Interface screening and imprint in poly(vinylidene fluoride/trifluoroethylene) ferroelectric field effect transistors

We investigated the imprint effect in ferroelectric capacitors and field effect transistors (FETs) with a poly(vinylidene fluoride/trifluoroethylene) [P(VDF-TrFE)] ferroelectric insulator. The shift in switching voltages and the change in the ferroelectric FET (FeFET) channel conductance were measured as a function of time and the thickness of the ferroelectric layer. Analyzing our experimental data, we show that the imprint originates from interface-induced processes, which effectively screen polarization charges in P(VDF-TrFE). This phenomenon significantly influences the retention of FeFET channel conductance and the memory functionality of FeFET with P(VDF-TrFE).

[1]  Y. Koval’,et al.  Mechanism of etching and surface relief development of PMMA under low-energy ion bombardment , 2004 .

[2]  Chien-Jang Wu,et al.  Device modeling of ferroelectric memory field-effect transistor (FeMFET) , 2002 .

[3]  K. Henkel,et al.  Organic field effect transistors with ferroelectric hysteresis , 2007 .

[4]  Y. Koval’,et al.  Graphitization of polymer surfaces by low-energy ion irradiation , 2007 .

[5]  N. Neumann,et al.  Pyroelectric thin film sensors and arrays based on P(VDF/TrFE) , 1995 .

[6]  Paul J. McWhorter,et al.  Physics of the ferroelectric nonvolatile memory field effect transistor , 1992 .

[7]  K. Rabe,et al.  Physics of thin-film ferroelectric oxides , 2005, cond-mat/0503372.

[8]  Rainer Waser,et al.  The interface screening model as origin of imprint in PbZrxTi1−xO3 thin films. I. Dopant, illumination, and bias dependence , 2002 .

[9]  A. Tagantsev,et al.  Interface-induced phenomena in polarization response of ferroelectric thin films , 2006 .

[10]  P. Blom,et al.  Low voltage switching of a spin cast ferroelectric polymer , 2004 .

[11]  S. Gevorgian,et al.  Ferroelectric thin films: Review of materials, properties, and applications , 2006 .

[12]  Gerwin H. Gelinck,et al.  High-performance solution-processed polymer ferroelectric field-effect transistors , 2005 .

[13]  Y. Koval’,et al.  Conductance enhancement of polymethylmethacrylate bombarded by low-energy ions , 2005 .

[14]  R. Waser,et al.  The interface screening model as origin of imprint in PbZrxTi1-xO3 thin films. II. Numerical simulation and verification , 2002 .

[15]  T. Furukawa Ferroelectric properties of vinylidene fluoride copolymers , 1989 .

[16]  M. Grell,et al.  Memory performance and retention of an all-organic ferroelectric-like memory transistor , 2005, IEEE Electron Device Letters.