Herbicide contamination of surficial groundwater in Northern Italy.

Data on herbicide pollution in groundwater are rather scarce; monitoring data are based on single investigation, focussing on limited area and on few compounds of interest. The large number of approved active ingredients (approximately 600 chemicals) makes difficult to obtain an accurate and actual information on herbicide application in different countries, even if herbicides are the second most important class of pesticides used in the European Union. The results of a two-year monitoring campaign undertaken in two areas intensively cultivated at Lombardy, Northern Italy, showed a diffuse groundwater contamination due to active ingredients and their metabolites. More than 50% of samples overcame M.A.C. and the most common herbicides were Atrazine, Terbuthylazine and Metolachlor, while DEA and DET metabolites were often characterized by greater concentrations than their relative active principles.

[1]  B. Patterson,et al.  Using polymer mats to biodegrade atrazine in groundwater: laboratory column experiments. , 2002, Journal of contaminant hydrology.

[2]  U. Dörfler,et al.  S-triazine residues in groundwater. , 1997, Chemosphere.

[3]  S. Rullo,et al.  Mobility of herbicides used for weed control in maize in lysimeter experiments. , 2001 .

[4]  A. Di Corcia,et al.  Multiresidue method for pesticides in drinking water using a graphitized carbon black cartridge extraction and liquid chromatographic analysis. , 1991, Analytical chemistry.

[5]  Mills Ms,et al.  Preferential Dealkylation Reactions of s-Triazine Herbicides in the Unsaturated Zone , 1994 .

[6]  M. Schiavon,et al.  Degradation of [14C]Terbuthylazine and [14C]Atrazine in Laboratory Soil Microcosms , 1997 .

[7]  W. Tappe,et al.  Diffuse atrazine pollution in German aquifers , 2004, Biodegradation.

[8]  M. Trevisan,et al.  Adsorption and degradation: from the laboratory to the real world. , 2003 .

[9]  A. Scheidleder,et al.  Groundwater quality and quantity in Europe , 1999 .

[10]  D. R. Hoagland,et al.  Persistence and leaching of atrazine, alachlor, and cyanazine under no-tillage practices , 1988 .

[11]  P. Sequi,et al.  Sorption of atrazine and trifluralin in relation to the physio-chemical characteristics of selected soils , 1992 .

[12]  M. Schiavon Studies of the leaching of atrazine, of its chlorinated derivatives, and of hydroxyatrazine from soil using 14C ring-labeled compounds under outdoor conditions. , 1988, Ecotoxicology and environmental safety.

[13]  C. Schenck,et al.  Atrazine contamination of groundwaters in eastern France in relation to the hydrogeological properties of the agricultural land , 1993 .

[14]  David I. Gustafson,et al.  Groundwater ubiquity score: a simple method for assessing pesticide leachability , 1989 .

[15]  E. Thurman,et al.  Formation and transport of deethylatrazine in the soil and vadose zone , 1991 .

[16]  F. Worrall,et al.  Aquifer vulnerability to pesticide pollution - Combining soil, land-use and aquifer properties with molecular descriptors , 2004 .

[17]  W. Battaglin,et al.  Herbicides and their metabolites in rainfall: Origin, transport, and deposition patterns across the midwestern and northeastern United States, 1990-1991 , 1997 .

[18]  S. Rullo,et al.  Studies on mobility and degradation pathways of terbuthylazine using lysimeters on a field scale. , 2003, Journal of environmental quality.

[19]  Spalding,et al.  Atrazine, Deethylatrazine, and Deisopropylatrazine Persistence Measured in Groundwater in Situ under Low-Oxygen Conditions. , 1998, Journal of agricultural and food chemistry.

[20]  D. Gooddy,et al.  Penetration of herbicides to groundwater in an unconfined chalk aquifer following normal soil applications. , 2001, Journal of contaminant hydrology.

[21]  M. Trevisan,et al.  Pesticide in air, plant, soil & water system. Proceedings of the XII Symposium Pesticide Chemistry, Piacenza, Italy, 4-6 June 2003. , 2003 .

[22]  A. Johnson,et al.  Potential for isoproturon, atrazine and mecoprop to be degraded within a chalk aquifer system , 2000 .

[23]  D. Barraclough,et al.  Bound residues: environmental solution or future problem? , 2005, Environmental pollution.

[24]  B. Patterson,et al.  Bioaugmentation of Atrazine and Fenamiphos Impacted Groundwater: Laboratory Evaluation , 2000 .

[25]  D. Sanyal,et al.  Effects of repeated metolachlor applications on its persistence in field soil and degradation kinetics in mixed microbial cultures , 1999, Biology and Fertility of Soils.

[26]  L. Guzzella,et al.  Migration of Pesticide Residues from Agricultural Soil to Groundwater , 1996 .

[27]  A. Crobe,et al.  Leaching properties of some degradation products of alachlor and metolachlor. , 2000, Chemosphere.

[28]  R. Wagenet,et al.  Nonequilibrium Sorption and Degradation of Three 2‐Chloro‐s‐Triazine Herbicides in Soil‐Water Systems , 1991 .

[29]  D. Watts,et al.  Tillage and application effects on herbicide leaching and runoff , 1996 .