Plasmonics and near field optics for sensing purposes

In the first part of the thesis I present a theoretical and experimental work due to develop a performing configuration for gas-sensing through the employ of Surface Plasmon Resonance effect. Different sensing layers have been studied and tested on our optical bench assembly. Metallic (Au) and bimetallic (Ag/Au) layers have been properly designed through simulations and then have been realized through electron-beam evaporation. TiO2 and TiO2 - Au doped layers have been deposited on the top of some of the metallic samples. These layers were prepared by the sol gel route. In the second part I focused on the development of an experimental set-up able to study the local field at an interface between two dielectrics. An approach based on photo-thermal-deflection has been used. Chromophores have been used as probes of the local field

[1]  S. Yeh,et al.  Applications of photothermal beam deflection calorimetry to organic photochemistry , 1995 .

[2]  H. Raether Surface Plasmons on Smooth and Rough Surfaces and on Gratings , 1988 .

[3]  A. García-Valenzuela,et al.  Design of an optical probe based on angle scanning reflectometry near the critical angle , 2003 .

[4]  Günter Gauglitz,et al.  Surface plasmon resonance sensors: review , 1999 .

[5]  P. Nicolosi,et al.  Different sensing layers for SPR sensing of organic vapours , 2008, NanoScience + Engineering.

[6]  Application of spectral surface plasmon resonance to gas pressure sensing , 2005 .

[7]  Y. Vlasov,et al.  Surface plasmon resonance monitoring by means of polarization state measurement in reflected light as the basis of a DNA-probe biosensor , 1996 .

[8]  Ken Gall,et al.  Intrinsic stress development and microstructure evolution of Au/Cr/Si multilayer thin films subject to annealing , 2005 .

[9]  Y. Shiraki,et al.  Thin‐film transistors on molecular‐beam‐deposited polycrystalline silicon , 1984 .

[10]  Zhongfan Liu,et al.  Gold nanoparticulate film bound to silicon surface with self-assembled monolayers , 1998 .

[11]  B. D. Gupta,et al.  On the performance of different bimetallic combinations in surface plasmon resonance based fiber optic sensors , 2007 .

[12]  J. D. Swalen,et al.  Anomalous dispersion of surface plasma oscillations , 1978 .

[13]  Zbigniew Opilski,et al.  An optical detection NH$_{3}$ gas by means of a-WO$_{3}$ thin films based on SPR technique* , 2005 .

[14]  Andre Knoesen,et al.  Absolute absorption measurements in polymer films using photothermal deflection spectroscopy , 1999, Optics & Photonics.

[15]  Mikhail A. Proskurnin,et al.  Modern analytical thermooptical spectroscopy , 2004 .

[16]  E. Kretschmann,et al.  Notizen: Radiative Decay of Non Radiative Surface Plasmons Excited by Light , 1968 .

[17]  M. Kreiter,et al.  Ensemble measurement of the orientation-dependent variations in chromophore lifetimes near a dielectric interface , 2009 .

[18]  R. S. Mendes,et al.  Time-resolved thermal mirror method: A theoretical study , 2008 .

[19]  Otto S. Wolfbeis,et al.  Nanometer-thick SPR sensor for gaseous HCl , 2005 .

[20]  B. Liedberg,et al.  Gas detection by means of surface plasmon resonance , 1982 .

[21]  C. Kittel Introduction to solid state physics , 1954 .

[22]  A. Otto Excitation of nonradiative surface plasma waves in silver by the method of frustrated total reflection , 1968 .

[23]  T Turbadar,et al.  Complete Absorption of Light by Thin Metal Films , 1959 .

[24]  R. Wood,et al.  On a Remarkable Case of Uneven Distribution of Light in a Diffraction Grating Spectrum , 1902 .

[25]  Resistivity and adhesive strength of thin film metallizations on single crystal quartz , 1997, IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control.

[26]  S. Kawata,et al.  A Compact Surface Plasmon Resonance Sensor for Measurement of Water in Process , 1988 .

[27]  Yan Huang,et al.  Effect of annealing on the characteristics of Au/Cr bilayer films grown on glass , 2003 .

[28]  Lionel Bertrand,et al.  Separation of surface and volume absorption by photothermal deflection , 1989 .

[29]  Pietro Siciliano,et al.  Investigation on alcohol vapours/TiO2 nanocrystal thin films interaction by SPR technique for sensing application , 2004 .

[30]  Bincheng Li,et al.  Sensitive photothermal interferometric detection method for characterization of transparent plate samples , 1996 .

[31]  Zhiliang Liu,et al.  Layer-by-layer assembly of multicolored semiconductor quantum dots towards efficient blue, green, red and full color optical films , 2008, Nanotechnology.

[32]  P. Siciliano,et al.  Tests in controlled atmosphere on new optical gas sensing layers based on TiO2/metal-phthalocyanines hybrid system , 2002 .

[33]  Alex A. Volinsky,et al.  Effects of diffusion on interfacial fracture of gold-chromium hybrid microcircuit films , 2003 .