

[46]  B. Singer,et al.  Age of Cu(-Fe)-Au mineralization and thermal evolution of the Punta del Cobre district, Chile , 1997 .

[47]  L. Wyborn,et al.  Age of Cu‐Au mineralisation, Cloncurry district, eastern Mt Isa Inlier, Queensland, as determined by 40Ar/39Ar dating∗ , 1998 .

[48]  S. Kesler Metallogeny of tin lecture notes in earth sciences 32: B. Lehmann. edited by S. Battacharji et al. Springer-Verlag, 1990, viii + 211p., US $29.00 (ISBN 0-387-52806-7) , 1992 .

[49]  T. Irvine,et al.  A Guide to the Chemical Classification of the Common Volcanic Rocks , 1971 .

[50]  James P. Johnson,et al.  U-Pb geochronological constraints on the genesis of the Olympic Dam Cu-U-Au-Ag deposit, South Australia , 1995 .

[51]  M. McCulloch,et al.  Sources of mineralising fluids for the Olympic Dam deposit (South Australia) : SmNd isotopic constraints , 1995 .

[52]  S. Ishihara The granitoid series and mineralization , 1981 .

[53]  T. Baker,et al.  Radiogenic and Stable Isotope Constraints on the Genesis of the Eloise Cu- Au Deposit, Cloncurry District, Northwest Queensland , 2001 .

[54]  M. Reed,et al.  Olympic Dam ore genesis; a fluid-mixing model , 1995 .

[55]  L. Fontboté,et al.  Implications of Pb isotope signatures of rocks and iron oxide Cu-Au ores in the Candelaria-Punta del Cobre district, Chile , 2003 .

[56]  R. Sillitoe,et al.  Characteristics and controls of the largest porphyry copper‐gold and epithermal gold deposits in the circum‐Pacific region , 1997 .