Functions of iota-carrageenan on the gelatinization and retrogradation behaviors of corn starch in the presence or absence of various salts

Abstract Gelatinization and retrogradation behaviors of the aqueous starch/iota-carrageenan composite system (0.5 w/v% starch and 0.2% carrageenan) were investigated. Purified iota-carrageenan in sodium form was mixed with corn starch in the presence or absence of various salts. Functions of iota-carrageenan on starch depended on salts added. During gelatinization, the addition of iota-carrageenan lowered the incipient swelling temperature of the composite system with decreased peak viscosity in the absence of added salts and in the presence of monovalent cations, while the temperature increased in the presence of divalent cations. It also increased the rate constant for short-term (

[1]  K. Nishinari,et al.  Influence of molecular structure imaged with atomic force microscopy on the rheological behavior of carrageenan aqueous systems in the presence or absence of cations , 2007 .

[2]  M. Liehr,et al.  Rheological examination of the influence of hydrocolloids on the freeze-thaw-stability of starch gels , 1996 .

[3]  G. Phillips,et al.  Phase behaviour and rheology of mixed polymer systems containing starch , 1994 .

[4]  K. Nishinari,et al.  Functions of fenugreek gum with various molecular weights on the gelatinization and retrogradation behaviors of corn starch—2: Characterizations of starch and investigations of corn starch/fenugreek gum composite system at a relatively low starch concentration; 5 w/v% , 2008 .

[5]  Katsuyoshi Nishinari,et al.  Food hydrocolloids control the gelatinization and retrogradation behavior of starch. 2b. Functions of guar gums with different molecular weights on the retrogradation behavior of corn starch , 2005 .

[6]  Glyn O. Phillips,et al.  Food Polysaccharides and Their Applications , 2006 .

[7]  M. Miles,et al.  The effect of concentration and botanical source on the gelation and retrogradation of starch , 1987 .

[8]  D. Brant,et al.  Imaging of carrageenan macrocycles and amylose using noncontact atomic force microscopy. , 1999, International journal of biological macromolecules.

[9]  Peter A. Williams,et al.  Effect of dextran on the thermal and rheological properties of sago starch , 2000 .

[10]  A. Raemy,et al.  A comparative study of the retrogradation kinetics of gelatinized wheat starch in gel and powder form using X-rays, differential scanning calorimetry and dynamic mechanical analysis , 1988 .

[11]  B. O'kennedy,et al.  Rheology of Stirred Yogurt as Affected by Added Milk Fat, Protein and Hydrocolloids , 1998 .

[12]  J. Doublier,et al.  Viscoelastic properties of maize starch/hydrocolloid pastes and gels , 1991 .

[13]  K. Kohyama,et al.  Cellulose derivatives effects on gelatinization and retrogradation of sweet potato starch , 1992 .

[14]  P. Muhrbeck,et al.  Effects of small amounts of kappa-carrageenan on the rheology of aqueous iota-carrageenan , 1992 .

[15]  K. Nishinari,et al.  Rheological studies on mixtures of corn starch and konjac-glucomannan , 1998 .

[16]  C. Rochas,et al.  87Rb+ spin relaxation in enzymically purified and in untreated iota-carrageenan. , 1990, Carbohydrate research.

[17]  M. Miles,et al.  Gelation of amylose , 1985 .

[18]  M. Miles,et al.  The roles of amylose and amylopectin in the gelation and retrogradation of starch , 1985 .

[19]  Xiaohong Shi,et al.  Effects of food gums on viscosities of starch suspensions during pasting , 2002 .

[20]  K. Nishinari,et al.  Effects of xyloglucan on the gelatinization and retrogradation of corn starch as studied by rheology and differential scanning calorimetry , 1999 .

[21]  R. J. Tye The rheology of starch/carrageenan systems , 1988 .

[22]  F. Escher,et al.  Phase separation and rheology of aqueous starch/galactomannan systems , 1999 .

[23]  L. Piculell,et al.  On the specificity of the binding of cations to carrageenans: Counterion N.M.R. spectroscopy in mixed carrageenan systems , 1989 .

[24]  D. D. Christianson,et al.  Starch-hydrocolloid composites prepared by steam jet cooking , 1996 .

[25]  A. Eliasson,et al.  The Effects of Water Soluble Arabinoxylan on Gelatinization and Retrogradation of Starch , 1991 .

[26]  H. Park,et al.  Freeze–thaw stabilization of sweet potato starch gel by polysaccharide gums , 2002 .

[27]  K. Nishinari,et al.  Effects of non-ionic polysaccharides on the gelatinization and retrogradation behavior of wheat starch☆ , 2005 .

[28]  E. Tojo,et al.  A simple 1H NMR method for the quantification of carrageenans in blends , 2003 .

[29]  J. Lefebvre,et al.  A rheological characterization of cereal starch-galactomannan mixtures , 1989 .

[30]  K. Nishinari,et al.  Effects of Konjac-Glucomannan on the Gelatinization and Retrogradation of Corn Starch As Determined by Rheology and Differential Scanning Calorimetry , 1996 .

[31]  M. Glicksman Gum Technology in the Food Industry , 1969 .

[32]  M. Rao,et al.  Effect of hydrocolloids on the rheological properties of wheat starch , 1987 .

[33]  W. Breene,et al.  Rapid Visco‐Analyzer (RVA) Pasting Profiles of Wheat, Corn, Waxy Corn, Tapioca and Amaranth Starches (A. hypochondriacus and A cruentus) in the Presence of Konjac Flour, Gellan, Guar, Xanthan and Locust Bean Gums , 1994 .

[34]  W. Kulicke,et al.  Rheologische Untersuchungen zum Einfluß von Hydrokolloiden auf die Gefrier-Tau-Stabilität von Stärkekleistern , 1996 .

[35]  D. D. Christianson,et al.  Gelatinization of wheat starch as modified by xanthan gum, guar gum, and cellulose gum. , 1981 .

[36]  I. Norton,et al.  Ultrastructural evidence for intramolecular double stranding in iota-carrageenan. , 1993, Carbohydrate research.

[37]  J. Chrastil Improved colorimetric determination of amylose in starches or flours , 1987 .