论文信息 - Behavior of the High Temperature Conductivity of Polypyrrole Nitrate Films

Behavior of the High Temperature Conductivity of Polypyrrole Nitrate Films

XPS, TGA, and conductivity measurement were performed on PPy(NO3−) films as prepared and those after treatment in a neutral aqueous solution. A characteristic decrease of conductivity accompanied by ca. 5% weight loss was observed for PPy(NO3−) film as prepared in the temperature range of ca. 105—130°C. Comparison with the results of PPy(NO3−) films after treatment in a neutral solution offers further support for the existence of a protonated structure in the PPy(NO3−) as prepared.

Yongfang Li | H. Inokuchi | Ren-yuan Qian | K. Imaeda

[1] Li Yongfang,et al. On the nature of redox processes in the cyclic voltammetry of polypyrrole nitrate in aqueous solutions , 1993 .

[2] V. Truong,et al. Thermal stability of polypyrroles , 1992 .

[3] Q. Pei,et al. Protonation and deprotonation of polypyrrole chain in aqueous solutions , 1991 .

[4] Li Yongfang,et al. XPS study of depth distribution of anion in conducting polypyrrole , 1990 .

[5] N. Mermilliod,et al. Overdoping and the capacitive effect in polypyrrole , 1987 .

[6] N. Mermilliod,et al. Capacitive Charge and Noncapacitive Charge in Conducting Polymer Electrodes , 1987 .

[7] J. Pernaut,et al. Spectroelectrochemical studies of the redox and kinetic behaviour of polypyrrole film , 1984 .

[8] M. Krounbi,et al. The chemical and physical properties of pyrrole‐based conducting polymers: The oxidation of neutral polypyrrole , 1983 .

[9] J. A. Logan,et al. ‘Organic metals’: polypyrrole, a stable synthetic ‘metallic’ polymer , 1979 .