A Bis(m‐phenylene)‐32‐crown‐10/Paraquat [2]Rotaxane

The successful preparation of the first bis(m-phenylene)-32-crown-10/paraquat [2]rotaxane showed unambiguously that psuedorotaxane-type complexation, rather than the taco-complex-type complexation previously observed in the solid state and in solution, exists – in solution – for complexation between bis(m-phenylene)-32-crown-10 derivatives and paraquat derivatives.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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