A study on dielectric response of bitumen in the low-frequency range

From the current state of literature, the dielectric property of bitumen has not been understood extensively, nor its relation with other properties such as polarity and rheology. In this study, dielectric spectroscopy measurement in a low-frequency range (10−2–106 Hz) was performed on both pure bitumen in different grades and wax-modified bitumen (WMB). From the performed tests we found the following: (i) the dielectric response of base bitumen is strongly temperature and frequency dependent, which is also highly linked to the rheology of the system. (ii) No remarkable differences in the dielectric constant among different grades of bitumen from the same crude oil source can be seen. (iii) Regular changes of dielectric loss tangent (tan δ) among the different grades of bitumen can be observed, which can be a good indicator for the linkage between the dielectric and rheological responses. In addition, it can also be perceived that the dielectric spectroscopy may have the potential to become a new approach for the multi-scale characterisation of road infrastructure materials.

[1]  Åsa Laurell Lyne,et al.  Adhesion between bitumen and aggregate: implementation of spectroscopic ellipsometry characterisation and estimation of Hamaker’s constant , 2013 .

[2]  J. Shea Electrical Properties of Polymers, 2nd edition [Book Review] , 2007, IEEE Electrical Insulation Magazine.

[3]  Xiaohu Lu,et al.  Wax morphology in bitumen , 2005 .

[4]  C. P. Smyth,et al.  Dielectrics and Waves. , 1955 .

[5]  Timo Saarenketo,et al.  Electrical properties of road materials and subgrade soils and the use of ground penetrating radar in traffic infrastructure surveys , 2006 .

[6]  H. Soenen,et al.  Correlation between Bitumen Polarity and Rheology , 2005 .

[7]  Felice Giuliani,et al.  Structural and rheological characterization of wax modified bitumens , 2012 .

[8]  H. Maruska,et al.  THE ROLE OF POLAR SPECIES IN THE AGGREGATION OF ASPHALTENES , 1987 .

[9]  P. Redelius Solubility parameters and bitumen , 2000 .

[10]  K. Cole,et al.  Dispersion and Absorption in Dielectrics I. Alternating Current Characteristics , 1941 .

[11]  Per Redelius,et al.  The structure of asphaltenes in bitumen , 2006 .

[12]  Application of Microwave Energy for Indirect Determination of Asphalt Total Polarity and Sulfur and Sulfide Content , 1998 .

[13]  Tine Tanghe,et al.  A laboratory study on the use of waxes to reduce paving temperatures , 2008 .

[14]  A. R. Blythe,et al.  Electrical properties of polymers , 1979 .

[15]  Linear response of regular asphalts to external harmonic fields , 1999 .

[16]  N. Taylor Dielectric response and partial discharge measurements on stator insulation at varied low frequency , 2010 .

[17]  Björn Birgisson,et al.  Micromechanical investigation of phase separation in bitumen by combining atomic force microscopy with differential scanning calorimetry results , 2013 .

[18]  I. N. Evdokimov,et al.  Electrical Conductivity and Dielectric Properties of Solid Asphaltenes , 2010 .

[19]  Z. Lei,et al.  Investigation of the effects of wax additive on the properties of asphalt binder , 2012 .

[20]  A. Helgeson,et al.  Analysis of dielectric response measurement methods and dielectric properties of resin-rich insulation during processing , 2000 .

[21]  P. Redelius Bitumen Solubility Model Using Hansen Solubility Parameter , 2004 .