论文信息 - Preparation and crystal structure of [(AlBr3)2(Se2N2)], the first example of a main-group element adduct of diselenium dinitride

Preparation and crystal structure of [(AlBr3)2(Se2N2)], the first example of a main-group element adduct of diselenium dinitride

The room temperature reaction of AlBr3 with Se4N4 in CH2Br2 generated [(AlBr3)2(Se2N2)] as an air-sensitive, yellow solid; X-ray crystallography confirmed the presence of the neutral Se2N2 ligand, bridging via two Al–N bonds.

A. Slawin | P. Kelly

[1] A. Slawin,et al. The Preparation of Salts of [Pd2(μ‐Se2N2)Cl6]2−, the First Adducts of Diselenium Dinitride , 1995 .

[2] H. Roesky,et al. SYNTHESIS AND CRYSTAL STRUCTURE OF ((PH3P)2(CO)2(S2N2)RUCL)+ALCL4‐. PREPARATION OF NOVEL S2N2 COMPLEXES , 1984 .

[3] U. Thewalt,et al. Cleavage of S4N4 to S2N2 at Room Temperature: Formation and Structure of (AlCl3)2S2N2 , 1982 .