论文信息 - Diastereospecific synthesis of amino-acid substituted 2,2′-bipyridyl complexes - 字舞流文

Diastereospecific synthesis of amino-acid substituted 2,2′-bipyridyl complexes

The L-valine substituted 2,2′-bipyridyl ligand 1 forms Δ-M(1)3 (M = FeII, CoII, CoIII) complexes diastereospecifically, with the L-valinate arms forming a chiral anion-binding pocket in the solid state.

G. Bernardinelli | S. Telfer | Alan F. Williams

[1] Philip A. Gale,et al. Anion Recognition and Sensing: The State of the Art and Future Perspectives. , 2001, Angewandte Chemie.

[2] M. Ziegler. Charge-transfer excited state properties of chiral transition metal coordination compounds studied by chiroptical spectroscopy , 1998 .

[3] A. Patri,et al. Synthesis of Unsymmetrical 5,5'-Disubstituted 2,2'-Bipyridines(1). , 1997, The Journal of organic chemistry.

[4] J. Sauvain,et al. Stereoselectivity in Reactions of Metal Complexes. Part XV. Structure and stability of chiral cobalt(III) complexes with pentadentate ligands , 1992 .

[5] P. Healy,et al. Structural studies in the iron(III)/chloride/α,α'-diimine system. III. Crystal structures of Tris(2,2'-bipyridine)iron(II) μ-Oxo-bis[trichloroferrate(III)] and of 'Compound A', μ-Oxo-bis[cis-chlorobis(1 ,10-phenanthroline)iron(III)] chloride solvate , 1983 .