Physical, chemical and optical properties of barium nitrate Raman crystal

Abstract The physical, chemical and optical properties of barium nitrate crystal are considered from the point of its application for development of solid state Raman lasers and shifters. The described growth procedure has shown the possibility to fabricate laser elements with high optical homogeneity. Using Raman spectroscopic investigation of vibronic modes in barium nitrate crystal the linewidth broadening and frequency shift were measured. This proved that internal Raman modes in barium nitrate crystal have weak couplings with lattice phonons that results in high gain of Stimulated Raman Scattering (SRS).

[1]  A. S. Eremenko,et al.  BRIEF COMMUNICATIONS: Stimulated Raman scattering of the second harmonic of a neodymium laser in nitrate crystals , 1980 .

[2]  Alfano,et al.  Multiphonon dephasing of the 1086-cm-1 mode in calcite. , 1989, Physical review. B, Condensed matter.

[3]  Tasoltan T. Basiev,et al.  Investigation of the line broadening of an SRS-active vibration in a barium nitrate crystal by two-photon Raman amplification spectroscopy , 1995 .

[4]  Roberto Righini,et al.  Temperature-dependent decay of vibrational excitons in dipotassium sulfate crystal measured by picosecond time-resolved CARS , 1988 .

[5]  D. Irish,et al.  Ionic Interactions in Crystals: Infrared and Raman Spectra of Powdered Ca(NO3)2, Sr(NO3)2, Ba(NO3)2, and Pb(NO3)2 , 1970 .

[6]  Tasoltan T. Basiev,et al.  Stimulated Raman scattering of picosecond pulses in barium nitrate crystals , 1993 .

[7]  V. I. Startsev,et al.  On the growth of large perfect crystals of sodium nitrate , 1969 .

[8]  T T Basiev,et al.  Vibrational dynamic of the Raman-active mode in barium nitrate crystal. , 1995, Optics letters.

[9]  Tasoltan T. Basiev,et al.  Conversion of tunable radiation from a laser utilizing an LiF crystal containing F2− color centers by stimulated Raman scattering in Ba(NO3)2 and KGd(WO4)2 crystals , 1987 .

[10]  R. Ruoff Mutual polarization of monomer charge distribution in (HCN)2, (HCN)3, and (HCN)∞ , 1991 .

[11]  R. C. Weast CRC Handbook of Chemistry and Physics , 1973 .

[12]  J. Kalus,et al.  Temperature dependence of phonon-frequencies and -linewidths for weakly anharmonic molecular crystals , 1985 .

[13]  Vincenzo Schettino,et al.  Vibrational relaxation in molecular crystals , 1988 .

[14]  W. Kaiser,et al.  Vibrational dynamics of liquids and solids investigated by picosecond light pulses , 1978 .

[15]  J. Eckstein,et al.  Influence of Growth Conditions and Thermal History on the Constitution of NaNO3 Single Crystals , 1967 .

[16]  E. W. Stryland,et al.  Sensitive Measurement of Optical Nonlinearities Using a Single Beam Special 30th Anniversary Feature , 1990 .

[17]  K. Tsukamoto,et al.  Growth mechanism of Ba(NO3)2 crystals from aqueous solution as revealed by growth rate measurements coupled with surface observations , 1983 .

[18]  Roberto Righini,et al.  Anomalous temperature dependence of the vibrational exciton lifetime in NaNO3 crystal , 1989 .

[19]  C. Benoit,et al.  Dynamical properties of crystals of Sr(NO3)2, Ba(NO3)2, and Pb(NO3)2. I. Infrared spectra and structure , 1976 .

[20]  A. Winchell,et al.  The microscopical characters of artificial inorganic solid substances : optical properties of artificial minerals , 1964 .