Abordagens semiquantitativa e quantitativa na avaliação da textura do solo por espectroscopia de reflectância bidirecional no VIS‑NIR‑SWIR

The objective of this work was to evaluate the potential of VIS‑NIR‑SWIR reflectance spectroscopy for the characterization of soil particle‑size distribution of samples from different textural classes, and to obtain models to predict clay, silt, and sand contents in the soil. A representative sample set of Oxisols and Ultisols from five locations in Mato Grosso do Sul state, Brazil, were used. Visible and near‑infrared to short‑wave infrared (from 350 to 2,500 nm) spectra of the samples were obtained and analyzed. Principal component analysis (PCA), fuzzy c‑means cluster analysis, multinomial logistic regression (MLR), and partial least squares regression were used. Characteristic spectra for the different soil texture classes and segregation of samples from texture classes and from sampling sites with distinct characteristics, through PCA, fuzzy c‑means, and RLM, show the semiquantitative potential of the VIS‑NIR‑SWIR reflectance data. Satisfactory quantification was obtained for clay (R²=0.92, RPD=3.59), silt (R²=0.80, RPD=2.15), and sand (R²=0.87, RPD=2.62). The reflectance spectroscopy techniques can help to assess soil texture and soil spacial variability with semiquantitative or quantitative methodologies.

[1]  Robert E. White,et al.  Principles and practice of soil science : the soil as a natural resource , 1997 .

[2]  José Alexandre Melo Demattê,et al.  Determining soil water status and other soil characteristics by spectral proximal sensing , 2006 .

[3]  James B. Reeves,et al.  Mid- and near-infrared spectroscopic assessment of soil compositional parameters and structural indices in two Ferralsols , 2006 .

[4]  Gilberto J. Garcia,et al.  Alteration of Soil Properties through a Weathering Sequence as Evaluated by Spectral Reflectance , 1999 .

[5]  Sabine Grunwald,et al.  Comparison of multivariate methods for inferential modeling of soil carbon using visible/near-infrared spectra , 2008 .

[6]  Carlos Roberto de Souza Filho,et al.  Identification of mineral components in tropical soils using reflectance spectroscopy and advanced spaceborne thermal emission and reflection radiometer (ASTER) data , 2011 .

[7]  Gerardo Beni,et al.  A Validity Measure for Fuzzy Clustering , 1991, IEEE Trans. Pattern Anal. Mach. Intell..

[8]  G. Bouyoucos Hydrometer Method Improved for Making Particle Size Analyses of Soils1 , 1962 .

[9]  J. Bezdek,et al.  FCM: The fuzzy c-means clustering algorithm , 1984 .

[10]  J. A. M. Demattê,et al.  Ambientes de produção como estratégia de manejo na cultura de cana-de-açúcar , 2009 .

[11]  William N. Venables,et al.  Modern Applied Statistics with S , 2010 .

[12]  Tomislav Hengl,et al.  Methods to interpolate soil categorical variables from profile observations: Lessons from Iran , 2007 .

[13]  H. Levene Robust tests for equality of variances , 1961 .

[14]  R. V. Rossel,et al.  In situ measurements of soil colour, mineral composition and clay content by vis–NIR spectroscopy , 2009 .

[15]  J. De Baerdemaeker,et al.  Classification of Soil Texture Classes by Using Soil Visual near Infrared Spectroscopy and Factorial Discriminant Analysis Techniques , 2005 .

[16]  José Alexandre Melo Demattê,et al.  Soil spectral library and its use in soil classification , 2010 .

[17]  Pedro Marques da Silveira,et al.  Espectroscopia de infravermelho na determinação da textura do solo , 2012 .

[18]  P. R. S. Vendrame,et al.  The potential of NIR spectroscopy to predict soil texture and mineralogy in Cerrado Latosols , 2012 .

[19]  K. Shepherd,et al.  Development of Reflectance Spectral Libraries for Characterization of Soil Properties , 2002 .

[20]  Russell G. Congalton,et al.  Assessing the accuracy of remotely sensed data : principles and practices , 1998 .

[21]  José Alexandre Melo Demattê,et al.  Caracterização e discriminação de solos pela sua energia eletromagnética refletida , 2002 .

[22]  Peter Filzmoser,et al.  Introduction to Multivariate Statistical Analysis in Chemometrics , 2009 .

[23]  E. R. Stoner,et al.  REFLECTANCE PROPERTIES OF SOILS , 1986 .

[24]  C. Hurburgh,et al.  Near-Infrared Reflectance Spectroscopy–Principal Components Regression Analyses of Soil Properties , 2001 .

[25]  Raphael A. Viscarra Rossel,et al.  ParLeS: Software for chemometric analysis of spectroscopic data , 2008 .

[26]  R. V. Rossel,et al.  Visible and near infrared spectroscopy in soil science , 2010 .