Constitutive equations in suspension mechanics. Part 1. General formulation

Neither the phenomenological nor the structural approach to the determination of constitutive equations has yet shown itself to be capable of producing useful and predictive descriptions of the majority of technologically important complex fluids. In the present paper we explore the suggestion that significant progress can be made when these two complementary approaches to rheology are combined. For this initial study we restrict our attention to materials which can be modelled as a suspension of particles in a Newtonian fluid, thereby including most polymer solutions while excluding polymer melts. By applying phenomenological techniques to the basic formulation of suspension mechanics we are able to deduce a common simplified constitutive model for all suspension-like materials and to reveal its physical origin. The present analysis demonstrates that the constitutive model of Hand (1962), involving a single second-order tensor, is not sufficiently general for a rigorous description of the majority of suspension-like materials. Consideration of the constitutive forms for the limiting cases of near-equilibrium and strongly non-equilibrium microstructure suggests, however, that Hand's model may provide a reasonable approximation to the exact constitutive behaviour which is useful over the whole range of flow strengths.