Investigation of AISI 1040 steel corrosion in H2S solution containing chloride ions by digital image processing coupled with electrochemical techniques

This paper presents a study of AISI 1040 steel corrosion in aqueous electrolyte of acetic acid buffer containing 3.1 and 31 � 10 � 3 mol dm � 3 of Na2S in both the presence and absence of 3.5 wt.% NaCl. This investigation of steel corrosion was carried out using potential polarization, and open-circuit and in situ optical microscopy. The morphological analysis and classification of types of surface corrosion damage by digital image processing reveals grain boundary corrosion and shows a non-uniform sulfide film growth, which occurs preferentially over pearlitic grains through successive formation and dissolution of the film.

[1]  F. Pérez,et al.  MORPHOLOGICAL ANALYSIS AND CLASSIFICATION OF TYPES OF SURFACE CORROSION DAMAGE BY DIGITAL IMAGE PROCESSING , 2006 .

[2]  G. Voort Metallography and microstructures , 2004 .

[3]  M. A. Gutiérrez,et al.  Spatial statistics of pitting corrosion patterning: Quadrat counts and the non-homogeneous Poisson process , 2008 .

[4]  Hugo Vieira Neto,et al.  Processamento digital de imagens , 1999 .

[5]  S. Laroche,et al.  Grain Sizing of Anodized Aluminum by Color Image Analysis , 1996, Microscopy Today.

[6]  M. G. Bailey,et al.  Electrochemical formation of mackinawite in alkaline sulphide solutions , 1978 .

[7]  G. Voort Color Metallography , 2004 .

[8]  Two-Phase Grain Structures Standard Test Methods for Determining Average Grain Size Using Semiautomatic and Automatic Image Analysis 1 , 2004 .

[9]  M. G. Bailey,et al.  The Formation of Ferrous Monosulfide Polymorphs during the Corrosion of Iron by Aqueous Hydrogen Sulfide at 21°C , 1980 .

[10]  R. Gillham,et al.  Formation of poorly crystalline iron monosulfides: Surface redox reactions on high purity iron, spectroelectrochemical studies , 2006 .

[11]  I. González,et al.  Electrochemical study of carbon steel corrosion in buffered acetic acid solutions with chlorides and H2S , 2002 .

[12]  M. Bueno,et al.  Image evaluation with chemometric strategies for quality control of paints. , 2007, Analytica chimica acta.

[13]  F. C. Bell,et al.  Improved metallographic etching techniques for stainless steel and for stainless steel to carbon steel weldments , 1976 .

[14]  S. Arzola,et al.  The effect of H2S concentration on the corrosion behavior of API 5L X-70 steel , 2005 .

[15]  Sami Matar,et al.  Chemistry of petrochemical processes , 1994 .

[16]  W. Zhou,et al.  Corrosion behavior of SM 80SS tube steel in stimulant solution containing H2S and CO2 , 2008 .

[17]  P. Shuler,et al.  A computational approach to predicting the formation of iron sulfide species using stability diagrams , 1997 .

[18]  George Spanos,et al.  Two- and three-dimensional microstructural characterization of a super-austenitic stainless steel , 2006 .

[19]  C.R.F. Azevedo,et al.  Failure analysis of a crude oil pipeline , 2007 .

[20]  Tie-hu Li,et al.  Corrosion behavior of oil tube steel in simulant solution with hydrogen sulfide and carbon dioxide , 2005 .

[21]  L. L. Shreir,et al.  Corrosion of metals and alloys , 1963 .

[22]  M. Pourbaix Atlas of Electrochemical Equilibria in Aqueous Solutions , 1974 .

[23]  Z. Quan,et al.  The influence of hydrogen sulfide on corrosion of iron under different conditions , 2000 .

[24]  Rafael C. González,et al.  Digital image processing using MATLAB , 2006 .

[25]  B. N. Chatterji,et al.  An FFT-based technique for translation, rotation, and scale-invariant image registration , 1996, IEEE Trans. Image Process..

[26]  L. Koene,et al.  Stochastic approach to the spatial analysis of pitting corrosion and pit interaction , 2007 .

[27]  W. Tsai,et al.  Electrochemical behavior of the simulated heat-affected zone of A516 carbon steel in H2S solution , 1996 .

[28]  Influence of sputtering conditions on corrosion of sputtered W–Ti–N thin film hard coatings: salt spray tests and image analysis , 2000 .

[29]  A S Mikhailov,et al.  Sudden Onset of Pitting Corrosion on Stainless Steel as a Critical Phenomenon , 2004, Science.

[30]  Riad Taha Al-Kasasbeh,et al.  Acceleration of Image Processing Using New Color Model , 2009 .

[31]  C. Cabrera,et al.  Electrochemically grown passive films on carbon steel (SAE 1018) in alkaline sour medium , 2003 .