Formation of Ohmic contacts: A breakdown mechanism in metal-insulator-metal structures

The occurrence of low currents in metal-insulator-metal (MIM) structures when high fields are present depends on the presence of a large energy barrier to charge injection at both metal-insulator interfaces. Formation of an Ohmic contact at either metal-insulator interface results in the easy injection of charge carriers into the insulator. The temperature dependence of current-voltage (I-V) characteristics of an Al–Al2O3–Au diode with 23nm of anodically formed Al2O3, after nondestructive dielectric breakdown, is reported. An Ohmic contact forms after initial breakdown as shown by the occurrence of space-charge limited currents, I∝V2, with an effective barrier height of 0.01–0.02eV that is independent of bias. Further breakdown of the MIM sample results in the forming of voltage-controlled negative resistance (VCNR) in the I-V characteristic and the observation of electroluminescence. Elimination of the VCNR conduction regime results in I-V characteristics of a form I∝Vn, where n is temperature dependent ...

[1]  R. Gurney,et al.  Electronic Processes in Ionic Crystals , 1964 .

[2]  Guido Groeseneken,et al.  Hot carrier degradation and time-dependent dielectric breakdown in oxides , 1999 .

[3]  J. J. O'Dwyer,et al.  The theory of electrical conduction and breakdown in solid dielectrics , 1973 .

[4]  T. W. Hickmott Temperature-dependent Fowler–Nordheim tunneling and a compensation effect in anodized Al-Al2O3-Au diodes , 2005 .

[5]  S. McKeever,et al.  Photoionization of deep centers in Al2O3 , 2000 .

[6]  Energetic electronic processes and negative resistance in amorphous TaTa2O5Au and AlAl2O3Au diodes , 1972 .

[7]  T. W. Hickmott LOW-FREQUENCY NEGATIVE RESISTANCE IN THIN ANODIC OXIDE FILMS , 1962 .

[8]  A. Goodman Photoemission of Holes and Electrons from Aluminum into Aluminum Oxide , 1970 .

[9]  S. Ikonopisov Problems and contradictions in galvanoluminescence, a critical review , 1975 .

[10]  K. Kao 6 – Charge Carrier Injection from Electrical Contacts , 2004 .

[11]  A. Ray,et al.  Invited paper A critical review of the observed electrical properties of MIM devices showing VCNR , 1984 .

[12]  Brian E. Conway,et al.  Modern Aspects of Electrochemistry , 1974 .

[13]  D. Morgan,et al.  Electrical phenomena in amorphous oxide films , 1970 .

[14]  Y. Koide,et al.  Ohmic Contacts for Compound Semiconductors , 1998 .

[15]  J. Stathis Percolation models for gate oxide breakdown , 1999 .

[16]  H. Biederman Metal-insulator-metal sandwich structures with anomalous properties , 1976 .

[17]  Jordi Suñé,et al.  Electron transport through broken down ultra-thin SiO2 layers in MOS devices , 2004, Microelectron. Reliab..

[18]  J. Simmons Theory of metallic contacts on high resistivity solids—I. Shallow traps , 1971 .

[19]  T. W. Hickmott Electron Emission, Electroluminescence, and Voltage‐Controlled Negative Resistance in Al–Al2O3–Au Diodes , 1965 .

[20]  J. Stathis,et al.  Dielectric breakdown mechanisms in gate oxides , 2005 .

[21]  Guoxian Li,et al.  Wavelength dependent photoluminescence of anodic alumina membranes , 2003 .

[22]  T. W. Hickmott Impurity Conduction and Negative Resistance in Thin Oxide Films , 1964 .

[23]  N. Klein A theory of localized electronic breakdown in insulating films , 1972 .

[24]  Albert Rose,et al.  Space-Charge-Limited Currents in Solids , 1955 .

[25]  J. Kadlec,et al.  Results and problems of internal photoemission in sandwich structures , 1976 .

[26]  A. Goodman Electron Hall effect in silicon dioxide , 1967 .

[27]  Yu. Yankelevitch The thin film metal-insulator-metal system used as a non-heated source of electrons , 1980 .

[28]  M. Lampert,et al.  Current injection in solids , 1970 .

[29]  T. W. Hickmott Voltage-dependent dielectric breakdown and voltage-controlled negative resistance in anodized Al–Al2O3–Au diodes , 2000 .